On-Surface Fabrication of Complex Hybrid Nanostructures

2020 ◽  
Author(s):  
Huihui Kong ◽  
Likun Wang ◽  
Wei Xu
Keyword(s):  
Hybrid Nanostructures ◽  
Complex Hybrid ◽  
Surface Fabrication

On-Surface Radical Oligomerisation: A New Approach to STM Tip-Induced Reactions

2018 ◽  
Author(s):  
Gaolei Zhan ◽  
Younes Makoudi ◽  
Judicael Jeannoutot ◽  
Simon Lamare ◽  
Michel Féron ◽  
...  
Keyword(s):  
Sample Surface ◽  
Scanning Tunnelling Microscope ◽  
Transfer Event ◽  
New Approach ◽  
The Past ◽  
Organic Nanostructures ◽  
Scanning Tunnelling ◽  
New Strategy ◽  
Surface Fabrication ◽  
And Control

Over the past decade, on-surface fabrication of organic nanostructures has been widely investigated for the development of molecular electronic devices, nanomachines, and new materials. Here, we introduce a new strategy to obtain alkyl oligomers in a controlled manner using on-surface radical oligomerisations that are triggered by the electrons/holes between the sample surface and the tip of a scanning tunnelling microscope. The resulting radical-mediated mechanism is substantiated by a detailed theoretical study. This electron transfer event only occurs when <i>V</i><sub>s</sub> < -3 V or <i>V</i><sub>s</sub> > + 3 V and allows access to reactive radical species under exceptionally mild conditions. This transfer can effectively ‘switch on’ a sequence leading to formation of oligomers of defined size distribution due to the on-surface confinement of reactive species. Our approach enables new ways to initiate and control radical oligomerisations with tunnelling electrons, leading to molecularly precise nanofabrication.

Creation and evaluation of new varieties and populations of alfalfa

2020 ◽  
Author(s):  
I. A. Meremyanina I. A. ◽  
◽  
V.V. Kenyz V.V.
Keyword(s):  
High Productivity ◽  
Green Mass ◽  
Economically Valuable Traits ◽  
New Varieties ◽  
Complex Hybrid ◽  
The Creation

The article is based on the creation and evaluation of new varieties and complex hybrid populations of alfalfa with economically valuable traits and properties.Varieties with high productivity of green mass and seeds have been created and studied.

Hydrogel-clay Nanocomposites as Carriers for Controlled Release

2020 ◽  
Vol 27 (6) ◽  
pp. 919-954 ◽  
Author(s):  
Raluca Ianchis ◽  
Claudia Mihaela Ninciuleanu ◽  
Ioana Catalina Gifu ◽  
Elvira Alexandrescu ◽  
Cristina Lavinia Nistor ◽  
...  
Keyword(s):  
Drug Delivery ◽  
Controlled Release ◽  
Hybrid Materials ◽  
Pharmaceutical Formulations ◽  
Tree Of Life ◽  
Present Review ◽  
Clay Nanocomposites ◽  
Delivery Platform ◽  
Complex Hybrid

The present review aims to summarize the research efforts undertaken in the last few years in the development and testing of hydrogel-clay nanocomposites proposed as carriers for controlled release of diverse drugs. Their advantages, disadvantages and different compositions of polymers/biopolymers with diverse types of clays, as well as their interactions are discussed. Illustrative examples of studies regarding hydrogel-clay nanocomposites are detailed in order to underline the progressive researches on hydrogel-clay-drug pharmaceutical formulations able to respond to a series of demands for the most diverse applications. Brief descriptions of the different techniques used for the characterization of the obtained complex hybrid materials such as: swelling, TGA, DSC, FTIR, XRD, mechanical, SEM, TEM and biology tests, are also included. Enlightened by the presented data, we can suppose that hydrogel-clay nanocomposites will still be a challenging subject of global assiduous researches. We can dare to dream to an efficient drug delivery platform for the treatment of multiple affection concomitantly, these being undoubtedly like ”a tree of life” bearing different kinds of fruits and leaves proper for human healing.

scholarly journals Strategies to Build Hybrid Protein–DNA Nanostructures

Nanomaterials ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1332
Author(s):  
Armando Hernandez-Garcia
Keyword(s):  
Dynamic Systems ◽  
Dna Nanotechnology ◽  
Chemical Properties ◽  
Hybrid Nanostructures ◽  
Advanced Materials ◽  
Dna Nanostructures ◽  
Hybrid Protein ◽  
Structural Protein ◽  
The Individual ◽  
Structural Dna Nanotechnology

Proteins and DNA exhibit key physical chemical properties that make them advantageous for building nanostructures with outstanding features. Both DNA and protein nanotechnology have growth notably and proved to be fertile disciplines. The combination of both types of nanotechnologies is helpful to overcome the individual weaknesses and limitations of each one, paving the way for the continuing diversification of structural nanotechnologies. Recent studies have implemented a synergistic combination of both biomolecules to assemble unique and sophisticate protein–DNA nanostructures. These hybrid nanostructures are highly programmable and display remarkable features that create new opportunities to build on the nanoscale. This review focuses on the strategies deployed to create hybrid protein–DNA nanostructures. Here, we discuss strategies such as polymerization, spatial directing and organizing, coating, and rigidizing or folding DNA into particular shapes or moving parts. The enrichment of structural DNA nanotechnology by incorporating protein nanotechnology has been clearly demonstrated and still shows a large potential to create useful and advanced materials with cell-like properties or dynamic systems. It can be expected that structural protein–DNA nanotechnology will open new avenues in the fabrication of nanoassemblies with unique functional applications and enrich the toolbox of bionanotechnology.

II–VI Organic–Inorganic Hybrid Nanostructures with Greatly Enhanced Optoelectronic Properties, Perfectly Ordered Structures, and Shelf Stability of Over 15 Years

ACS Nano ◽  
2021 ◽  
Author(s):  
Tang Ye ◽  
Margaret Kocherga ◽  
Yi-Yang Sun ◽  
Andrei Nesmelov ◽  
Fan Zhang ◽  
...  
Keyword(s):  
Optoelectronic Properties ◽  
Hybrid Nanostructures ◽  
Ordered Structures ◽  
Inorganic Hybrid ◽  
Shelf Stability

Discriminative detection of volatile organic compounds using an electronic nose based on TiO2 hybrid nanostructures

2021 ◽  
pp. 130124
Author(s):  
Patrick P. Conti ◽  
Rafaela S. Andre ◽  
Luiza A. Mercante ◽  
Lucas Fugikawa-Santos ◽  
Daniel S. Correa
Keyword(s):  
Volatile Organic Compounds ◽  
Organic Compounds ◽  
Electronic Nose ◽  
Hybrid Nanostructures ◽  
Volatile Organic

scholarly journals Vertical monolithic integration of wide- and narrow-bandgap semiconductor nanostructures on graphene films

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Youngbin Tchoe ◽  
Janghyun Jo ◽  
HoSung Kim ◽  
Heehun Kim ◽  
Hyeonjun Baek ◽  
...  
Keyword(s):  
Graphene Film ◽  
Monolithic Integration ◽  
Hybrid Nanostructures ◽  
Dual Wavelength ◽  
Multilayer Graphene ◽  
Graphene Films ◽  
Transmission Electron ◽  
Zno Nanotubes ◽  
Metal Organic ◽  
Hybrid Configuration

AbstractWe report monolithic integration of indium arsenide (InAs) nanorods and zinc oxide (ZnO) nanotubes using a multilayer graphene film as a suspended substrate, and the fabrication of dual-wavelength photodetectors with the hybrid configuration of these materials. For the hybrid nanostructures, ZnO nanotubes and InAs nanorods were grown vertically on the top and bottom surfaces of the graphene films by metal-organic vapor-phase epitaxy and molecular beam epitaxy, respectively. The structural, optical, and electrical characteristics of the hybrid nanostructures were investigated using transmission electron microscopy, spectral photoresponse analysis, and current–voltage measurements. Furthermore, the hybrid nanostructures were used to fabricate dual-wavelength photodetectors sensitive to both ultraviolet and mid-infrared wavelengths.

Modified optoelectronic behavior of MoS2/TiO2 hybrid nanostructures by thermal annealing

2020 ◽  
Author(s):  
Sanjeev Kumar ◽  
J. Shakya ◽  
M. K. Kumawat ◽  
T. Mohanty
Keyword(s):  
Thermal Annealing ◽  
Hybrid Nanostructures

scholarly journals Tight-binding investigation of the structural and vibrational properties of graphene–single wall carbon nanotube junctions

2021 ◽  
Author(s):  
Juhi Srivastava ◽  
Anshu Gaur
Keyword(s):  
Charge Transfer ◽  
Carbon Nanotube ◽  
Phonon Mode ◽  
Tight Binding ◽  
Hybrid Nanostructures ◽  
Structural Deformation ◽  
Vibrational Properties ◽  
Single Wall Carbon Nanotube ◽  
Single Wall Carbon ◽  
Carbon Nanotube Junctions

The phonon mode frequencies of SWNT and SLG in hybrid nanostructures are sensitive to various interactions, such as vdW forces, structural deformation and/or charge transfer between SWNT and SLG.

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