Computational electrochemistry: prediction of liquid-phase reduction potentials

2014 ◽  
Vol 16 (29) ◽  
pp. 15068-15106 ◽  
Author(s):  
Aleksandr V. Marenich ◽  
Junming Ho ◽  
Michelle L. Coote ◽  
Christopher J. Cramer ◽  
Donald G. Truhlar
Keyword(s):  
Liquid Phase ◽  
Chemical Reactions ◽  
Reduction Potentials ◽  
Phase Reduction ◽  
Computational Electrochemistry ◽  
Recent Developments

The article reviews recent developments and applications for predicting the standard reduction potentials of chemical reactions in solution.

scholarly journals A Review on Recent Progress of Glycan-Based Surfactant Micelles as Nanoreactor Systems for Chemical Synthesis Applications

2021 ◽  
Vol 2 (1) ◽  
pp. 168-186
Author(s):  
Bahareh Vafakish ◽  
Lee D. Wilson
Keyword(s):  
Chemical Synthesis ◽  
Chemical Reactions ◽  
Recent Progress ◽  
Chemical Species ◽  
Reaction Rates ◽  
Bulk Solution ◽  
Surfactant Micelles ◽  
Conventional Surfactant ◽  
Recent Developments ◽  
To Receive

The nanoreactor concept and its application as a modality to carry out chemical reactions in confined and compartmentalized structures continues to receive increasing attention. Micelle-based nanoreactors derived from various classes of surfactant demonstrate outstanding potential for chemical synthesis. Polysaccharide (glycan-based) surfactants are an emerging class of biodegradable, non-toxic, and sustainable alternatives over conventional surfactant systems. The unique structure of glycan-based surfactants and their micellar structures provide a nanoenvironment that differs from that of the bulk solution, and supported by chemical reactions with uniquely different reaction rates and mechanisms. In this review, the aggregation of glycan-based surfactants to afford micelles and their utility for the synthesis of selected classes of reactions by the nanoreactor technique is discussed. Glycan-based surfactants are ecofriendly and promising surfactants over conventional synthetic analogues. This contribution aims to highlight recent developments in the field of glycan-based surfactants that are relevant to nanoreactors, along with future opportunities for research. In turn, coverage of research for glycan-based surfactants in nanoreactor assemblies with tailored volume and functionality is anticipated to motivate advanced research for the synthesis of diverse chemical species.

Multichannel gas-uptake/evolution reactor for monitoring liquid-phase chemical reactions

2021 ◽  
Vol 92 (4) ◽  
pp. 044103
Author(s):  
Chase A. Salazar ◽  
Blaise J. Thompson ◽  
Spring M. M. Knapp ◽  
Steven R. Myers ◽  
Shannon S. Stahl
Keyword(s):  
Liquid Phase ◽  
Chemical Reactions ◽  
Gas Uptake ◽  
Phase Chemical

scholarly journals Visible Light Photochemical Reactions for Nucleic Acid-Based Technologies

Molecules ◽  
2021 ◽  
Vol 26 (3) ◽  
pp. 556
Author(s):  
Bonwoo Koo ◽  
Haneul Yoo ◽  
Ho Jeong Choi ◽  
Min Kim ◽  
Cheoljae Kim ◽  
...  
Keyword(s):  
Nucleic Acid ◽  
Nucleic Acids ◽  
Visible Light ◽  
Chemical Reactions ◽  
Chemical Biology ◽  
Photochemical Reactions ◽  
Reaction Conditions ◽  
Promising Tool ◽  
Recent Developments ◽  
Visible Light Driven

The expanding scope of chemical reactions applied to nucleic acids has diversified the design of nucleic acid-based technologies that are essential to medicinal chemistry and chemical biology. Among chemical reactions, visible light photochemical reaction is considered a promising tool that can be used for the manipulations of nucleic acids owing to its advantages, such as mild reaction conditions and ease of the reaction process. Of late, inspired by the development of visible light-absorbing molecules and photocatalysts, visible light-driven photochemical reactions have been used to conduct various molecular manipulations, such as the cleavage or ligation of nucleic acids and other molecules as well as the synthesis of functional molecules. In this review, we describe the recent developments (from 2010) in visible light photochemical reactions involving nucleic acids and their applications in the design of nucleic acid-based technologies including DNA photocleaving, DNA photoligation, nucleic acid sensors, the release of functional molecules, and DNA-encoded libraries.

Feasibility of improving the quality of dirty manganese ores in furnaces used for the liquid-phase reduction of iron

Metallurgist ◽  
1999 ◽  
Vol 43 (11) ◽  
pp. 473-477
Author(s):  
E. F. Vegman ◽  
S. E. Lazutkin ◽  
S. S. Lazutkin
Keyword(s):  
Liquid Phase ◽  
Manganese Ores ◽  
Phase Reduction ◽  
Reduction Of Iron

Preparation of nickel–silver core–shell nanoparticles by liquid-phase reduction for use in conductive paste

2015 ◽  
Vol 10 (17) ◽  
pp. 1347-1356 ◽  
Author(s):  
Jun Jie Jing ◽  
Jimin Xie ◽  
Gao Yuan Chen ◽  
Wen Hua Li ◽  
Ming Mei Zhang
Keyword(s):  
Liquid Phase ◽  
Core Shell ◽  
Shell Nanoparticles ◽  
Nickel Silver ◽  
Phase Reduction ◽  
Core Shell Nanoparticles ◽  
Silver Core

Questions, Controversies and Frustration in Quantum Antiferromagnetism

1991 ◽  
Vol 05 (01n02) ◽  
pp. 171-189 ◽  
Author(s):  
P. Chandra ◽  
P. Coleman ◽  
I. Ritchey
Keyword(s):  
Liquid Phase ◽  
Spin Liquid ◽  
Nematic State ◽  
Recent Developments

The search for a gapless spin liquid phase has raised many issues in quantum antiferromagnetism. Here we review recent developments in this field, and in particular address questions and controversies surrounding a proposed “spin nematic” state.

scholarly journals Liquid-phase exfoliated graphene: functionalization, characterization, and applications

2014 ◽  
Vol 5 ◽  
pp. 2328-2338 ◽  
Author(s):  
Mildred Quintana ◽  
Jesús Iván Tapia ◽  
Maurizio Prato
Keyword(s):  
Organic Chemistry ◽  
Liquid Phase ◽  
Chemical Reactions ◽  
Functional Materials ◽  
Atomic Plane ◽  
Graphene Sheets ◽  
Exfoliated Graphene ◽  
Graphene Functionalization ◽  
Chemical Strategies ◽  
Insight Into

The development of chemical strategies to render graphene viable for incorporation into devices is a great challenge. A promising approach is the production of stable graphene dispersions from the exfoliation of graphite in water and organic solvents. The challenges involve the production of a large quantity of graphene sheets with tailored distribution in thickness, size, and shape. In this review, we present some of the recent efforts towards the controlled production of graphene in dispersions. We also describe some of the chemical protocols that have provided insight into the vast organic chemistry of the single atomic plane of graphite. Controlled chemical reactions applied to graphene are expected to significantly improve the design of hierarchical, functional platforms, driving the inclusion of graphene into advanced functional materials forward.

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