scholarly journals Porous cage-derived nanomaterial inks for direct and internal three-dimensional printing

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Tangi Aubert ◽  
Jen-Yu Huang ◽  
Kai Ma ◽  
Tobias Hanrath ◽  
Ulrich Wiesner
Keyword(s):  
3D Printing ◽  
Structural Control ◽  
High Surface ◽  
High Surface Area ◽  
Three Dimensional ◽  
Processing Technique ◽  
Advanced Materials ◽  
Host Matrix ◽  
Digital Light Processing ◽  
Three Dimensional Printing

Abstract The convergence of 3D printing techniques and nanomaterials is generating a compelling opportunity space to create advanced materials with multiscale structural control and hierarchical functionalities. While most nanoparticles consist of a dense material, less attention has been payed to 3D printing of nanoparticles with intrinsic porosity. Here, we combine ultrasmall (about 10 nm) silica nanocages with digital light processing technique for the direct 3D printing of hierarchically porous parts with arbitrary shapes, as well as tunable internal structures and high surface area. Thanks to the versatile and orthogonal cage surface modifications, we show how this approach can be applied for the implementation and positioning of functionalities throughout 3D printed objects. Furthermore, taking advantage of the internal porosity of the printed parts, an internal printing approach is proposed for the localized deposition of a guest material within a host matrix, enabling complex 3D material designs.

scholarly journals Digital Light Processing Based Three-dimensional Printing for Medical Applications

2019 ◽  
Vol 6 (1) ◽  
pp. 1 ◽  
Author(s):  
Jiumeng Zhang ◽  
Qipeng Hu ◽  
Shuai Wang ◽  
Jie Tao ◽  
Maling Gou
Keyword(s):  
3D Printing ◽  
Clinical Medicine ◽  
Scale Up ◽  
Three Dimensional ◽  
Biological Research ◽  
Printing Technology ◽  
Digital Light Processing ◽  
Three Dimensional Printing ◽  
Dimensional Printing ◽  
Potential Tool

An additive manufacturing technology based on projection light, digital light processing (DLP) 3D printing, has been widely applied in the field of medical products production and development. The precision projection light, reflected by a million pixels instead of a focused point, provides this technology both printing accuracy and printing speed. In particular, this printing technology provides a relatively milder condition to cells due to its non-direct contact. This review introduces the DLP-based 3D printing technology and its applications in medicine, including precise medical devices, functionalized artificial tissues and specific drug delivery systems. The products are particularly discussed for their significance for medicine. We believe that this technology provides a potential tool for biological research and clinical medicine, while challenges of scale-up and regulatory approval are also discussed.

scholarly journals Fabrication of Conducting Polyacrylate Resin Solution with Polyaniline Nanofiber and Graphene for Conductive 3D Printing Application

Polymers ◽  
2018 ◽  
Vol 10 (9) ◽  
pp. 1003 ◽  
Author(s):  
Hoseong Han ◽  
Sunghun Cho
Keyword(s):  
3D Printing ◽  
Three Dimensional ◽  
Optical Microscope ◽  
Graphene Sheets ◽  
Digital Light Processing ◽  
Three Dimensional Printing ◽  
Resin Solution ◽  
Light Curing ◽  
Dimensional Printing ◽  
Printing Time

Three-dimensional printing based on the digital light processing (DLP) method offers solution processability, fast printing time, and high-quality printing through selective light curing of photopolymers. This research relates to a method of dispersing polyaniline nanofibers (PANI NFs) and graphene sheets in a polyacrylate resin solution for optimizing the conductive solution suitable for DLP-type 3D printing. Dispersion and morphology of the samples with different filler contents were investigated by field emission scanning electron microscope (FE-SEM) and optical microscope (OM) analyses. The polyacrylate composite solution employing the PANI NFs and graphene was printed well with various shapes and sizes through the 3D printing of DLP technology. In addition, the electrical properties of the printed sculptures have been investigated using a 4-point probe measurement system. The printed sculpture containing the PANI NFs and graphene sheets exhibited electrical conductivity (4.00 × 10−9 S/cm) up to 107 times higher than the pure polyacrylate (1.1 × 10−16 S/cm). This work suggests potential application of the PANI NF/graphene cofiller system for DLP-type 3D printing.

Development of fabrics by digital light processing three-dimensional printing technology and using a polyurethane acrylate photopolymer

2019 ◽  
Vol 90 (7-8) ◽  
pp. 847-856
Author(s):  
Seul Gi Kim ◽  
Ji Eun Song ◽  
Hye Rim Kim
Keyword(s):  
3D Printing ◽  
Layer Thickness ◽  
Three Dimensional ◽  
Curing Time ◽  
Printing Technology ◽  
Digital Light Processing ◽  
Three Dimensional Printing ◽  
3D Printing Technology ◽  
Polyurethane Acrylate ◽  
3D Printed

This study aimed to produce fabrics by the digital light processing (DLP) three-dimensional (3D) printing technology and using a polyurethane acrylate photopolymer as the printing material. The effect of the acrylate oligomer concentration on printing was evaluated. The DLP 3D printing conditions, such as the curing time and layer thickness, were controlled considering the physical properties, such as the tensile strength, elongation, and crease recovery of the 3D printed material. The optimal printing conditions were as follows: concentration of acrylate oligomer in the photopolymer: 10% (v/v); curing time per layer: 14 s; and layer thickness: 100 µm. These results are expected to guide further studies on the development of fabrics using DLP 3D printing technology.

scholarly journals Traditional versus mirror three-dimensional printing technology for isolated acetabular fractures: a retrospective study with a median follow-up of 25 months

2021 ◽  
Vol 49 (6) ◽  
pp. 030006052110285
Author(s):  
Kai Xiao ◽  
Bo Xu ◽  
Lin Ding ◽  
Weiguang Yu ◽  
Lei Bao ◽  
...  
Keyword(s):  
3D Printing ◽  
Three Dimensional ◽  
Operation Time ◽  
Harris Hip Score ◽  
Acetabular Fractures ◽  
Printing Technology ◽  
Three Dimensional Printing ◽  
3D Printing Technology ◽  
Significant Difference

Objective To assess the outcomes of traditional three-dimensional (3D) printing technology (TPT) versus mirror 3D printing technology (MTT) in treating isolated acetabular fractures (IAFs). Methods Consecutive patients with an IAF treated by either TPT or MTT at our tertiary medical centre from 2012 to 2018 were retrospectively reviewed. Follow-up was performed 1, 3, 6, and 12 months postoperatively and annually thereafter. The primary outcome was the Harris hip score (HHS), and the secondary outcomes were major intraoperative variables and key orthopaedic complications. Results One hundred fourteen eligible patients (114 hips) with an IAF (TPT, n = 56; MTT, n = 58) were evaluated. The median follow-up was 25 months (range, 21–28 months). At the last follow-up, the mean HHS was 82.46 ±14.70 for TPT and 86.30 ± 13.26 for MTT with a statistically significant difference. Significant differences were also detected in the major intraoperative variables (operation time, intraoperative blood loss, number of fluoroscopic screenings, and anatomical reduction number) and the major orthopaedic complications (loosening, implant failure, and heterotopic ossification). Conclusion Compared with TPT, MTT tends to produce accurate IAF reduction and may result in better intraoperative variables and a lower rate of major orthopaedic complications.

scholarly journals Three-dimensional printing for heart diseases: clinical application review

2021 ◽  
Author(s):  
Yanyan Ma ◽  
Peng Ding ◽  
Lanlan Li ◽  
Yang Liu ◽  
Ping Jin ◽  
...  
Keyword(s):  
3D Printing ◽  
Clinical Application ◽  
Heart Diseases ◽  
Three Dimensional ◽  
Convincing Evidence ◽  
Surgical Interventions ◽  
Three Dimensional Printing ◽  
Complex Anatomy ◽  
Precise Understanding ◽  
3D Printed

AbstractHeart diseases remain the top threat to human health, and the treatment of heart diseases changes with each passing day. Convincing evidence shows that three-dimensional (3D) printing allows for a more precise understanding of the complex anatomy associated with various heart diseases. In addition, 3D-printed models of cardiac diseases may serve as effective educational tools and for hands-on simulation of surgical interventions. We introduce examples of the clinical applications of different types of 3D printing based on specific cases and clinical application scenarios of 3D printing in treating heart diseases. We also discuss the limitations and clinically unmet needs of 3D printing in this context.

scholarly journals Three-Dimensional Printing of Hydroxyapatite Composites for Biomedical Application

Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 353
Author(s):  
Yanting Han ◽  
Qianqian Wei ◽  
Pengbo Chang ◽  
Kehui Hu ◽  
Oseweuba Valentine Okoro ◽  
...  
Keyword(s):  
Tissue Engineering ◽  
3D Printing ◽  
Biomedical Application ◽  
Three Dimensional ◽  
Antibacterial Properties ◽  
Natural Polymers ◽  
Three Dimensional Printing ◽  
3D Printed ◽  
Dental Applications ◽  
Hard Tissue Engineering

Hydroxyapatite (HA) and HA-based nanocomposites have been recognized as ideal biomaterials in hard tissue engineering because of their compositional similarity to bioapatite. However, the traditional HA-based nanocomposites fabrication techniques still limit the utilization of HA in bone, cartilage, dental, applications, and other fields. In recent years, three-dimensional (3D) printing has been shown to provide a fast, precise, controllable, and scalable fabrication approach for the synthesis of HA-based scaffolds. This review therefore explores available 3D printing technologies for the preparation of porous HA-based nanocomposites. In the present review, different 3D printed HA-based scaffolds composited with natural polymers and/or synthetic polymers are discussed. Furthermore, the desired properties of HA-based composites via 3D printing such as porosity, mechanical properties, biodegradability, and antibacterial properties are extensively explored. Lastly, the applications and the next generation of HA-based nanocomposites for tissue engineering are discussed.

scholarly journals Glucose/Graphene-Based Aerogels for Gas Adsorption and Electric Double Layer Capacitors

Polymers ◽  
2018 ◽  
Vol 11 (1) ◽  
pp. 40 ◽  
Author(s):  
Kang-Kai Liu ◽  
Biao Jin ◽  
Long-Yue Meng
Keyword(s):  
Gas Adsorption ◽  
High Surface ◽  
Aqueous Media ◽  
High Surface Area ◽  
Three Dimensional ◽  
High Specific Capacitance ◽  
Mesopore Size Distribution ◽  
Excellent Electrochemical Performance ◽  
Double Layer Capacitors ◽  
Hydrothermal Reduction

In this study, three-dimensional glucose/graphene-based aerogels (G/GAs) were synthesized using the hydrothermal reduction and CO2 activation method. Graphene oxide (GO) was used as a matrix, and glucose was used as a binder for the orientation of the GO morphology in an aqueous media. We determined that G/GAs exhibited narrow mesopore size distribution, a high surface area (763 m2 g−1), and hierarchical macroporous and mesoporous structures. These features contributed to G/GAs being promising adsorbents for the removal of CO2 (76.5 mg g−1 at 298 K), CH4 (16.8 mg g−1 at 298 K), and H2 (12.1 mg g−1 at 77 K). G/GAs presented excellent electrochemical performance, featuring a high specific capacitance of 305.5 F g−1 at 1 A g−1, and good cyclic stability of 98.5% retention after 10,000 consecutive charge-discharge cycles at 10 A g−1. This study provided an efficient approach for preparing graphene aerogels exhibiting hierarchical porosity for gas adsorption and supercapacitors.

Hierarchical Nano/Micro-structured Surfaces with High Surface Area/Volume Ratios

2021 ◽  
pp. 1-36
Author(s):  
Ketki Lichade ◽  
Yizhou Jiang ◽  
Yayue Pan
Keyword(s):  
Surface Structure ◽  
Surface Area ◽  
Light Trapping ◽  
High Surface ◽  
High Surface Area ◽  
Three Dimensional ◽  
Structure Design ◽  
Surface Structures ◽  
Structured Surfaces ◽  
Design And Manufacture

Abstract Recently, many studies have investigated additive manufacturing of hierarchical surfaces with high surface area/volume (SA/V) ratios, and their performance has been characterized for applications in next-generation functional devices. Despite recent advances, it remains challenging to design and manufacture high SA/V ratio structures with desired functionalities. In this study, we established the complex correlations among the SA/V ratio, surface structure geometry, functionality, and manufacturability in the Two-Photon Polymerization (TPP) process. Inspired by numerous natural structures, we proposed a 3-level hierarchical structure design along with the mathematical modeling of the SA/V ratio. Geometric and manufacturing constraints were modeled to create well-defined three-dimensional hierarchically structured surfaces with a high accuracy. A process flowchart was developed to design the proposed surface structures to achieve the target functionality, SA/V ratio, and geometric accuracy. Surfaces with varied SA/V ratios and hierarchy levels were designed and printed. The wettability and antireflection properties of the fabricated surfaces were characterized. It was observed that the wetting and antireflection properties of the 3-level design could be easily tailored by adjusting the design parameter settings and hierarchy levels. Furthermore, the proposed surface structure could change a naturally-hydrophilic surface to near-superhydrophobic. Geometrical light trapping effects were enabled and the antireflection property could be significantly enhanced (>80% less reflection) by the proposed hierarchical surface structures. Experimental results implied the great potential of the proposed surface structures for various applications such as microfluidics, optics, energy, and interfaces.

scholarly journals 3D Printing of Thermo-Sensitive Drugs

Pharmaceutics ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1524
Author(s):  
Sadikalmahdi Abdella ◽  
Souha H. Youssef ◽  
Franklin Afinjuomo ◽  
Yunmei Song ◽  
Paris Fouladian ◽  
...  
Keyword(s):  
3D Printing ◽  
Three Dimensional ◽  
Fused Deposition Modelling ◽  
Future Directions ◽  
Digital Light Processing ◽  
Fused Deposition ◽  
Printing Technique ◽  
3D Printed ◽  
Semi Solid ◽  
Selection Of

Three-dimensional (3D) printing is among the rapidly evolving technologies with applications in many sectors. The pharmaceutical industry is no exception, and the approval of the first 3D-printed tablet (Spiratam®) marked a revolution in the field. Several studies reported the fabrication of different dosage forms using a range of 3D printing techniques. Thermosensitive drugs compose a considerable segment of available medications in the market requiring strict temperature control during processing to ensure their efficacy and safety. Heating involved in some of the 3D printing technologies raises concerns regarding the feasibility of the techniques for printing thermolabile drugs. Studies reported that semi-solid extrusion (SSE) is the commonly used printing technique to fabricate thermosensitive drugs. Digital light processing (DLP), binder jetting (BJ), and stereolithography (SLA) can also be used for the fabrication of thermosensitive drugs as they do not involve heating elements. Nonetheless, degradation of some drugs by light source used in the techniques was reported. Interestingly, fused deposition modelling (FDM) coupled with filling techniques offered protection against thermal degradation. Concepts such as selection of low melting point polymers, adjustment of printing parameters, and coupling of more than one printing technique were exploited in printing thermosensitive drugs. This systematic review presents challenges, 3DP procedures, and future directions of 3D printing of thermo-sensitive formulations.

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