Synthesis of nitrogen doped mesoporous carbons for carbon dioxide capture

RSC Advances ◽  
2015 ◽  
Vol 5 (58) ◽  
pp. 46568-46582 ◽  
Author(s):  
Chitrakshi Goel ◽  
Haripada Bhunia ◽  
Pramod K. Bajpai

Nitrogen doped mesoporous carbons were prepared from melamine-formaldehyde resin and mesoporous silica by nanocasting method followed by their characterization and CO2 adsorption performance evaluation by fixed-bed experiments.

2011 ◽  
Vol 143 (1) ◽  
pp. 174-179 ◽  
Author(s):  
Marília R. Mello ◽  
Delphine Phanon ◽  
Gleiciani Q. Silveira ◽  
Philip L. Llewellyn ◽  
Célia M. Ronconi

2012 ◽  
Vol 554-556 ◽  
pp. 778-782 ◽  
Author(s):  
Chao Liu ◽  
Yong Qi Hu ◽  
Yi Feng Yu ◽  
Yue Zhang ◽  
Yan Yan Wang ◽  
...  

Nitrogen-doped mesoporous carbon materials have been synthesized by using melamine-formaldehyde resin as carbon precursor and SBA-15 as a removable template. The structure of the materials was investigated by X-ray diffraction, BET specific surface area analysis, Fourier transform infrared spectroscopy, and thermogravimetric analysis. X-ray and BET studies confirmed that a pore nanostructure is inherited from the silica templates. Fourier transform infrared spectroscopy analysis showed N atoms are strongly bonded in the carbon structure in heterocycles or nitrile functions. These mesoporous nitrogen-doped carbon materials exhibits textural properties with BET surface areas ranging between 400 and 600 m2/g and uniform pore size(3.9 nm). The mechanism of carbonization process is studied by thermogravimetric analysis. The ratio of melamine/formaldehyde plays an important role during the carbonization process for the surface areas and textural properties, and element analysis reveals that the nitrogen content of the mesoporous carbon materials is as high as 10wt%.


2019 ◽  
Vol 491 ◽  
pp. 607-615 ◽  
Author(s):  
Fangfang Qin ◽  
Zhongya Guo ◽  
Jiashi Wang ◽  
Shijie Qu ◽  
Pingping Zuo ◽  
...  

2019 ◽  
Vol 10 (33) ◽  
pp. 4611-4620 ◽  
Author(s):  
Ningning Song ◽  
Tianjiao Wang ◽  
Hongyan Yao ◽  
Tengning Ma ◽  
Kaixiang Shi ◽  
...  

Microporous polyimide networks with high surface area and excellent CO2 adsorption performance have been constructed based on cross-linkable linear polyimides through crosslinking reaction.


2020 ◽  
Vol 9 (3) ◽  
pp. 3249-3260 ◽  
Author(s):  
Zaitun Ghazali ◽  
Nabilah Suhaili ◽  
Maratun Najiha Abu Tahari ◽  
Mohd Ambar Yarmo ◽  
Nur Hasyareeda Hassan ◽  
...  

2018 ◽  
Vol 34 ◽  
pp. 02030 ◽  
Author(s):  
N.Z. Zulkurnai ◽  
U.F. Md. Ali ◽  
N. Ibrahim ◽  
N.S. Abdul Manan

The increment amount of the CO2 emission by years has become a major concern worldwide due to the global warming issue. However, the influence modification of activated carbon (AC) has given a huge revolution in CO2 adsorption capture compare to the unmodified AC. In the present study, the Deep Eutectic Solvent (DES) modified surface AC was used for Carbon Dioxide (CO2) capture in the fixed-bed column. The AC underwent pre-carbonization and carbonization processes at 519.8 °C, respectively, with flowing of CO2 gas and then followed by impregnation with 53.75% phosphoric acid (H3PO4) at 1:2 precursor-to-activant ratios. The prepared AC known as sea mango activated carbon (SMAC) was impregnated with DES at 1:2 solid-to-liquid ratio. The DES is composing of choline chloride and urea with ratio 1:2 choline chloride to urea. The optimum adsorption capacity of SMAC was 33.46 mgco2/gsol and 39.40 mgco2/gsol for DES modified AC (DESAC).


2018 ◽  
Vol 16 (2) ◽  
pp. 115-119
Author(s):  
А. Zhumagaliyeva ◽  
V. Gargiulo ◽  
Ye. Doszhanov ◽  
M. Alfe

In this work carbonized rice husk  was used as carbon-based solid matrix in the preparation of composite materials modified with Fe3O4 particles. Aim of this study is to exploit the advantages and shortcomings of using a real biomass as starting material for the preparation of sorbents for CO2 capture applications. Sorption capacity of the obtained composite materials was tested on fixed-bed  microreactor.


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