scholarly journals Pure crystal orientation and anisotropic charge transport in large-area hybrid perovskite films

2016 ◽  
Vol 7 (1) ◽  
Author(s):  
Namchul Cho ◽  
Feng Li ◽  
Bekir Turedi ◽  
Lutfan Sinatra ◽  
Smritakshi P. Sarmah ◽  
...  
2020 ◽  
Vol 1 (3) ◽  
pp. 292-309 ◽  
Author(s):  
Ahmed Esmail Shalan

In the current review, we have reported the practical potential of PSCs, strategies, challenges, and approaches towards large-area scale PSC modules via different deposition techniques as well as functional materials for the device architecture.


2019 ◽  
Vol 5 (12) ◽  
pp. eaay0571 ◽  
Author(s):  
Haipeng Lu ◽  
Jingying Wang ◽  
Chuanxiao Xiao ◽  
Xin Pan ◽  
Xihan Chen ◽  
...  

Chiral-induced spin selectivity (CISS) occurs when the chirality of the transporting medium selects one of the two spin ½ states to transport through the media while blocking the other. Monolayers of chiral organic molecules demonstrate CISS but are limited in their efficiency and utility by the requirement of a monolayer to preserve the spin selectivity. We demonstrate CISS in a system that integrates an inorganic framework with a chiral organic sublattice inducing chirality to the hybrid system. Using magnetic conductive-probe atomic force microscopy, we find that oriented chiral 2D-layered Pb-iodide organic/inorganic hybrid perovskite systems exhibit CISS. Electron transport through the perovskite films depends on the magnetization of the probe tip and the handedness of the chiral molecule. The films achieve a highest spin-polarization transport of up to 86%. Magnetoresistance studies in modified spin-valve devices having only one ferromagnet electrode confirm the occurrence of spin-dependent charge transport through the organic/inorganic layers.


2020 ◽  
Vol 230 ◽  
pp. 00006
Author(s):  
Paola Lova ◽  
Paolo Giusto ◽  
Francesco Di Stasio ◽  
Giovanni Manfredi ◽  
Giuseppe M. Paternò ◽  
...  

Thanks to versatile optoelectronic properties solution processable perovskites have attracted increasing interest as active materials in photovoltaic and light emitting devices. However, the deposition of perovskite thin films necessitates wide range solvents that are incompatible with many other solution-processable media, including polymers that are usually dissolved by the perovskite solvents. In this work, we demonstrate that hybrid perovskite thin films can be coupled with all polymer planar photonic crystals with different approaches to achieve emission intensity enhancement and reshaping using different approaches. The possibility to control and modify the emission spectrum of a solution processable perovskite via a simple spun-cast polymer structure is indeed of great interest in optoelectronic applications requiring high color purity or emission directionality. Furthermore, thanks to the ease of fabrication and scalability of solution-processed photonic crystals, this approach could enable industrial scale production of low-cost, large area, lightweight and flexible polymer-perovskite lighting devices, which may be tuned without resorting to compositional engineering.


2016 ◽  
Vol 9 (1) ◽  
pp. 1077-1085 ◽  
Author(s):  
Tom Kollek ◽  
Daniel Wurmbrand ◽  
Susanne T. Birkhold ◽  
Eugen Zimmermann ◽  
Julian Kalb ◽  
...  

1991 ◽  
Vol 35 (A) ◽  
pp. 681-685 ◽  
Author(s):  
Danut Dragoi

AbstractNonlinear equations are given for determining the crystallographic orientation of surfaces of single crystals. The equations are solved by an iterative method in several variables. The angle ϕ between the surface plane and the lattice plane in question is decomposed into two components α and β. These two components are obtained from the solution of a non-linear system of equations using two measurements and the Bragg angle. The diffractometric system considered is the well known θ/2θ with a sufficiently large area of x-ray detection and the capability of holding single crystal samples. The results obtained are discussed from experimental and theoretical points of view.


2020 ◽  
Vol 13 (9) ◽  
pp. 3093-3101 ◽  
Author(s):  
Yi Yang ◽  
Cheng Liu ◽  
Arup Mahata ◽  
Mo Li ◽  
Cristina Roldán-Carmona ◽  
...  

A universal vertically-rotated (VR) methodology is proposed to rotate the crystal orientation of 2D perovskites, which improves charge transport properties by several orders of magnitude and boosts the efficiency of 2D (n ≤ 4) PSCs to above 17%.


2019 ◽  
Vol 70 (1) ◽  
pp. 219-244 ◽  
Author(s):  
Tong Zhu ◽  
Jordan M. Snaider ◽  
Long Yuan ◽  
Libai Huang

We highlight the recent progress in ultrafast dynamic microscopy that combines ultrafast optical spectroscopy with microscopy approaches, focusing on the application transient absorption microscopy (TAM) to directly image energy and charge transport in solar energy harvesting and conversion systems. We discuss the principles, instrumentation, and resolutions of TAM. The simultaneous spatial, temporal, and excited-state-specific resolutions of TAM unraveled exciton and charge transport mechanisms that were previously obscured in conventional ultrafast spectroscopy measurements for systems such as organic solar cells, hybrid perovskite thin films, and molecular aggregates. We also discuss future directions to improve resolutions and to develop other ultrafast imaging contrasts beyond transient absorption.


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