Carrier dilution in TiSe2 based intergrowth compounds for enhanced thermoelectric performance

2015 ◽  
Vol 3 (40) ◽  
pp. 10451-10458 ◽  
Author(s):  
S. R. Bauers ◽  
D. R. Merrill ◽  
D. B. Moore ◽  
D. C. Johnson
Keyword(s):  
Thin Film ◽  
Electrical Properties ◽  
Seebeck Coefficient ◽  
Thermoelectric Power ◽  
Power Factor ◽  
Thermoelectric Performance ◽  
Thermoelectric Power Factor

Synthesis and electrical properties of kinetically stabilized (PbSe)1+δ(TiSe2)n thin-film intergrowths are reported for 1 ≤ n ≤ 18. The carriers donated to the TiSe2 from PbSe are diluted with increasing n, leading to a systematic increase in the Seebeck coefficient and thermoelectric power factor.

Electrochemical doping engineering tuning of the thermoelectric performance of a π-conjugated free-standing poly(thiophene-furan) thin-film

2020 ◽  
Vol 4 (2) ◽  
pp. 597-604 ◽  
Author(s):  
Wenqian Yao ◽  
Lanlan Shen ◽  
Peipei Liu ◽  
Congcong Liu ◽  
Jingkun Xu ◽  
...  
Keyword(s):  
Thin Film ◽  
Thermoelectric Power ◽  
Power Factor ◽  
Thermoelectric Performance ◽  
Free Standing ◽  
Thermoelectric Power Factor ◽  
Electrochemical Doping

Promising free-standing poly(thiophene-furan) gains a high thermoelectric power factor by facile electrochemical doping engineering.

scholarly journals Macroscopic weavable fibers of carbon nanotubes with giant thermoelectric power factor

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Natsumi Komatsu ◽  
Yota Ichinose ◽  
Oliver S. Dewey ◽  
Lauren W. Taylor ◽  
Mitchell A. Trafford ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Carbon Nanotubes ◽  
Thermoelectric Power ◽  
Power Factor ◽  
Fermi Energy ◽  
Performance Enhancement ◽  
Thermoelectric Performance ◽  
Thermoelectric Power Factor ◽  
Large Power ◽  
Energy Tuning

AbstractLow-dimensional materials have recently attracted much interest as thermoelectric materials because of their charge carrier confinement leading to thermoelectric performance enhancement. Carbon nanotubes are promising candidates because of their one-dimensionality in addition to their unique advantages such as flexibility and light weight. However, preserving the large power factor of individual carbon nanotubes in macroscopic assemblies has been challenging, primarily due to poor sample morphology and a lack of proper Fermi energy tuning. Here, we report an ultrahigh value of power factor (14 ± 5 mW m−1 K−2) for macroscopic weavable fibers of aligned carbon nanotubes with ultrahigh electrical and thermal conductivity. The observed giant power factor originates from the ultrahigh electrical conductivity achieved through excellent sample morphology, combined with an enhanced Seebeck coefficient through Fermi energy tuning. We fabricate a textile thermoelectric generator based on these carbon nanotube fibers, which demonstrates high thermoelectric performance, weavability, and scalability. The giant power factor we observe make these fibers strong candidates for the emerging field of thermoelectric active cooling, which requires a large thermoelectric power factor and a large thermal conductivity at the same time.

scholarly journals Influence of crystallinity on the thermoelectric power factor of P3HT vapour-doped with F4TCNQ

RSC Advances ◽  
2018 ◽  
Vol 8 (3) ◽  
pp. 1593-1599 ◽  
Author(s):  
Jonna Hynynen ◽  
David Kiefer ◽  
Christian Müller
Keyword(s):  
Electrical Conductivity ◽  
Seebeck Coefficient ◽  
Thermoelectric Power ◽  
Power Factor ◽  
Thermoelectric Power Factor ◽  
Order Of Magnitude

The crystallinity of P3HT strongly benefits the electrical conductivity but not Seebeck coefficient, leading to an increase in power factor by one order of magnitude.

scholarly journals Centimeter-Long Weavable Fibers of Carbon Nanotubes with Giant Thermoelectric Power Factor

2021 ◽  
Author(s):  
Natsumi Komatsu ◽  
Yota Ichinose ◽  
Oliver Dewey ◽  
Lauren Taylor ◽  
Mitchell Trafford ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Carbon Nanotubes ◽  
Thermoelectric Power ◽  
Power Factor ◽  
Fermi Energy ◽  
Performance Enhancement ◽  
Thermoelectric Performance ◽  
Thermoelectric Power Factor ◽  
Electronic Density ◽  
Large Power

Abstract Low-dimensional materials have recently attracted much interest as thermoelectric materials because of their charge carrier confinement leading to thermoelectric performance enhancement. Carbon nanotubes are promising candidates because of their one-dimensionality in addition to their unique advantages such as flexibility and light weight. However, preserving the large power factor of individual carbon nanotubes in macroscopic assemblies has been challenging, primarily due to poor sample morphology and a lack of proper Fermi energy tuning. Here, we report an unprecedentedly high value of power factor (14±5 mWm-1K-2) for centimeter-long weavable fibers of aligned carbon nanotubes with ultrahigh electrical and thermal conductivity. Our theoretical simulations show that the observed giant power factor originates from the one-dimensional quantum confinement of charge carriers, appearing when the Fermi energy is near a van Hove singularity in the electronic density of states. We fabricated a textile thermoelectric generator based on these carbon nanotube fibers, which demonstrated high thermoelectric performance, weavablity, and scalability. The giant power factor we observed make these fibers strong candidates for the emerging field of thermoelectric active cooling, which requires a large thermoelectric power factor and a large thermal conductivity at the same time.

PHONON-DRAG EFFECT OF ULTRA-THIN FeSi2 AND MnSi1.7/FeSi2 FILMS

2011 ◽  
Vol 25 (22) ◽  
pp. 1829-1838 ◽  
Author(s):  
Q. R. HOU ◽  
B. F. GU ◽  
Y. B. CHEN ◽  
Y. J. HE
Keyword(s):  
Electrical Resistivity ◽  
Seebeck Coefficient ◽  
Single Crystals ◽  
Thermoelectric Power ◽  
Power Factor ◽  
Low Temperatures ◽  
Room Temperature ◽  
Phonon Drag ◽  
Drag Effect ◽  
Thermoelectric Power Factor

Phonon-drag effect usually occurs in single crystals at very low temperatures (10–200 K). Strong phonon-drag effect is observed in ultra-thin β- FeSi 2 films at around room temperature. The Seebeck coefficient of a 23 nm-thick β- FeSi 2 film can reach -1.375 mV/K at 343 K. However, the thermoelectric power factor of the film is still small, only 0.42×10-3 W/m-K2, due to its large electrical resistivity. When a 27 nm-thick MnSi 1.7 film with low electrical resistivity is grown on it, the thermoelectric power factor of the MnSi 1.7 film can reach 1.5×10-3 W/m-K2 at around room temperature. This value is larger than that of bulk MnSi 1.7 material in the same temperature range.

Enhancement of thermoelectric power factor in NaxCoO2/Au multilayers

RSC Advances ◽  
2014 ◽  
Vol 4 (100) ◽  
pp. 57148-57152 ◽  
Author(s):  
Xiaohui Zhao ◽  
Haifeng Wang ◽  
Shufang Wang ◽  
Dogheche Elhadj ◽  
Jianglong Wang ◽  
...  
Keyword(s):  
Thin Film ◽  
High Temperature ◽  
Thermoelectric Power ◽  
Power Factor ◽  
Thermoelectric Power Factor ◽  
Post Annealing ◽  
Au Thin Film

NaxCoO2/Au thin film multilayers, with a thickness of the Au layer of 0.5–12 nm, have been fabricated on c-Al2O3 by post annealing of the CoO/Au thin film multilayers in Na vapor at high temperature in air.

scholarly journals Enormous thermoelectric power factor of ZrTe2/SrTiO3 heterostructure

2021 ◽  
Author(s):  
Chun Hung Suen ◽  
Songhua Cai ◽  
Hui Li ◽  
Xiaodan Tang ◽  
Huichao Wang ◽  
...  
Keyword(s):  
Thin Film ◽  
Thermoelectric Power ◽  
Power Factor ◽  
High Performance ◽  
Transition Metal Dichalcogenides ◽  
Thermoelectric Device ◽  
Two Dimensional ◽  
Dimensional Electron ◽  
Thermoelectric Power Factor ◽  
Dimensional Electron Gas

Abstract Achieving high thermoelectric power factor in thin film heterostructures is essential for integrated and miniaturized thermoelectric device applications. In this work, we demonstrate a mechanism to enhance thermoelectric power factor through coupling the interfacial confined two-dimensional electron gas (2DEG) with thin film conductivity in a transition metal dichalcogenides-SrTiO3 heterostructure. Owing to the formed conductive interface with two-dimensional electron confinement effect and the elevated conductivity, the ZrTe2/SrTiO3 (STO) heterostructure presents enormous thermoelectric power factor as high as 4×10^5 μW cm^(-1) K^(-2) at 20 K and 4800 μW cm^(-1) K^(-2) at room temperature. Interfacial reaction induced degradation of Ti cations valence number from Ti4+ to Ti3+ is attributed to be responsible for the formation of the quasi-two-dimensional electrons at the interface which results in very large Seebeck coefficient; and the enhanced electrical conductivity is suggested to be originated from the charge transfer induced doping in the ZrTe2. By taking the thermal conductivity of STO substrate as a reference, the effective zT value of this heterostructure can reach 15 at 300 K. This superior thermoelectric property makes this heterostructure a promising candidate for future thermoelectric device, and more importantly, paves a new pathway to design promising high-performance thermoelectric systems.

Study of Electrical and Thermoelectrical Properties of One Strand DNA Chain for Nanoscale Thermoelectric Applications

2021 ◽  
Vol 19 (8) ◽  
pp. 70-76
Author(s):  
Shakir A.A. AL-Saidi ◽  
Alaa Ayad K. Al-mebir ◽  
J.M. Al-Mukh
Keyword(s):  
Seebeck Coefficient ◽  
Thermoelectric Power ◽  
Power Factor ◽  
Dna Sequences ◽  
Transmission Probability ◽  
Dna Molecules ◽  
Thermoelectric Devices ◽  
Thermoelectric Power Factor ◽  
Dna Chain ◽  
Energy Dependent

The concept of using DNA molecules for designing nano-scale electronic systems has attracted researcher’s attention due to the unique properties of DNA, such as self-assembly and self-recognition. Thus, increased number of studies, theoretically and experimentally, have been carried out to study the possibility of adopting DNA molecules in designing nanoscale thermoelectric devices. In this work, a general expression of the electron transmission probability that describes the electron transfer through one strand DNA chain has been derived using the steady-state-formalism by assuming one strand of DNA molecules as line model. The energy-dependent transmission was studied, then energy-and temperature-dependent Seebeck coefficient, and thermoelectric characteristics of four one strand DNA sequences: (A-A)10, (C-C)10, (G-G)10 and (T-T)10 are theoretically studied. According to the obtained results, it is found that the transmission behavior (magnitude and position) is varying with the type of DNA sequence. Also, the energy dependent Seebeck coefficient (S-E) curves clearly show a nonlinear energy-dependence, while the relationship between Seebeck coefficient and temperature (S-T) is linear. Thermoelectric power factor as a function of temperature was found to be enhanced with the temperature increment for the four types of DNA nucleobases. The highest values of thermoelectric power factor belong to thymine (120Wm-1K-2) and cytosine (60 Wm-1K-2), that nominate them as outstanding candidate thermoelectric materials to be adopted in the fabrication of one strand DNA-base nanoscale thermoelectric devices.

Enhanced thermoelectric performance of PEDOT:PSS/PANI–CSA polymer multilayer structures

2016 ◽  
Vol 9 (9) ◽  
pp. 2806-2811 ◽  
Author(s):  
Hye Jeong Lee ◽  
Gopinathan Anoop ◽  
Hyeon Jun Lee ◽  
Chingu Kim ◽  
Ji-Woong Park ◽  
...  
Keyword(s):  
Thin Films ◽  
Conducting Polymers ◽  
Thermoelectric Power ◽  
Power Factor ◽  
Organic Thin Films ◽  
Thermoelectric Performance ◽  
Multilayer Structures ◽  
Layer By Layer ◽  
Thermoelectric Power Factor ◽  
Layer Deposition

A layer-by-layer deposition of two conducting polymers, each layer of which is a few tenths of nanometer thick, has been successfully performed to enhance the thermoelectric power factor of organic thin films.

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