Heterocarbon nanosheets incorporating iron phthalocyanine for oxygen reduction reaction in both alkaline and acidic media

2016 ◽  
Vol 18 (16) ◽  
pp. 10856-10863 ◽  
Author(s):  
Koangyong Hyun ◽  
Tomonaga Ueno ◽  
Gasidit Panomsuwan ◽  
Oi Lun Li ◽  
Nagahiro Saito

Heterocarbon nanosheets incorporating iron phthalocyanine as electrocatalysts have been successfully synthesized by a solution plasma process using high-repetition-frequency discharges at room temperature and atmospheric pressure.

2017 ◽  
Vol 5 (5) ◽  
pp. 2073-2082 ◽  
Author(s):  
Oi Lun Li ◽  
Satoshi Chiba ◽  
Yuta Wada ◽  
Gasidit Panomsuwan ◽  
Takahiro Ishizaki

N-doped carbon synthesized by a room temperature plasma process demonstrated the synergic effect of amino-N and graphitic-N towards advanced ORR activity.


2015 ◽  
Vol 3 (18) ◽  
pp. 9972-9981 ◽  
Author(s):  
Gasidit Panomsuwan ◽  
Nagahiro Saito ◽  
Takahiro Ishizaki

Fluorine-doped carbon nanoparticles were successfully synthesized via a simple one-step solution plasma process at room temperature and atmospheric pressure without the addition of a metal catalyst.


2020 ◽  
Vol 9 (1) ◽  
pp. 843-852
Author(s):  
Hunan Jiang ◽  
Jinyang Li ◽  
Mengni Liang ◽  
Hanpeng Deng ◽  
Zuowan Zhou

AbstractAlthough Fe–N/C catalysts have received increasing attention in recent years for oxygen reduction reaction (ORR), it is still challenging to precisely control the active sites during the preparation. Herein, we report FexN@RGO catalysts with the size of 2–6 nm derived from the pyrolysis of graphene oxide and 1,1′-diacetylferrocene as C and Fe precursors under the NH3/Ar atmosphere as N source. The 1,1′-diacetylferrocene transforms to Fe3O4 at 600°C and transforms to Fe3N and Fe2N at 700°C and 800°C, respectively. The as-prepared FexN@RGO catalysts exhibited superior electrocatalytic activities in acidic and alkaline media compared with the commercial 10% Pt/C, in terms of electrochemical surface area, onset potential, half-wave potential, number of electrons transferred, kinetic current density, and exchange current density. In addition, the stability of FGN-8 also outperformed commercial 10% Pt/C after 10000 cycles, which demonstrates the as-prepared FexN@RGO as durable and active ORR catalysts in acidic media.


2021 ◽  
Author(s):  
Suojiang Zhang ◽  
jiayao Cui ◽  
Qingjun Chen ◽  
Xiaojin Li

The high cost and limited supply of platinum has driven intensive research into the use of non-platinum group metal (PGM-free) as cathode oxygen reduction reaction (ORR) catalysts for proton exchange...


2015 ◽  
Vol 51 (12) ◽  
pp. 2450-2453 ◽  
Author(s):  
Dae-Soo Yang ◽  
Min Young Song ◽  
Kiran Pal Singh ◽  
Jong-Sung Yu

The exact role of iron in catalyzing oxygen reduction reaction in both alkaline and acidic media is portrayed with unique platelet ordered mesoporous carbon prepared using Fe-phthalocyanine as iron, nitrogen and carbon sources.


2019 ◽  
Vol 9 (3) ◽  
pp. 611-619 ◽  
Author(s):  
Mitsuharu Chisaka ◽  
Hiroyuki Morioka

Phosphor and nitrogen atoms were co-doped into rutile TiO2 phase on TiN to produce new active sites for oxygen reduction reaction.


Ionics ◽  
2017 ◽  
Vol 24 (1) ◽  
pp. 229-236 ◽  
Author(s):  
Yanli Huang ◽  
Zhan Tan ◽  
Huimin Wu ◽  
Chuanqi Feng ◽  
Yu Ding

Sign in / Sign up

Export Citation Format

Share Document