Magnetite–Maghemite Nanoparticles in the 5–15 nm Range: Correlating the Core–Shell Composition and the Surface Structure to the Magnetic Properties. A Total Scattering Study.

2013 ◽  
Vol 25 (23) ◽  
pp. 4820-4827 ◽  
Author(s):  
Ruggero Frison ◽  
Giuseppe Cernuto ◽  
Antonio Cervellino ◽  
Oksana Zaharko ◽  
Gian Maria Colonna ◽  
...  
2020 ◽  
Vol 65 (10) ◽  
pp. 904
Author(s):  
V. O. Zamorskyi ◽  
Ya. M. Lytvynenko ◽  
A. M. Pogorily ◽  
A. I. Tovstolytkin ◽  
S. O. Solopan ◽  
...  

Magnetic properties of the sets of Fe3O4(core)/CoFe2O4(shell) composite nanoparticles with a core diameter of about 6.3 nm and various shell thicknesses (0, 1.0, and 2.5 nm), as well as the mixtures of Fe3O4 and CoFe2O4 nanoparticles taken in the ratios corresponding to the core/shell material contents in the former case, have been studied. The results of magnetic research showed that the coating of magnetic nanoparticles with a shell gives rise to the appearance of two simultaneous effects: the modification of the core/shell interface parameters and the parameter change in both the nanoparticle’s core and shell themselves. As a result, the core/shell particles acquire new characteristics that are inherent neither to Fe3O4 nor to CoFe2O4. The obtained results open the way to the optimization and adaptation of the parameters of the core/shell spinel-ferrite-based nanoparticles for their application in various technological and biomedical domains.


2017 ◽  
Vol 31 (33) ◽  
pp. 1750307 ◽  
Author(s):  
Ersin Kantar

In this study, we examine by comparing the dynamic magnetic and hysteretic properties of Ising-type endohedral fullerene (EF) with various dopant magnetic particles confined within a spherical cage. The model of EF X@C[Formula: see text] with X = spin-1/2, spin-1 and spin-3/2 is proposed to study the effect of the nature of core particle on the magnetic properties. The results were obtained by mean-field theory as well as Glauber-type stochastic dynamics, and focused on the response of thermal and hysteretic behaviors of systems. The system exhibits second- and first-order phase transitions. In three different core cases, the system also exhibits type-II superconductivity behavior with a dynamic hysteresis curves of the core. All results display magnetic properties of the EF which strongly depend on the nature of core particle. Moreover, core particle and core/shell (C–S) interaction are proposed as the basic factors affecting the magnetic properties of EF system.


2019 ◽  
Vol 7 (5) ◽  
pp. 1280-1291 ◽  
Author(s):  
Alaka Panda ◽  
R. Govindaraj ◽  
R. Mythili ◽  
G. Amarendra

Bismuth and iron oxides subjected to ball milling followed by controlled annealing treatments showed the formation of core–shell nanostructures with Bi2Fe4O9 as the core and a shell of BiFeO3 and Bi25FeO40 phases as deduced based on the analysis of transmission electron microscopy results.


2020 ◽  
Vol 62 (2) ◽  
pp. 285-290 ◽  
Author(s):  
D. A. Balaev ◽  
S. V. Semenov ◽  
A. A. Dubrovskii ◽  
A. A. Krasikov ◽  
S. I. Popkov ◽  
...  

2003 ◽  
Vol 789 ◽  
Author(s):  
Mathew M. Maye ◽  
Sandy Chen ◽  
Wai-Ben Chan ◽  
Lingyan Wang ◽  
Peter Njoki ◽  
...  

ABSTRACTThe application of molecularly-capped gold nanoparticles (1–5 nm) in catalysis (e.g., electrocatalytic oxidation of CO and methanol) requires a thorough understanding of the surface composition and structural properties. Gold nanoparticles consisting of metallic or alloy cores and organic encapsulating shells serve as an intriguing model system. One of the challenges for the catalytic application is the ability to manipulate the core and the shell properties in controllable ways. There is a need to understand the relative core-shell composition and the ability to remove the shell component under thermal treatment conditions. In this paper, we report results of a thermogravimetric analysis of the alkanethiolate monolayer-capped gold nanoparticles. This investigation is aimed at enhancing our understanding of the relative core-shell composition and thermal profiles.


2017 ◽  
Vol 36 (4) ◽  
pp. 01 ◽  
Author(s):  
Vagner Sargentelli ◽  
Antônio A. P. Ferreira

Nanotechnology is the understanding and control f matter at dimensions of roughly 1 – 100 nm. At the nanoscale, the properties like electrical conductivity and mechanical strength are not the same as the materials with particles in dimensions much more than 100 nm. The electronic structure changes dramatically too. Between nanomaterials, there is recently a great number of works that investing as the synthesis as the properties of the magnetic nanoparticles. The interest in these materials is due to its magnetic applications. Some of more representative magnetic materials are the metallic oxides, as some ferrites. However, the ferrites are often obtained as mixture of some oxides, which implies that the magnetic properties are not always well defined and reproducible. Thus, the researches has been turned to use of the magnetic metals, between which the cobalt. The cobalt is investigated because its high magnetic susceptility. However, this transition metal is easily oxidate in air and is toxic to human organism. For this reason, it has looked for to effect synthesis involving core – shell structures, which no to allow the oxidation of the cobalt and prevent against its toxicity. Between the shells that come being obtained it is of silica and of gold. In addition, in if treating to catalysis in a general way, the price of the cobalt and its magnetic properties are adjusted for the attainment core – shell catalysts, Cocore@Ptshell, (Co@Pt). So, the aim of this article is to present and to do an analysis of the more representative synthetic route used until the present moment to obtain the core – shell structures: Co@SiO2, Co@Au and Co@Pt.


SPIN ◽  
2017 ◽  
Vol 07 (04) ◽  
pp. 1750011 ◽  
Author(s):  
A. Jabar ◽  
R. Masrour ◽  
M. Hamedoun ◽  
A. Benyoussef

A cylindrical ferrimagnetic magnetic nanowire system of core and shell layers has been investigated using Monte Carlo simulation. Critical temperature is obtained for different values of exchange couplings at the core–shell interface, at shell–shell and core–core. The total magnetization has been the determinate for different values of crystal field. Hysteresis loop, coercive field and remanent magnetization of a core and shell layers are obtained using the Monte Carlo simulation. A number of characteristic behaviors are found, such as the occurrence of single and triple hysteresis loops for appropriate values of crystal field, temperatures values and exchange interaction values.


2014 ◽  
Vol 936 ◽  
pp. 359-363
Author(s):  
Yan Li Wu ◽  
Min Liao ◽  
Hai Xin Ding ◽  
Ru Chun Yang ◽  
Dan Dan Xiong ◽  
...  

The SiO2/NaGdF4:Eu3+ core/shell composite was prepared by a template-mediated method, making monodispersed SiO2 as core and NaGdF4:Eu colloids as shell, the morphology and the core-shell structure of the resulting particles were analyzed by SEM,X-ray diffraction, and the photo-luminescence and magnetic properties of the microspheres were investigated too. The results shows the composite have great potential to be used as homogeneous magnetic/optical bifunctional material.


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