scholarly journals Highly tunable magneto-optical response from magnesium-vacancy color centers in diamond

2021 ◽  
Vol 7 (1) ◽  
Author(s):  
Anton Pershin ◽  
Gergely Barcza ◽  
Örs Legeza ◽  
Adam Gali
Keyword(s):  
Ground State ◽  
Large Scale ◽  
Optical Response ◽  
Emerging Technology ◽  
Spin States ◽  
Quantum Bits ◽  
Theoretical Methods ◽  
Operational Conditions ◽  
Spin Properties ◽  
External Strain

AbstractDefect quantum bits (qubits) constitute an important emerging technology. However, it is necessary to explore new types of defects to enable large-scale applications. In this article, we examine the potential of magnesium-vacancy (MgV) in diamond to operate as a qubit by computing the key electronic- and spin properties with robust theoretical methods. We find that the electronic structure of MgV permits the coexistence of two loosely separated spin-states, where both can emerge as a ground state and be interconverted depending on the temperature and external strain. These results demonstrate a route to control the magneto-optical response of a qubit by modulating the operational conditions.

Effects of a scattering center on the ground-state energy of quantum-dot lithium

2017 ◽  
Vol 31 (07) ◽  
pp. 1750071
Author(s):  
Z. D. Vatansever ◽  
S. Sakiroglu ◽  
I. Sokmen
Keyword(s):  
Quantum Dot ◽  
Ground State Energy ◽  
Ground State ◽  
State Energy ◽  
Electronic Charge ◽  
Strongly Correlated ◽  
Configuration Interaction Method ◽  
Charge Localization ◽  
Scattering Center ◽  
Spin Properties

In this paper, the effects of a repulsive scattering center on the ground-state energy and spin properties of a three-electron parabolic quantum dot are investigated theoretically by means of configuration interaction method. Phase transition from a weakly correlated regime to a strongly correlated regime is examined from several strengths and positions of Gaussian impurity. Numerical results reveal that the transition from spin-1/2 to spin-3/2 state depends strongly on the location of the impurity which accordingly states the controllability of the spin polarization. Moreover, broken circular symmetry results in more pronounced electronic charge localization.

scholarly journals A Survey on Edge Performance Benchmarking

2021 ◽  
Vol 54 (3) ◽  
pp. 1-33
Author(s):  
Blesson Varghese ◽  
Nan Wang ◽  
David Bermbach ◽  
Cheol-Ho Hong ◽  
Eyal De Lara ◽  
...  
Keyword(s):  
Large Scale ◽  
Future Internet ◽  
Coupled Systems ◽  
Operational Conditions ◽  
Loosely Coupled ◽  
Performance Benchmarking ◽  
The Past ◽  
Geographically Dispersed ◽  
Tightly Coupled ◽  
History Of

Edge computing is the next Internet frontier that will leverage computing resources located near users, sensors, and data stores to provide more responsive services. Therefore, it is envisioned that a large-scale, geographically dispersed, and resource-rich distributed system will emerge and play a key role in the future Internet. However, given the loosely coupled nature of such complex systems, their operational conditions are expected to change significantly over time. In this context, the performance characteristics of such systems will need to be captured rapidly, which is referred to as performance benchmarking, for application deployment, resource orchestration, and adaptive decision-making. Edge performance benchmarking is a nascent research avenue that has started gaining momentum over the past five years. This article first reviews articles published over the past three decades to trace the history of performance benchmarking from tightly coupled to loosely coupled systems. It then systematically classifies previous research to identify the system under test, techniques analyzed, and benchmark runtime in edge performance benchmarking.

scholarly journals Numerical Simulation of EPB Shield Tunnelling with TBM Operational Condition Control Using Coupled DEM–FDM

2021 ◽  
Vol 11 (6) ◽  
pp. 2551
Author(s):  
Hyobum Lee ◽  
Hangseok Choi ◽  
Soon-Wook Choi ◽  
Soo-Ho Chang ◽  
Tae-Ho Kang ◽  
...  
Keyword(s):  
Numerical Simulation ◽  
Large Scale ◽  
Tunnel Boring Machine ◽  
Chamber Pressure ◽  
Screw Conveyor ◽  
Shield Tunnel ◽  
Pressure Balance ◽  
Operational Conditions ◽  
Shield Tunnelling ◽  
Epb Shield

This study demonstrates a three-dimensional numerical simulation of earth pressure balance (EPB) shield tunnelling using a coupled discrete element method (DEM) and a finite difference method (FDM). The analysis adopted the actual size of a spoke-type EPB shield tunnel boring machine (TBM) consisting of a cutter head with cutting tools, working chamber, screw conveyor, and shield. For the coupled model to reproduce the in situ ground condition, the ground formation was generated partially using the DEM (for the limited domain influenced by excavation), with the rest of the domain being composed of FDM grids. In the DEM domain, contact parameters of particles were calibrated via a series of large-scale triaxial test analyses. The model simulated tunnelling as the TBM operational conditions were controlled. The penetration rate and the rotational speed of the screw conveyor were automatically adjusted as the TBM advanced to prevent the generation of excessive or insufficient torque, thrust force, or chamber pressure. Accordingly, these parameters were maintained consistently around their set operational ranges during excavation. The simulation results show that the proposed numerical model based on DEM–FDM coupling could reasonably simulate EPB driving while considering the TBM operational conditions.

Surveillance Models of Large-Scale ESP With High Viscosity Fluids and Gas

2012 ◽  
Author(s):  
Lissett Barrios ◽  
Stuart Scott ◽  
Charles Deuel
Keyword(s):  
Large Scale ◽  
Two Phase Flow ◽  
Electrical Current ◽  
High Viscosity ◽  
Viscous Fluids ◽  
Phase Flow ◽  
Centrifugal Pumps ◽  
Operational Parameters ◽  
Two Phase ◽  
Operational Conditions

The paper reports on developmental research on the effects of viscosity and two phases, liquid–gas fluids on ESPs which are multi stage centrifugal pumps for deep bore holes. Multiphase viscous performance in a full-scale Electrical Submersible Pump (ESP) system at Shell’s Gasmer facility has been studied experimentally and theoretically. The main objectives is to predict the operational conditions that cause degradations for high viscosity fluids when operating in high Gas Liquid Radio (GLR) wells to support operation in Shell major Projects. The system studied was a 1025 series tandem WJE 1000. The test was performed using this configuration with ten or more pump stages moving fluids with viscosity from 2 to 200 cP at various speed, intake pressure and Gas Void Fractions (GVF). For safety considerations the injected gas was restricted to nitrogen or air. The ESP system is a central artificial lift method commonly used for medium to high flow rate wells. Multiphase flow and viscous fluids causes problems in pump applications. Viscous fluids and free gas inside an ESP can cause head degradation and gas locking. Substantial attempts have been made to model centrifugal pump performance under gas-liquid viscous applications, however due to the complexity this is still a uncertain problem. The determination of the two-phase flow performance in these harmful conditions in the ESP is fundamental aspects in the surveillance operation. The testing at Shell’s Gasmer facility revealed that the ESP system performed as theoretical over the range of single flowrates and light viscosity oils up to Gas Volume Fractions (GVF) around 25%. The developed correlations predict GVF at the pump intake based on the operational parameters. ESP performance degrades at viscosity higher than 100cp as compared to light oil applications, gas lock condition is observed at gas fraction higher than 45%. Pump flowrate can be obtained from electrical current and boost for all range of GVF and speed. The main technical contributions are the analysis of pump head degradation under two important variables, high viscosity and two-phase flow inside the ESP.

MO-Theoretical Studies on a Model Complex for Deoxymyoglobin

1998 ◽  
Vol 53 (9) ◽  
pp. 755-765
Author(s):  
Christian Kollma ◽  
Sighart F. Fischer ◽  
Michael C. Böhm
Keyword(s):  
High Spin ◽  
Ground State ◽  
High Spin State ◽  
Open Shell ◽  
Spin States ◽  
Hartree Fock ◽  
Intermediate Spin ◽  
Model Complex ◽  
Out Of Plane ◽  
Overlap Method

AbstractThe origin of the displacement of the Fe atom in deoxymyoglobin with respect to the porphyrin plane in the high-spin state is examined by a qualitative molecular orbital (MO) analysis on the extended Hückel level. We find that attachment of a fifth ligand (imidazole in our model complex) to Fe(II)porphyrin favors the out-of-plane shift due to a strengthening of the bonding interaction between Fe and the nitrogen of the imidazole ligand. This results in a high-spin (5 = 2) ground state with Fe shifted out-of-plane for the five-coordinate complex instead of an intermediate spin ground state (5 = 1) with Fe lying in the plane for four-coordinate Fe(II)porphyrin. The relative energies of the different spin states as a function of the distance between Fe and the porphyrin plane are evaluated using an ROHF (restricted open shell Hartree-Fock) version of an INDO (intermediate neglect of differential overlap) method. We observe a level crossing between high-spin and intermediate spin states whereas the low-spin (5 = 0) state remains always higher in energy.

scholarly journals Operational modifications for the development of nitrifying bacteria in a large-scale biological aerated filter and its impact on wastewater treatment

2018 ◽  
Vol 78 (8) ◽  
pp. 1704-1714 ◽  
Author(s):  
François-René Bourgeois ◽  
Frédéric Monette ◽  
Daniel G. Cyr
Keyword(s):  
Large Scale ◽  
Oxygen Demand ◽  
Bacterial Biofilm ◽  
Nitrifying Bacteria ◽  
Nitrification Rate ◽  
Total Biomass ◽  
Ammonia Oxidizing Bacteria ◽  
Operational Conditions ◽  
Nitrite Oxidizing Bacteria ◽  
Aerated Filter

Abstract To develop a better understanding for fixed biomass processes, the development of a nitrifying bacterial biofilm, as well as the performance of treatment during modifications to operational conditions of a full-scale submerged biological filter were examined. The development of the nitrifying biofilm was investigated at four depth levels (1, 2, 4 and 5 feet). The result of bacterial subpopulations analyzed by qPCR relative to the physico-chemical parameters of the wastewater during the various tests (sustained aeration, modified backwash parameters and inflow restriction) revealed an increase of the relative presence of nitrifying microorganisms throughout the biofilm (especially for nitrite oxidizing bacteria (NOB)), but this was not necessarily accompanied by a better nitrification rate. The highest observed nitrification rate was 49% of removal in the test cell during backwashing conditions, whereas the relative ammonia oxidizing bacteria (AOB) population was 0.032% and NOB was 0.008% of the total biomass collected. The highest percentage of nitrifying bacteria observed (0.034% AOB and 0.18% NOB) resulted in a nitrification rate of 21%. The treatment of organic matter determined by measuring the chemical and biochemical oxygen demand (COD, CBOD5) was improved.

Analysis of a Large-Scale Cooling System Fan Gearbox Loads

2017 ◽  
Author(s):  
Charles H. O. Lombard ◽  
Daniel N. J. Els ◽  
Jacques Muiyser ◽  
Albert Zapke
Keyword(s):  
Large Scale ◽  
Cooling System ◽  
Axial Flow ◽  
Output Shaft ◽  
Blade Loading ◽  
Operational Conditions ◽  
Power Stations ◽  
Reverse Loading ◽  
Air Cooled Condensers ◽  
Input Side

South Africa’s coal-fired power stations use super heated steam to drive generator turbines. In arid regions, air-cooled condensers (ACCs) are used to condense the process steam. These ACCs consists of an array of over 200 axial flow fans, each driven by a motor via a reduction gearbox. Distorted fan inlet air flow conditions cause transient blade loading, which results in variations in output shaft bending and torque. A measurement project was conducted where the input and output shaft of such a gearbox were instrumented with strain gauges and wireless bridge amplifiers. Gearbox shaft speed and vibration were also measured. Torsional and bending strains were measured for a variety of operational conditions, where correlations were seen between gearbox loading and wind conditions. The input side experienced no unexpected loads from the motor or changing wind conditions, whereas output shaft loading was influenced by the latter. Digital filters were applied to identify specific bending components, such as the influence of fan hub misalignment and dynamic blade loading. Reverse loading of the gearbox was measured during the fan stop period, and vibration analysis revealed torsional and gearbox vibrations. This investigation documented reliable full scale ACC gearbox loads.

scholarly journals Deploying Low Carbon Public Procurement to Accelerate Carbon Removal

2021 ◽  
Vol 3 ◽  
Author(s):  
Eric Dunford ◽  
Robert Niven ◽  
Christopher Neidl
Keyword(s):  
Carbon Dioxide ◽  
Carbon Capture ◽  
Large Scale ◽  
Carbon Materials ◽  
Public Procurement ◽  
Emerging Technology ◽  
Regulatory Environment ◽  
Low Carbon ◽  
Procurement Strategies ◽  
And Storage

Carbon dioxide removal (CDR) will be required to keep global temperature rise below 2°C based on IPCC models. Greater adoption of carbon capture utilization and storage (CCUS) technologies will drive demand for CDR. Public procurement of low carbon materials is a powerful and under-utilized tool for accelerating the development and of CCUS through a targeted and well-regulated approach. The policy environment is nascent and presents significant barriers for scaling and guiding emerging technology solutions. The concrete sector has unique attributes that make it ideally suited for large-scale low-carbon public procurement strategies. This sector offers immediate opportunities to study the efficacy of a supportive policy and regulatory environment in driving the growth of CCUS solutions.

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