Mussel-inspired synthesis of polydopamine-functionalized calcium carbonate as reusable adsorbents for heavy metal ions

RSC Advances ◽  
2014 ◽  
Vol 4 (88) ◽  
pp. 47848-47852 ◽  
Author(s):  
Chengyong Li ◽  
Zhong-ji Qian ◽  
Chunxia Zhou ◽  
Weiming Su ◽  
Pengzhi Hong ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Calcium Carbonate ◽  
Chemical Modification ◽  
Heavy Metal Ions ◽  
High Efficiency ◽  
Low Cost ◽  
High Adsorption ◽  
High Adsorption Capacity ◽  
Adsorption Desorption ◽  
Multiple Adsorption

A new high-efficiency adsorbent (PDA-CaCO3) is fabricated via simple thermal calcination ostracean shells and chemical modification with dopamine. It can be easily regenerated by low-cost reagents, and exhibited high adsorption capacity after multiple adsorption–desorption cycles.

Investigation of Zn2+ heavy metal handling ability by macadamite activated by H3PO4

2019 ◽  
pp. 125-132
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Activated Carbon ◽  
Adsorption Capacity ◽  
Carbon Material ◽  
High Efficiency ◽  
High Adsorption ◽  
Research Results ◽  
Activating Agent ◽  
High Adsorption Capacity

Investigate the possibility of treating wastewater containing heavy metals Zn2+ with activated carbon material prepared from macadamia shell with chemical activating agent H3PO4, showing high efficiency of adsorption of Zn2+. The results of the study showed that activated carbon with H3PO4 activating agent has high adsorption capacity, capable of handling Zn2+ best at pH = 4.5, dosage 1.8 g/L and time is 120 minutes. . The results show similarities with other research results and are capable of treating wastewater containing heavy metals Zn2+.

scholarly journals Preparation of PVDF/Hyperbranched-Nano-Palygorskite Composite Membrane for Efficient Removal of Heavy Metal Ions

Polymers ◽  
2019 ◽  
Vol 11 (1) ◽  
pp. 156 ◽  
Author(s):  
Xiaoye Zhang ◽  
Yingxi Qin ◽  
Guifang Zhang ◽  
Yiping Zhao ◽  
Chao Lv ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Metal Ions ◽  
Adsorption Capacity ◽  
Composite Membrane ◽  
Heavy Metal Ions ◽  
Thermo Gravimetric Analysis ◽  
Composite Membranes ◽  
Gravimetric Analysis ◽  
High Adsorption ◽  
High Adsorption Capacity

In this work, three kinds of hyperbranched polyamidoamine-palygorskite (PAMAM-Pal) were designed and synthesized by grafting the first generation polyamidoamine (G1.0 PAMAM), G2.0 PAMAM and G3.0 PAMAM onto Pal surfaces, respectively. Then, these PAMAM-Pals were used as additives to prepare polyvinylidene fluoride (PVDF)/hyperbranched polyamidoamine-palygorskite bicomponent composite membranes. The structures of the composite membranes were characterized by Fourier transform infrared spectroscopy (FTIR), thermo gravimetric analysis (TEM), X-ray photoelectron spectroscopy (XPS), field-emission scanning electronmicroscopy (SEM), atomic force microscope (AFM) and Thermogravimetric analysis (TGA). The adsorption properties of composite membranes to heavy metal ions was studied, and the results found that the maximum adsorption capacities for Cu(II), Ni(II) and Cd(II) could reach 155.19 mg/g, 124.28 mg/g and 125.55 mg/g, respectively, for the PVDF/G3.0 PAMAM-Pal membrane, while only 23.70 mg/g, 17.74 mg/g and 14.87 mg/g could be obtained for unmodified membranes in the same conditions. The high adsorption capacity can be ascribed to the large number of amine-terminated groups, amide groups and carbonyl groups of the composite membrane. The above results indicated that the prepared composite membrane has a high adsorption capacity for heavy metal ions removal in water treatment.

Preparation of amino-functionalized CoFe2O4@SiO2 magnetic nanocomposites for potential application in absorbing heavy metal ions

RSC Advances ◽  
2016 ◽  
Vol 6 (76) ◽  
pp. 72479-72486 ◽  
Author(s):  
Chunrong Ren ◽  
Xingeng Ding ◽  
Huiqin Fu ◽  
Cheng Meng ◽  
Wenqi Li ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Shell Structure ◽  
Potential Application ◽  
Heavy Metal Ions ◽  
Magnetic Nanocomposites ◽  
Core Shell ◽  
High Adsorption ◽  
High Adsorption Capacity ◽  
Core Shell Structure

The magnetic CoFe2O4@SiO2–NH2 particles with core-shell structure are designed and synthesized. They have high adsorption capacity (170.829 mg g−1), high removal efficiency (96.93%) for heavy metals, and can be recycled easily.

scholarly journals Synthesis and Performance Evaluation of Chitosan/zinc Oxide Nanocomposite as a Highly Efficient Adsorbent in the Removal of Reactive Red 198 From Water

2021 ◽  
Author(s):  
Najmeh Amirmahani ◽  
Hakimeh Mahdizadeh ◽  
Neda Seyedi ◽  
Alireza Nasiri ◽  
Ghazal Yazdanpanah
Keyword(s):  
Zinc Oxide ◽  
Adsorption Capacity ◽  
High Efficiency ◽  
Low Cost ◽  
Industrial Effluents ◽  
Textile Wastewater ◽  
Secondary Compounds ◽  
High Adsorption ◽  
Reactive Red 198 ◽  
High Adsorption Capacity

Abstract Disposal of textile industrial effluents causes many environmental problems. The presence of chemical dyes in textile wastewater lead to the primary environmental pollution as well as the production of hazardous secondary compounds that are toxic and carcinogenic. In this study, Chitosan and Chitosan-zinc oxide (ZnO) nanocomposite were prepared and selected as a low-cost adsorbent with high adsorption capacity for removing reactive red 198 (RR 198) dye from contaminated. After preparation, it was characterized using Fourier-transform infrared spectroscopy [FT-IR], X-ray diffraction spectrophotometer [XRD], and scanning electron microscopy [SEM]. The effect of pH, temperature, time, adsorbent amount, and initial dye concentration were investigated in the removal efficiency of reactive red 198 (RR 198) dyes. The results showed that the maximum adsorption capacity (qm) obtained from the Langmuir equation was 172.41 mg/g in adsorbent dose of 0.1 g/L, pH: 4, temperature of 25°C, adsorption time of 40 min. The thermodynamic parameters demonstrated the spontaneous and endothermic nature of the adsorption process. Due to the high efficiency of chitosan/ZnO nanocomposite in removal of RR 198 from water and advantages such as high adsorption capacity, simple synthesis, and easy application, it can be used as an effective method in removal of RR 198 from water.

Fe3O4/PANI/MnO2 core–shell hybrids as advanced adsorbents for heavy metal ions

2017 ◽  
Vol 5 (8) ◽  
pp. 4058-4066 ◽  
Author(s):  
Jian Zhang ◽  
Jie Han ◽  
Minggui Wang ◽  
Rong Guo
Keyword(s):  
Heavy Metal ◽  
Metal Ions ◽  
Adsorption Capacity ◽  
Heavy Metal Ions ◽  
Core Shell ◽  
High Adsorption ◽  
Magnetic Adsorbents ◽  
Solution Route ◽  
High Adsorption Capacity

Multifunctional magnetic adsorbents of Fe3O4/PANI/MnO2 core–shell hybrids have been developed through a facile and economic solution route, which show high adsorption capacity toward heavy metal ions.

scholarly journals Preparation and Characterization of High-Efficiency Magnetic Heavy Metal Capture Flocculants

Water ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 1732
Author(s):  
Yuanyuan Yu ◽  
Yongjun Sun ◽  
Jun Zhou ◽  
Aowen Chen ◽  
Kinjal J. Shah
Keyword(s):  
Heavy Metal ◽  
Reaction Time ◽  
High Efficiency ◽  
Removal Rate ◽  
Low Cost ◽  
Monomer Concentration ◽  
Synthesis Process ◽  
Response Surface Optimization ◽  
Metal Capture ◽  
Total Monomer Concentration

In this study, a high-efficiency magnetic heavy metal flocculant MF@AA was prepared based on carboxymethyl chitosan and magnetic Fe3O4. It was characterized by SEM, FTIR, XPS, XRD and VSM, and the Cu(II) removal rate was used as the evaluation basis for the preparation process. The effects of AMPS content, total monomer concentration, photoinitiator concentration and reaction time on the performance of MF@AA flocculation to remove Cu(II) were studied. The characterization results show that MF@AA has been successfully prepared and exhibits good magnetic induction characteristics. The synthesis results show that under the conditions of 10% AMPS content, 35% total monomer concentration, 0.04% photoinitiator concentration, and 1.5 h reaction time, the best yield of MF@AA is 77.69%. The best removal rate is 87.65%. In addition, the response surface optimization of the synthesis process of MF@AA was performed. The optimal synthesis ratio was finally determined as iron content 6.5%, CMFS: 29.5%, AM: 53.9%, AMPS: 10.1%. High-efficiency magnetic heavy metal flocculant MF@AA shows excellent flocculation performance in removing Cu(II). This research provides guidance and ideas for the development of efficient and low-cost flocculation technology to remove Cu(II) in wastewater.

scholarly journals Rapid removal of heavy metal ions from aqueous solutions by low cost adsorbents

2012 ◽  
Vol 12 (2/3/4) ◽  
pp. 318 ◽  
Author(s):  
Ali Ahmadpour ◽  
Tahereh Rohani Bastami ◽  
Masumeh Tahmasbi ◽  
Mohammad Zabihi
Keyword(s):  
Heavy Metal ◽  
Aqueous Solutions ◽  
Metal Ions ◽  
Heavy Metal Ions ◽  
Low Cost ◽  
Rapid Removal

Thermo-kinetic investigation of heavy metal ions adsorption onto lignin considering coupled adsorption–desorption mechanisms: Modeling and experimental validation

2018 ◽  
Vol 09 (02) ◽  
pp. 1850014
Author(s):  
Farnaz Seyedvakili ◽  
Mohammad Samipoorgiri
Keyword(s):  
Heavy Metal ◽  
Metal Ions ◽  
Heavy Metal Ions ◽  
Individual Characteristics ◽  
Adsorption And Desorption ◽  
Isotherm Equation ◽  
Proposed Model ◽  
Isotherm And Kinetic Models ◽  
The Individual ◽  
Adsorption Desorption

A coupled adsorption–desorption thermo-kinetic model is developed incorporating both adsorption and desorption reactions. A local pseudo-equilibrium condition at the interface of adsorbent and adsorbate bulk phases was used as isotherm equation which can even be applied for multi-pollutants scenarios. The developed model is then validated using collected experimental data of heavy metal ions (Pb, Cu, Cd, Zn, and Ni). Comparisons were made for a number of isotherm and kinetic models to examine the performance of the proposed model. The developed model revealed desirable accuracy and superiority over other models in predicting the adsorption behavior and can be used for other systems of concern. The model correlates the adsorption kinetic with an [Formula: see text] value of 0.9391 and desorption kinetic with an [Formula: see text] value of 0.9383. By application of the proposed model to any available adsorption datasets, the individual characteristics of adsorption and desorption can be determined.

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