Adsorption of Cesium at the External Surface of TOT Type Clay Mineral: Effect of the Interlayer Cation and the Hydrated State

2019 ◽  
Vol 123 (32) ◽  
pp. 19540-19548 ◽  
Author(s):  
Xiong Li ◽  
Na Liu ◽  
Jianguo Zhang
Author(s):  
Jane A. Westfall ◽  
S. Yamataka ◽  
Paul D. Enos

Scanning electron microscopy (SEM) provides three dimensional details of external surface structures and supplements ultrastructural information provided by transmission electron microscopy (TEM). Animals composed of watery jellylike tissues such as hydras and other coelenterates have not been considered suitable for SEM studies because of the difficulty in preserving such organisms in a normal state. This study demonstrates 1) the successful use of SEM on such tissue, and 2) the unique arrangement of batteries of nematocysts within large epitheliomuscular cells on tentacles of Hydra littoralis.Whole specimens of Hydra were prepared for SEM (Figs. 1 and 2) by the fix, freeze-dry, coat technique of Small and Màrszalek. The specimens were fixed in osmium tetroxide and mercuric chloride, freeze-dried in vacuo on a prechilled 1 Kg brass block, and coated with gold-palladium. Tissues for TEM (Figs. 3 and 4) were fixed in glutaraldehyde followed by osmium tetroxide. Scanning micrographs were taken on a Cambridge Stereoscan Mark II A microscope at 10 KV and transmission micrographs were taken on an RCA EMU 3G microscope (Fig. 3) or on a Hitachi HU 11B microscope (Fig. 4).


Author(s):  
W. W. Barker ◽  
W. E. Rigsby ◽  
V. J. Hurst ◽  
W. J. Humphreys

Experimental clay mineral-organic molecule complexes long have been known and some of them have been extensively studied by X-ray diffraction methods. The organic molecules are adsorbed onto the surfaces of the clay minerals, or intercalated between the silicate layers. Natural organo-clays also are widely recognized but generally have not been well characterized. Widely used techniques for clay mineral identification involve treatment of the sample with H2 O2 or other oxidant to destroy any associated organics. This generally simplifies and intensifies the XRD pattern of the clay residue, but helps little with the characterization of the original organoclay. Adequate techniques for the direct observation of synthetic and naturally occurring organoclays are yet to be developed.


Author(s):  
James F. Hainfeld ◽  
Frederic R. Furuya ◽  
Kyra Carbone ◽  
Martha Simon ◽  
Beth Lin ◽  
...  

A recently developed 1.4 nm gold cluster has been found to be useful in labeling macromolecular sites to 1-3 nm resolution. The gold compound is organically derivatized to contain a monofunctional arm for covalent linking to biomolecules. This may be used to mark a specific site on a structure, or to first label a component and then reassemble a multicomponent macromolecular complex. Two examples are given here: the chaperonin groEL and ribosomes.Chaperonins are essential oligomeric complexes that mediate nascent polypeptide chain folding to produce active proteins. The E. coli chaperonin, groEL, has two stacked rings with a central hole ∽6 nm in diameter. The protein dihydrofolate reductase (DHFR) is a small protein that has been used in chain folding experiments, and serves as a model substrate for groEL. By labeling the DHFR with gold, its position with respect to the groEL complex can be followed. In particular, it was sought to determine if DHFR refolds on the external surface of the groEL complex, or whether it interacts in the central cavity.


2007 ◽  
Vol 2007 (suppl_26) ◽  
pp. 417-422 ◽  
Author(s):  
W. Oueslati ◽  
M. S. Karmous ◽  
H. Ben Rhaiem ◽  
B. Lanson ◽  
A. Ben Haj Amara

Author(s):  
A., C. Prasetyo

Overpressure existence represents a geological hazard; therefore, an accurate pore pressure prediction is critical for well planning and drilling procedures, etc. Overpressure is a geological phenomenon usually generated by two mechanisms, loading (disequilibrium compaction) and unloading mechanisms (diagenesis and hydrocarbon generation) and they are all geological processes. This research was conducted based on analytical and descriptive methods integrated with well data including wireline log, laboratory test and well test data. This research was conducted based on quantitative estimate of pore pressures using the Eaton Method. The stages are determining shale intervals with GR logs, calculating vertical stress/overburden stress values, determining normal compaction trends, making cross plots of sonic logs against density logs, calculating geothermal gradients, analyzing hydrocarbon maturity, and calculating sedimentation rates with burial history. The research conducted an analysis method on the distribution of clay mineral composition to determine depositional environment and its relationship to overpressure. The wells include GAP-01, GAP-02, GAP-03, and GAP-04 which has an overpressure zone range at depth 8501-10988 ft. The pressure value within the 4 wells has a range between 4358-7451 Psi. Overpressure mechanism in the GAP field is caused by non-loading mechanism (clay mineral diagenesis and hydrocarbon maturation). Overpressure distribution is controlled by its stratigraphy. Therefore, it is possible overpressure is spread quite broadly, especially in the low morphology of the “GAP” Field. This relates to the delta depositional environment with thick shale. Based on clay minerals distribution, the northern part (GAP 02 & 03) has more clay mineral content compared to the south and this can be interpreted increasingly towards sea (low energy regime) and facies turned into pro-delta. Overpressure might be found shallower in the north than the south due to higher clay mineral content present to the north.


2019 ◽  
Vol 16 (2) ◽  
Author(s):  
M. N. Setia Nusa

Water pipe of 4.5” diameter and has been operated for 8 year having failure due to corrosion attack on its external and internal surface. It is conducted failure analysis to find out the cause of corrosion by having testing examination of visual fractography, metalography,, SEM EDAX, hardness and chemical composition. Testing and examination results show that the failure / corroded pipe has a for in of general corrosion on the external surface due to environment factor or ground factor arround the pipe and on the internal surface was influenced by excessive root weld creating protrude which then causing turbolens and deposite to accelerate corrosion attack.Pipa berdiameter 4.5” yang berfungsi mengalirkan air bersih dan telah beroperasi selama 8 tahun, terjadi kerusakan berbentuk korosi pada permukaan luar pipa dan permukaan dalam. Untuk itu dilakukan analisa kerusakan untuk mengetahui penyebab terjadinya korosi dengan pengujian dan pemeriksaan secara visual,Fractography, Metallography, SEM, EDAX, Uji Kekerasan dan Uji Komposisi Kimia. Hasil pemeriksaan dan pengujian pada pipa yang rusak / korosi berbentuk jenis general korosi pada permukaan luar pipa yang diakibatkan faktor lingkungan atau tanah disekitar pipa, sedangkan pada bagian dalam pipa dipengaruhi oleh adanya lelehan pengelasan yang kurang sempurna sehingga menimbulkan benjolan yang mengakibatkan aliran air didalam pipa tidak lancar sehingga terjadi turbolensi yang menimbulkan endapan dan mengakibatkan percepatan terjadinya korosi.Keywords: Pipe, environtment, turbolens, corrosion, failure


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