scholarly journals An experimentally informed statistical elasto-plastic mineralised collagen fibre model at the micrometre and nanometre lengthscale

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Alexander Groetsch ◽  
Philippe K. Zysset ◽  
Peter Varga ◽  
Alexandra Pacureanu ◽  
Françoise Peyrin ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Self Assembly ◽  
Load Transfer ◽  
Collagen Fibre ◽  
High Strength ◽  
X Ray Scattering ◽  
Yield Behaviour ◽  
Nanoscale Imaging ◽  
Collagen Molecules ◽  
Inorganic Mineral

AbstractBone is an intriguingly complex material. It combines high strength, toughness and lightweight via an elaborate hierarchical structure. This structure results from a biologically driven self-assembly and self-organisation, and leads to different deformation mechanisms along the length scales. Characterising multiscale bone mechanics is fundamental to better understand these mechanisms including changes due to bone-related diseases. It also guides us in the design of new bio-inspired materials. A key-gap in understanding bone’s behaviour exists for its fundamental mechanical unit, the mineralised collagen fibre, a composite of organic collagen molecules and inorganic mineral nanocrystals. Here, we report an experimentally informed statistical elasto-plastic model to explain the fibre behaviour including the nanoscale interplay and load transfer with its main mechanical components. We utilise data from synchrotron nanoscale imaging, and combined micropillar compression and synchrotron X-ray scattering to develop the model. We see that a 10-15% micro- and nanomechanical heterogeneity in mechanical properties is essential to promote the ductile microscale behaviour preventing an abrupt overall failure even when individual fibrils have failed. We see that mineral particles take up 45% of strain compared to collagen molecules while interfibrillar shearing seems to enable the ductile post-yield behaviour. Our results suggest that a change in mineralisation and fibril-to-matrix interaction leads to different mechanical properties among mineralised tissues. Our model operates at crystalline-, molecular- and continuum-levels and sheds light on the micro- and nanoscale deformation of fibril-matrix reinforced composites.

scholarly journals Microstructural Changes of Aramid Fiber Due to Reaction with Toluene 2,4-diisocyanate under Tension in scCO2

Polymers ◽  
2019 ◽  
Vol 11 (7) ◽  
pp. 1110 ◽  
Author(s):  
Haijuan Kong ◽  
Qian Xu ◽  
Muhuo Yu
Keyword(s):  
Mechanical Properties ◽  
High Temperature ◽  
High Strength ◽  
Amorphous Region ◽  
Aramid Fiber ◽  
Crosslinking Reaction ◽  
X Ray Scattering ◽  
Rigid Molecule ◽  
Rigid Segment ◽  
Orientation Structure

High modulus aramid fiber, such as Kevlar 49, is conventionally prepared by the heat annealing of high strength aramid fiber under a suitable tension at high temperature, especially higher than 500 °C. This enables the mobility of a rigid molecule chain to be rearranged into a more perfect crystalline or orientation structure under tension. However, annealing decreases the tensile strength, since the thermal degradation of the molecular chain at high temperature cannot be avoided. Kevlar 49 fibers treated in supercritical carbon dioxide (scCO2) under tension could improve their mechanical properties at a low temperature. The effects of the tension on the mechanical properties and structure of the Kevlar 49 fibers were studied by mechanical testing, wide-angle and small-angle X-ray scattering (WAXS, SAXS), and scanning electron microscopy (SEM). The results show that the mechanical properties, crystallinity and orientation of the fiber can be improved when the tension is less than 0.6 cN/dtex, which may be due to the increasing of the mobility of a rigid segment with the help of the plasticization of scCO2 and re-arrangement of macromolecular chain into crystalline and orientation structure under tension. What’s more, the amorphous region also was enhanced by crosslinking reaction of toluene 2,4-diisocyanate (TDI) with the chain end groups of the macromolecules in the amorphous regions. However, a decrease of tenacity was found when the tension was higher than 0.6 cN/dtex, which is because the tension was so high that the microfibril was broken. The results indicated that treating the Kevlar 49 fiber in scCO2 under a suitable tension with TDI as a crosslink agent can simultaneously improve both the tenacity and modulus of the fiber.

scholarly journals Effect of the Application of a Dehydrothermal Treatment on the Structure and the Mechanical Properties of Collagen Film

Materials ◽  
2020 ◽  
Vol 13 (2) ◽  
pp. 377 ◽  
Author(s):  
Xuefei Chen ◽  
Lingling Zhou ◽  
Huaizhong Xu ◽  
Masaki Yamamoto ◽  
Masaya Shinoda ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Self Assembly ◽  
Triple Helix ◽  
Treatment Time ◽  
Covalent Bond ◽  
Crosslinking Density ◽  
Treatment Temperature ◽  
Collagen Film ◽  
Helix Structure ◽  
Collagen Molecules

Dehydrothermal (DHT) treatment was used to improve the properties of collagen casings because of its non-cytotoxicity. Understanding the effects of DHT treatment on the structure and mechanical properties of collagen films is beneficial to developing satisfying collagen casings. Herein, DHT treatment with various temperatures (85–145 °C) and timescales (1–7 days) were investigated. It was clarified that the chemical crosslinking covalent bond between collagen molecules was formed after the DHT treatment. Crosslinking density increased with increasing DHT treatment temperatures, contributing to the increase of tensile strength up to over three times of that of the untreated collagen film. The increased crosslinking density was also found when increasing the DHT treatment time, and the maximum was obtained in 3 days. Further DHT treatment time did not change the crosslinking density. The damage in the triple helix structure and the self-assembly of collagen molecules were observed from IR and SAXS. The extent of denaturation increased with increasing DHT treatment temperature and time, although the effect of the DHT treatment time on the denaturation was more moderate. When the DHT treatment temperature was as high as 145 °C or the DHT treatment time exceeded 5 days, serious denaturation occurs, leading to the deterioration of mechanical properties.

scholarly journals Tailoring nanocomposite interfaces with graphene to achieve high strength and toughness

2020 ◽  
Vol 6 (42) ◽  
pp. eaba7016
Author(s):  
Ningning Song ◽  
Zan Gao ◽  
Xiaodong Li
Keyword(s):  
Self Assembly ◽  
Load Transfer ◽  
Low Cost ◽  
High Strength ◽  
Transfer Efficiency ◽  
Assembly Mechanism ◽  
Shear Mixing ◽  
Load Transfer Efficiency ◽  
Predicted Values ◽  
Dynamics Simulations

The nanofiller reinforcing effect in nanocomposites is often far below the theoretically predicted values, largely because of the poor interfacial interaction between the nanofillers and matrix. Here, we report that graphene-wrapped B4C nanowires (B4C-NWs@graphene) empowered exceptional dispersion of nanowires in matrix and superlative nanowire-matrix bonding. The 0.2 volume % B4C-NWs@graphene reinforced epoxy composite exhibited simultaneous enhancements in strength (144.2 MPa), elastic modulus (3.5 GPa), and ductility (15%). Tailoring the composite interfaces with graphene enabled effective utilization of the nanofillers, resulting in two times increase in load transfer efficiency. Molecular dynamics simulations unlocked the shear mixing graphene/nanowire self-assembly mechanism. This low-cost yet effective technique presents unprecedented opportunities for improving nanocomposite interfaces, enabling high load transfer efficiency, and opens up a new path for developing strong and tough nanocomposites.

Effects of cooling rate on the mechanical properties of dual phase treated vanadium steels

1983 ◽  
Vol 41 ◽  
pp. 220-221
Author(s):  
L.J. Chen ◽  
H.C. Cheng ◽  
J.R. Gong ◽  
J.G. Yang
Keyword(s):  
Mechanical Properties ◽  
Cooling Rate ◽  
Automobile Industry ◽  
High Strength ◽  
Weight Percent ◽  
Low Alloy Steels ◽  
Dual Phase ◽  
Resource Requirement ◽  
Alloy Steels ◽  
Potential Weight

For fuel savings as well as energy and resource requirement, high strength low alloy steels (HSLA) are of particular interest to automobile industry because of the potential weight reduction which can be achieved by using thinner section of these steels to carry the same load and thus to improve the fuel mileage. Dual phase treatment has been utilized to obtain superior strength and ductility combinations compared to the HSLA of identical composition. Recently, cooling rate following heat treatment was found to be important to the tensile properties of the dual phase steels. In this paper, we report the results of the investigation of cooling rate on the microstructures and mechanical properties of several vanadium HSLA steels.The steels with composition (in weight percent) listed below were supplied by China Steel Corporation: 1. low V steel (0.11C, 0.65Si, 1.63Mn, 0.015P, 0.008S, 0.084Aℓ, 0.004V), 2. 0.059V steel (0.13C, 0.62S1, 1.59Mn, 0.012P, 0.008S, 0.065Aℓ, 0.059V), 3. 0.10V steel (0.11C, 0.58Si, 1.58Mn, 0.017P, 0.008S, 0.068Aℓ, 0.10V).

In situ Time-Resolved Small-Angle X-ray Scattering Reveals the Formation Kinetics of Polyelectrolyte Complex Micelles

2019 ◽  
Author(s):  
Hao Wu ◽  
Jeffrey Ting ◽  
Siqi Meng ◽  
Matthew Tirrell
Keyword(s):  
Small Angle ◽  
Self Assembly ◽  
Electrostatic Interactions ◽  
Polyelectrolyte Complex ◽  
Time Resolved ◽  
X Ray ◽  
X Ray Scattering ◽  
Kinetics Of ◽  
Ray Scattering

We have directly observed the <i>in situ</i> self-assembly kinetics of polyelectrolyte complex (PEC) micelles by synchrotron time-resolved small-angle X-ray scattering, equipped with a stopped-flow device that provides millisecond temporal resolution. This work has elucidated one general kinetic pathway for the process of PEC micelle formation, which provides useful physical insights for increasing our fundamental understanding of complexation and self-assembly dynamics driven by electrostatic interactions that occur on ultrafast timescales.

CARLSON ALLOY C600 and C600 ESR

Alloy Digest ◽  
1994 ◽  
Vol 43 (11) ◽  
Keyword(s):  
Mechanical Properties ◽  
Solid Solution ◽  
Fracture Toughness ◽  
Cold Working ◽  
Elevated Temperatures ◽  
High Strength ◽  
Heat Treating ◽  
Solid Solution Alloy ◽  
Resistance To Oxidation ◽  
Good Workability

Abstract CARLSON ALLOYS C600 AND C600 ESR have excellent mechanical properties from sub-zero to elevated temperatures with excellent resistance to oxidation at high temperatures. It is a solid-solution alloy that can be hardened only by cold working. High strength at temperature is combined with good workability. This datasheet provides information on composition, physical properties, elasticity, and tensile properties as well as fracture toughness. It also includes information on corrosion resistance as well as forming, heat treating, and machining. Filing Code: Ni-470. Producer or source: G.O. Carlson Inc.

BERYLCO NICKEL ALLOY 440

Alloy Digest ◽  
1975 ◽  
Vol 24 (9) ◽  
Keyword(s):  
Mechanical Properties ◽  
High Temperature ◽  
Nickel Alloy ◽  
High Strength ◽  
Heat Treating ◽  
Electronic Components ◽  
High Temperature Mechanical Properties ◽  
Temperature Performance ◽  
Solution Treated ◽  
Complex Shapes

Abstract BERYLCO NICKEL ALLOY 440 is an age-hardenable nickel-beryllium-titanium alloy that offers high strength, excellent spring properties outstanding formability, good high-temperature mechanical properties, and resistance to corrosion and fatigue. Complex shapes can be produced in the solution-treated (soft) condition and then aged to a minimum tensile strength of 215,500 psi. It is used for mechanical and electrical/electronic components in the temperature range -320 to 800 F. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as fracture toughness. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, machining, joining, and surface treatment. Filing Code: Ni-94. Producer or source: Kawecki Berylco Industries Inc.. Originally published September 1964, revised September 1975.

UNS A97075

Alloy Digest ◽  
1986 ◽  
Vol 35 (7) ◽  
Keyword(s):  
Mechanical Properties ◽  
Heat Treatment ◽  
Aluminum Alloy ◽  
High Strength ◽  
Heat Treating ◽  
Good Resistance ◽  
Temperature Performance ◽  
Structural Applications ◽  
Structural Parts ◽  
Very High

Abstract UNS No. A97075 is a wrought precipitation-hardenable aluminum alloy. It has excellent mechanical properties, workability and response to heat treatment and refrigeration. Its typical uses comprise aircraft structural parts and other highly stressed structural applications where very high strength and good resistance to corrosion are required. This datasheet provides information on composition, physical properties, hardness, elasticity, tensile properties, and shear strength as well as fatigue. It also includes information on low temperature performance as well as forming, heat treating, and machining. Filing Code: Al-269. Producer or source: Various aluminum companies.

JESSOP JS600

Alloy Digest ◽  
1983 ◽  
Vol 32 (6) ◽  
Keyword(s):  
Mechanical Properties ◽  
Corrosion Resistance ◽  
Food Processing ◽  
Iron Alloy ◽  
High Strength ◽  
Heat Treating ◽  
Steel Company ◽  
Nickel Chromium ◽  
Good Workability ◽  
Resistance To Heat

Abstract JESSOP JS600 is a nickel-chromium-iron alloy for use in environments requiring resistance to heat and/or corrosion. It has excellent mechanical properties and a combination of high strength and good workability. It performs well in applications with temperatures from cryogenic to more than 2000 F. Its many applications include aircraft/aerospace components, equipment for chemical and food processing and parts for heat-treating equipment. This datasheet provides information on composition, physical properties, elasticity, and tensile properties. It also includes information on corrosion resistance as well as forming, heat treating, machining, joining, and surface treatment. Filing Code: Ni-287. Producer or source: Jessop Steel Company.

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