scholarly journals Machine learning assisted optimization of blending process of polyphenylene sulfide with elastomer using high speed twin screw extruder

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Shingo Takada ◽  
Toru Suzuki ◽  
Yoshihiro Takebayashi ◽  
Takumi Ono ◽  
Satoshi Yoda
Keyword(s):  
Impact Strength ◽  
High Speed ◽  
Particle Diameter ◽  
Charpy Impact ◽  
Polyphenylene Sulfide ◽  
Training Dataset ◽  
Melt Viscosity ◽  
Screw Speed ◽  
Blending Process ◽  
The Impact

AbstractRandom forest regression was applied to optimize the melt-blending process of polyphenylene sulfide (PPS) with poly(ethylene-glycidyl methacrylate-methyl acrylate) (E-GMA-MA) elastomer to improve the Charpy impact strength. A training dataset was constructed using four elastomers with different GMA and MA contents by varying the elastomer content up to 20 wt% and the screw rotation speed of the extruder up to 5000 rpm at a fixed barrel temperature of 300 °C. Besides the controlled parameters, the following measured parameters were incorporated into the descriptors for the regression: motor torque, polymer pressure, and polymer temperatures monitored by infrared-ray thermometers installed at four positions (T1 to T4) as well as the melt viscosity and elastomer particle diameter of the product. The regression without prior knowledge revealed that the polymer temperature T1 just after the first kneading block is an important parameter next to the elastomer content. High impact strength required high elastomer content and T1 below 320 °C. The polymer temperature T1 was much higher than the barrel temperature and increased with the screw speed due to the heat of shear. The overheating caused thermal degradation, leading to a decrease in the melt viscosity and an increase in the particle diameter at high screw speed. We thus reduced the barrel temperature to keep T1 around 310 °C. This increased the impact strength from 58.6 kJ m−2 as the maximum in the training dataset to 65.3 and 69.0 kJ m−2 at elastomer contents of 20 and 30 wt%, respectively.

The Effect of Chitosan Addition in Acrylic Resin Matrix towards the Residual Monomers and Impact Strength

2021 ◽  
pp. 2280-2285
Author(s):  
Titik Ismiyati ◽  
Ananto Ali Alhasyimi
Keyword(s):  
Acrylic Acid ◽  
Impact Strength ◽  
Charpy Impact ◽  
Acrylic Resin ◽  
Test Sample ◽  
Acid Group ◽  
Resin Matrix ◽  
Residual Monomer ◽  
Group 2 ◽  
The Impact

Background: A residual monomer might have impact on the quality of acrylic resin since its caused allergic reactions and inflammation. Chitosan is a biocompatible material and potential to reduce residual monomers and ameliorate the impact strength of acrylic resin Objective of the study: To examine the effect of an acrylic resin matrix mixed with chitosan together with 1% and 2% acrylic acid as denture base and orthodontic material on residual monomers and impact strength. Methodology: There were 30 samples for the test analysis. The impact strength test sample formed with a plate size of 55 × 10 × 10mm, whereas the residual monomer test sample was prepared into powder. The test samples were divided into 3 groups, of 10 samples. Group 1 acrylic resin only, group 2 acrylic resin matrix mixed with chitosan and 1% acrylic acid, group 3 is the same as group 2 but with a concentration of 2% acrylic acid. Gas chromatography was used for measuring the residual monomers. The impact strength was tested by the Charpy impact. The data was evaluated using the ANOVA and correlation test. Results: There were significant differences (p < 0.05) in acrylic resin without addition with the matrix of acrylic resin with chitosan and acrylic acid 1% and 2% to the number of monomers and impact strength. Conclusion: The mixture of acrylic resin with chitosan and acrylic acid 1% and 2% can reduce the amount of residual monomer and increase the impact strength.

scholarly journals The Effect of Crystallinity on the Toughness of Cast Polyamide 6 Rods with Different Diameters

Polymers ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 293
Author(s):  
Miklós Odrobina ◽  
Tamás Deák ◽  
László Székely ◽  
Tamás Mankovits ◽  
Róbert Zsolt Keresztes ◽  
...  
Keyword(s):  
Impact Strength ◽  
Impact Test ◽  
Charpy Impact ◽  
Polyamide 6 ◽  
Degree Of Crystallinity ◽  
Scanning Calorimetry ◽  
Tensile Impact ◽  
Different Diameters ◽  
The Impact ◽  
The Degree Of Crystallinity

The present paper concentrates on the toughness and the degree of crystallinity of the magnesium-catalyzed polyamide 6 rods cast in different diametres, which are commonly used for gear manufacturing. Its toughness cannot be regarded as a constant feature due to the casting technology. The mechanical properties of the semi-finished products are sensitive to the manufactured dimension, e.g., cast diameter, which are investigated by the Charpy impact test and tensile impact test. It is generally accepted that the impact strength and tensile-impact strength correlate with the degree of crystallinity beside many other material’s feature. Crystallinity is evaluated by Differential Scanning Calorimetry. The aim of this study is to determine the relationship between toughness and crystallinity of the magnesium-catalyzed cast PA6 rods with different diameters. For the research cast rods between 40 and 300 mm diameter were selected in seven-dimensional steps. Based on the results, it was found that the toughness depends strongly on the diameter size. Furthermore, it is proved that the crystallinity explains 62.3% of the variation of the Charpy’s impact strengths, while the tensile impact method was not suitable to detect the difference between the test samples.

Structure-property relationship of biodegradable poly(butylene succinate)/polycaprolactone coated inorganic particle composites

2013 ◽  
Vol 33 (2) ◽  
pp. 111-119
Author(s):  
Yiming Liu ◽  
Qing Liu ◽  
Bing Meng ◽  
Zhihua Wu
Keyword(s):  
Impact Strength ◽  
High Speed ◽  
Complex Viscosity ◽  
Structure Property ◽  
Scanning Calorimetry ◽  
Butylene Succinate ◽  
Elongation At Break ◽  
Inorganic Particle ◽  
Biodegradable Poly ◽  
The Impact

Abstract Polycaprolactone (PCL)-coated micro kaolin and nano-titania were prepared by high-speed hybrid mechanical coating. Poly(butylene succinate) (PBS)-coated inorganic particle composites were prepared by the melt-blending process. The influence of coated kaolin microparticles on the dynamic rheological behavior, non-isothermal crystallization behavior, micromorphology, and mechanical behavior were investigated. The effect of coated nano-titania on the mechanical properties of PBS-coated kaolin composites was also studied. A dynamic rheological property indicates that the complex viscosity of PBS-coated kaolin microcomposites is higher than neat PBS. Differential scanning calorimetry (DSC) implies that the micrometric size of kaolin particles restrains the crystallization of PBS. Scanning electronic microscopy (SEM) reveals a well dispersed state of coated kaolin in the polymer matrix. The impact strength of PBS-coated kaolin microcomposites is improved, while the tensile strength and elongation at break is decreased, but still appreciable. The introduction of coated nano-titania improves the impact strength dramatically, and the elongation at break of composites is considerable.

Study on the effect of processing conditions on the impact strength of PP/SEBS/PC ternary blends using Taguchi experimental analysis

2011 ◽  
Vol 31 (2-3) ◽  
Author(s):  
Omid Moini Jazani ◽  
Ahmad Arefazar ◽  
Seyyed Hassan Jafari ◽  
Mohammad Reza Saeb
Keyword(s):  
Impact Strength ◽  
Processing Condition ◽  
Point Of View ◽  
Interactive Effects ◽  
Processing Conditions ◽  
Ternary Blends ◽  
Screw Speed ◽  
Die Temperature ◽  
Blending Sequence ◽  
The Impact

Abstract In this study, nine ternary blends of polypropylene (PP)/poly [styrene-b-(ethylene-co butylene)-b-styrene] tri-block copolymer (SEBS)/polycarbonate (PC) were produced at different processing conditions through twin screw extruder. Accordingly, die temperature, screw speed, and blending sequences were altered based on L9 Taguchi experimental design as indications of processing variables. Consequently, the impact strength of each produced sample is considered as the responding variable. Analyzing two important aspects, namely main and interactive effects by using Taguchi analysis, was the especial point of view in our contribution; as a result, not only was the PP/SEBS/PC ternary system studied for the first time, but the SEBS-g-MAH compatibilizer also showed sufficient effects on morphology development. It was observed that the impact strength of PP/SEBS/PC ternary blends is not affected by die temperature significantly, whereas screw speed and blending sequence have had effective impacts. Besides, the optimum processing condition, which is proportional to the highest value of impact strength, is recommended through the mentioned ternary blends. These results are also confirmed while applying image analysis on morphology micrographs.

Comparison of Mechanical and Frictional Properties of PTFE Matrix Composites Reinforced by Different Fibers and Graphite

2013 ◽  
Vol 575-576 ◽  
pp. 203-208
Author(s):  
Hong Xing Xu ◽  
Xin Hua Yuan ◽  
En Bo Zhu ◽  
Shuang Lian Li ◽  
Ling Chen ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Impact Strength ◽  
Tribological Properties ◽  
Polyphenylene Sulfide ◽  
Matrix Composites ◽  
Load Bearing Capacity ◽  
Elongation At Break ◽  
Frictional Properties ◽  
Mass Fractions ◽  
The Impact

The polytetrafluoroethylene (PTFE) matrix composites which filled with polyphenylene sulfide (PPS) fiber, poly-p-phenelenferephthalamide (PPTA) fibre or glass fiber (GF)) and graphite at various mass fractions were prepared by the processes of mechanical blending, compression molding and sintering. The mechanical properties of the composites, such as tensile strength, impact strength and hardness were investigated. The results show that tensile strength and elongation at break markedly decrease but elasticity increases by filling with fibers. Impact strength decreases by filling with PPS and GF, and the composite displays brittle characteristic. However, the impact strength rapidly increases by filling with PPTA fiber. Hardness increases with the fibers content increases, and decreases with graphite content increases. Filling graphite into PTFE has light effect on the impact and tensile strength of composites. The tribological properties of the composites were investigated on M-2000 wear tester at dry friction condition. The wear mechanism was also discussed and the wear surfaces were examined by SEM. The result indicates that fibers which diffused in PTFE matrix wind with PTFE molecule chain, and then form grid structure. The load-bearing capacity of composites can be obviously enhanced and the trend of block fragmentations slide is inhibited, so that the tribological properties are improved markedly.

scholarly journals An Experimental Study on the Effect of Nanomaterials and Fibers on the Mechanical Properties of Polymer Composites

Buildings ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 7
Author(s):  
Chanachai Thongchom ◽  
Nima Refahati ◽  
Pouyan Roodgar Saffari ◽  
Peyman Roudgar Saffari ◽  
Meysam Nouri Niyaraki ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Impact Strength ◽  
Modulus Of Elasticity ◽  
Graphene Nanosheets ◽  
Charpy Impact ◽  
Tensile Tests ◽  
Basalt Fibers ◽  
Low Weight ◽  
Internal Mixer ◽  
The Impact

This study aims to explore the tensile and impact properties (tensile strength, modulus of elasticity, and impact strength) of polypropylene (PP)-based nanocomposites reinforced with graphene nanosheets, nanoclay, and basalt fibers. The response surface methodology (RSM) with Box–Behnken design (BBD) was adopted as the experimental design. An internal mixer was used to prepare compounds consisting of 0, 0.75 and 1.5 wt% graphene nanosheets, 0, 10 and 20 wt% basalt fibers, and 0, 3 and 6 wt% nanoclay. The samples were prepared by a hot press machine for mechanical testing. The tensile tests were run to determine the tensile strength, and modulus of elasticity, and the Charpy impact tests were performed to assess the impact strength. It was found that the addition of basalt increased the tensile strength, modulus of elasticity, and impact strength by 32%, 64% and 18%, respectively. Also, the incorporation of the low-weight graphene nanosheets increased the tensile and impact strength by 15% and 20%, respectively, Adding graphene nanosheets generally improved the modulus of elasticity by 66%. Similarly, the addition of nanoclay improved the tensile strength by 17% and increased the modulus of elasticity by 59%, but further addition of it decreased the impact strength by 19%. The values obtained by this experiment for the mechanical property were roughly close to the data yielded from desirability optimization.

Study on the Thermal and Rheological Properties of Reactive Blending PC/PLA/EVA Blends

2011 ◽  
Vol 79 ◽  
pp. 282-287 ◽  
Author(s):  
Yi Chen ◽  
Guang Sheng Zeng ◽  
Ping Jiang ◽  
Wei Lu ◽  
Wei Long Huang
Keyword(s):  
Thermal Stability ◽  
Thermal Properties ◽  
Impact Strength ◽  
Rheological Properties ◽  
Apparent Viscosity ◽  
Melt Blending ◽  
Reactive Blending ◽  
Blending Process ◽  
The Impact ◽  
Thermal Stability Of

EVA was added into PC/PLA blends as a modifier for improving the impact strength of blends, and meanwhile the thermal properties and rheological properties of blends should also be influenced. PC/PLA/EVA blends were prepared by melt blending and the catalyst DBTO was added into the blends in blending process to catalyze the transesterification of PC and EVA for improving the compatibility of blends. The effects of blend composition and transesterification on the thermal and rheological properties of blends were investigated. The results showed that the addition of EVA could improve the crystallinity of PLA in PC/PLA/EVA blends but had little influence on the thermal stability of blends,and the transesterification was beneficial to both the crystallization of PLA and thermal stability of blends. The addition of EVA and the transesterification of PC and EVA increased the apparent viscosity of blends, while the apparent viscosity of blends decreased drastically and the pseudo-plasticity characteristic of blend melts was weakened obviously with increasing PLA content and rising temperature.

A Method and Device for Testing Impact Resistance of Glassware

2015 ◽  
Vol 237 ◽  
pp. 154-159
Author(s):  
Szymon Zacharski ◽  
Wojciech Jóźwik
Keyword(s):  
Impact Strength ◽  
Research Laboratory ◽  
High Speed ◽  
Test Procedure ◽  
Impact Resistance ◽  
Digital Camera ◽  
Industrial Research ◽  
Different Types ◽  
Pharmaceutical Industries ◽  
The Impact

Currently, nearly 1.5 M tons of different types of glassware are produced in Poland, and the majority of it is used as packaging in the food, cosmetic, and pharmaceutical industries. The article presents a method for testing impact resistance of glassware, which was developed at the ITeE-PIB. The authors also present a prototype of a device for glassware tests, discuss a test procedure applied in such tests, and show the results of verification tests for which a high-speed digital camera was used to record the impact strength and the propagation of cracks in glassware. The device in question has been successfully implemented in an industrial research laboratory.

Dispersion and Impact Strength of Epoxy Resin/Nano-Al2O3 Composites

2013 ◽  
Vol 761 ◽  
pp. 161-164 ◽  
Author(s):  
Nai Kui Gao ◽  
Zhou Xu ◽  
Chun Wu ◽  
Rui Hua Li ◽  
Hai Yun Jin
Keyword(s):  
Impact Strength ◽  
Epoxy Resin ◽  
Surface State ◽  
Coupling Agent ◽  
High Speed ◽  
Impact Property ◽  
Al2o3 Content ◽  
Shear Dispersion ◽  
The Impact ◽  
Agent Treatment

This paper focuses on the influence of nano-Al2O3 surface state and composite process on the dispersion of nano-Al2O3 filler. Toughening was performed to epoxy resin by nano-Al2O3, and the effect of impact property of epoxy resin/nano-Al2O3 composites was studied. The results showed that coupling agent treatment and high-speed shear dispersion can improve many properties of the composites. With nano-Al2O3 content increasing, the impact strength of the composites increased at first and then decreased. The maximum appears when the nano-Al2O3 content reached 3wt. %, no matter with or without the coupling agent treatment, which is 87.4% and 78.6% higher than that of monolithic epoxy resin respectively. The coupling agent treatment of nano-Al2O3 helped to improve the impact strength of the composites.

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