Estimation of Neck Size Distribution in Ordered Cagelike Materials Using Nitrogen and Water Desorption Isotherms

2017 ◽  
Vol 121 (48) ◽  
pp. 26806-26814
Author(s):  
Kunimitsu Morishige
1997 ◽  
Vol 275 (10) ◽  
pp. 964-971 ◽  
Author(s):  
W. A. P. Luck ◽  
K. Rangsriwatananon

2000 ◽  
Vol 43 (2) ◽  
pp. 103-107 ◽  
Author(s):  
A Belarbi ◽  
Ch Aymard ◽  
J.M Meot ◽  
A Themelin ◽  
M Reynes

2017 ◽  
Vol 31 (1) ◽  
pp. 73-82 ◽  
Author(s):  
Milena Kercheva ◽  
Zofia Sokołowska ◽  
Mieczysław Hajnos ◽  
Kamil Skic ◽  
Toma Shishkov

Abstract The heterogeneity of soil physical properties of Fluvisols, lack of large pristine areas, and different moisture regimes on non-flooded and flooded terraces impede the possibility to find a soil profile which can serve as a baseline for estimating the impact of natural or anthropogenic factors on soil evolution. The aim of this study is to compare the pore size distribution of pristine Fluvisols on flooded and non-flooded terraces using the method of the soil water retention curve, mercury intrusion porosimetry, nitrogen adsorption isotherms, and water vapour sorption. The pore size distribution of humic horizons of pristine Fluvisols on the non-flooded terrace differs from pore size distribution of Fluvisols on the flooded terrace. The peaks of textural and structural pores are higher in the humic horizons under more humid conditions. The structural characteristics of subsoil horizons depend on soil texture and evolution stage. The peaks of textural pores at about 1 mm diminish with lowering of the soil organic content. Structureless horizons are characterized by uni-modal pore size distribution. Although the content of structural pores of the subsoil horizons of Fluvisols on the non-flooded terrace is low, these pores are represented by biopores, as the coefficient of filtration is moderately high. The difference between non-flooded and flooded profiles is well expressed by the available water storage, volume and mean radius of pores, obtained by mercury intrusion porosimetry and water desorption, which are higher in the surface horizons of frequently flooded Fluvisols.


Fuel ◽  
2016 ◽  
Vol 171 ◽  
pp. 101-107 ◽  
Author(s):  
Keji Wan ◽  
Qiongqiong He ◽  
Zhenyong Miao ◽  
Xuejing Liu ◽  
Shaomeng Huang

2015 ◽  
Vol 40 (1) ◽  
pp. e12278 ◽  
Author(s):  
Gabriel Henrique Horta de Oliveira ◽  
Paulo Cesar Corrêa ◽  
Ana Paula Lelis Rodrigues de Oliveira ◽  
Renata Cunha dos Reis ◽  
Ivano Alessandro Devilla

2017 ◽  
Vol 13 (11) ◽  
Author(s):  
Pan Wang ◽  
Nan Fu ◽  
Dong Li ◽  
Li-jun Wang

AbstractThe desorption isotherms ofjaponicaandindicarice seeds were determined at 15, 25, 35, 45 °C within the water activity range from 0.12 to 0.92 and it was observed that GAB model could accurately describe the desorption behaviors with low values of mean relative error (MRE). The thermodynamic properties of rice seeds were obtained by water desorption isotherms. The moisture content with the minimum integral entropy was considered as the best storage condition where the strongest energetic interaction between water molecular and solid occurred and the optimum seed moisture for storage at 35 °C occurred at 6.02 g water per 100 g of dry matter (ɑwof 0.12) forjaponicarice seed and 5.28 g water per 100 g of dry matter (ɑwof 0.08) forindicarice seed, respectively. The mechanisms of desorption process were determined with integral enthalpy–entropy compensation theory and it was observed that the at low moisture content the desorption process of rice seed was controlled by changes of entropy, whereas the desorption process was considered to be controlled by enthalpy mechanism at high moisture content. It was found that theindicarice seed exhibited a wider water activity range in the minimum integral entropy zone, indicating thatindicarice seed was more stable to withstand the different storage conditions compared withjaponicarice seed.


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