Flexible BaTiO3/PVDF gradated multilayer nanocomposite film with enhanced dielectric strength and high energy density

2015 ◽  
Vol 3 (37) ◽  
pp. 9740-9747 ◽  
Author(s):  
Y. N. Hao ◽  
X. H. Wang ◽  
S. O'Brien ◽  
J. Lombardi ◽  
L. T. Li
Keyword(s):  
Energy Density ◽  
Dielectric Breakdown ◽  
Dielectric Strength ◽  
High Energy ◽  
Dielectric Constants ◽  
High Energy Density ◽  
Nanocomposite Films ◽  
High Dielectric ◽  
High Flexibility ◽  
Discharged Energy Density

BaTiO3/PVDF nanocomposite films with high flexibility and gradated BaTiO3 distribution structure are fabricated. These films show high dielectric constants of 20–25, a maximal discharged energy density value of 19.37 J cm−3 and dielectric breakdown strengths of up to 495 kV mm−1.

Metalized Polypropylene Film in Capacitors: Characterization and The Effect of Interfacial Pressure on the Dielectric Strength

1997 ◽  
Vol 476 ◽  
Author(s):  
Shalabh Tandon ◽  
Richard J. Farris
Keyword(s):  
Thermal Expansion ◽  
Energy Density ◽  
Dielectric Breakdown ◽  
Coefficient Of Thermal Expansion ◽  
Dielectric Strength ◽  
High Energy ◽  
High Energy Density ◽  
Polypropylene Film ◽  
Interfacial Pressure ◽  
Out Of Plane

AbstractMetalized polypropylene film used in high energy density capacitors has been mechanically characterized to determine its elastic constants. The out of plane coefficient of thermal expansion (CTE) of the orthotropic film is 10 times as large as the smaller in plane CTE. The out of plane modulus is twice as large compared to one of the in plane moduli. The effect of interfacial pressure on the dielectric breakdown is also studied for the same film. It is observed that the dielectric strength of the film decreases at first and then increases above 4 MPa of compressive stress.

Modeling, characterization and evaluation of MU100 high-energy density ceramic nanodielectric for use in pulsed power applications

2017 ◽  
Author(s):  
◽  
Alexander B. Howard
Keyword(s):  
Energy Density ◽  
Dielectric Strength ◽  
High Energy ◽  
Pulsed Power ◽  
High Energy Density ◽  
Small Scale ◽  
University Of Missouri ◽  
High Dielectric ◽  
The University ◽  
Preparation And Evaluation

A high dielectric, nanodielectric, composite material, MU100, was developed by the University of Missouri for use in dielectric loaded antennas. Based on its dielectric strength and losses, MU100 had possible uses in the development for high energy-density capacitors. This work presents the theory behind, methods of preparation and evaluation, modeling and properties of MU100. MU100’s dielectric properties are explored in high energy-density pulsed power applications, compact high voltage capacitors. Small scale tests have shown the average dielectric strength of MU100 to be 225 kV/cm with a peak break down field of 328 kV/cm. When potted, these small-scale capacitors have lifetimes in excess of 800,000 discharges at 80% of their maximum rated field strength. This shows a remarkable development in the performance of high energy density capacitors for use in pulsed power applications.

scholarly journals Prospects for the Development of High Energy Density Dielectric Capacitors

2021 ◽  
Vol 11 (17) ◽  
pp. 8063
Author(s):  
Andrew Burke
Keyword(s):  
Dielectric Constant ◽  
Energy Density ◽  
Breakdown Strength ◽  
High Energy ◽  
Dielectric Constants ◽  
Polymer Materials ◽  
High Energy Density ◽  
Effective Dielectric Constant ◽  
High Dielectric ◽  
Very High

In this paper, the design of high energy density dielectric capacitors for energy storage in vehicle, industrial, and electric utility applications have been considered in detail. The performance of these devices depends primarily on the dielectric constant and breakdown strength characteristics of the dielectric material used. A review of the literature on composite polymer materials to assess their present dielectric constants and the various approaches being pursued to increase energy density found that there are many papers in which materials having dielectric constants of 20–50 were reported, but only a few showing materials with very high dielectric constants of 500 and greater. The very high dielectric constants were usually achieved with nanoscale metallic or carbon particles embedded in a host polymer and the maximum dielectric constant occurred near the percolation threshold particle loading. In this study, an analytical method to calculate the dielectric constant of composite dielectric polymers with various types of nanoparticles embedded is presented. The method was applied using an Excel spreadsheet to calculate the characteristics of spiral wound battery cells using various composite polymers with embedded particles. The calculated energy densities were strong functions of the size of the particles and thickness of the dielectric layer in the cell. For a 1000 V cell, an energy density of 100–200 Wh/kg was calculated for 3–5 nm particles and 3–5 µ thick dielectric layers. The results of this study indicate that dielectric materials with an effective dielectric constant of 500–1000 are needed to develop dielectric capacitor cells with battery-like energy density. The breakdown strength would be 300–400 V/µ in a reverse sandwich multilayer dielectric arrangement. The leakage current of the cell would be determined from appropriate DC testing. These high energy density dielectric capacitors are very different from electrochemical capacitors that utilize conducting polymers and liquid electrolytes and are constructed much like batteries. The dielectric capacitors have a very high cell voltage and are constructed like conventional ceramic capacitors.

scholarly journals Glycerolized Li+ Ion Conducting Chitosan-Based Polymer Electrolyte for Energy Storage EDLC Device Applications with Relatively High Energy Density

Polymers ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 1433 ◽  
Author(s):  
Ahmed S. F. M. Asnawi ◽  
Shujahadeen B. Aziz ◽  
Muaffaq M. Nofal ◽  
Muhamad H. Hamsan ◽  
Mohamad A. Brza ◽  
...  
Keyword(s):  
Energy Density ◽  
Polymer Electrolyte ◽  
Specific Capacitance ◽  
Power Density ◽  
High Specific Capacitance ◽  
High Energy ◽  
High Energy Density ◽  
Equivalent Series Resistance ◽  
Ion Conducting ◽  
High Dielectric

In this study, the solution casting method was employed to prepare plasticized polymer electrolytes of chitosan (CS):LiCO2CH3:Glycerol with electrochemical stability (1.8 V). The electrolyte studied in this current work could be established as new materials in the fabrication of EDLC with high specific capacitance and energy density. The system with high dielectric constant was also associated with high DC conductivity (5.19 × 10−4 S/cm). The increase of the amorphous phase upon the addition of glycerol was observed from XRD results. The main charge carrier in the polymer electrolyte was ion as tel (0.044) < tion (0.956). Cyclic voltammetry presented an almost rectangular plot with the absence of a Faradaic peak. Specific capacitance was found to be dependent on the scan rate used. The efficiency of the EDLC was observed to remain constant at 98.8% to 99.5% up to 700 cycles, portraying an excellent cyclability. High values of specific capacitance, energy density, and power density were achieved, such as 132.8 F/g, 18.4 Wh/kg, and 2591 W/kg, respectively. The low equivalent series resistance (ESR) indicated that the EDLC possessed good electrolyte/electrode contact. It was discovered that the power density of the EDLC was affected by ESR.

The high energy density and efficiency of PVDF-based composites with double-shell Nd-BaTiO3 particles as fillers

2020 ◽  
Vol 13 (06) ◽  
pp. 2051042
Author(s):  
Zhong Yang ◽  
Jing Wang ◽  
Long He ◽  
Chaoyong Deng ◽  
Kongjun Zhu
Keyword(s):  
Energy Storage ◽  
Energy Density ◽  
Vinylidene Fluoride ◽  
Composite Films ◽  
High Energy ◽  
Maximum Energy ◽  
Dielectric Constants ◽  
High Energy Density ◽  
Element Simulation ◽  
Poly Vinylidene Fluoride

Flexible dielectric capacitors are becoming shining stars in modern electronic devices. Ceramic particles with large dielectric constants and benign compatibility are attractive candidates to enhance the energy storage density of pristine polymer capacitors while guaranteeing their flexibility. In this work, double-shell structure of Al2O3 (AO) and dopamine (PDA) were successively coated on the Nd-doped BaTiO3 (NBT) particles and then introduced into the Poly(vinylidene fluoride) (PVDF) matrix. Obvious enhancement in dielectric constants was observed while the dielectric loss remained nearly constant. For the composite films with 1–4[Formula: see text]vol.% NBT@AO@PDA NPs, the maximum energy density of 9.1[Formula: see text]J/cm3 and energy efficiency of 65% was achieved at 430[Formula: see text]MV/m in the sample with 1[Formula: see text]vol.% filling ratio, which are 1.4 and 1.3 times larger than those of pristine PVDF at 450[Formula: see text]MV/m. The finite element simulation reveals the effective relief of the electric field concentration in the composite film induced by the AO and PDA layers. The greater improvement in the energy storage performance could be anticipated if the dispersity of NBT@AO@PDA NPs was further improved.

High-field antiferroelectric-like behavior in uniaxially stretched poly(vinylidene fluoride-trifluoroethylene-chlorotrifluoroethylene)-grafted-poly(methyl methacrylate) films with high energy density

RSC Advances ◽  
2016 ◽  
Vol 6 (2) ◽  
pp. 1589-1599 ◽  
Author(s):  
Honghong Gong ◽  
Bei Miao ◽  
Xiao Zhang ◽  
Junyong Lu ◽  
Zhicheng Zhang
Keyword(s):  
Energy Density ◽  
Methyl Methacrylate ◽  
High Field ◽  
Vinylidene Fluoride ◽  
Breakdown Strength ◽  
High Energy ◽  
High Energy Density ◽  
Poly Methyl Methacrylate ◽  
Poly Vinylidene Fluoride ◽  
Discharged Energy Density

The antiferroelectric-like behavior could be retained up to 675 MV m−1 with a discharged energy density of 23.3 J cm−3 because of the confinement of rigid PMMA segment onto the ferroelectric relaxation of P(VDF-TrFE-CTFE) and the high breakdown strength.

Electro-active phase formation in PVDF–BiVO4 flexible nanocomposite films for high energy density storage application

RSC Advances ◽  
2014 ◽  
Vol 4 (89) ◽  
pp. 48220-48227 ◽  
Author(s):  
Subrata Sarkar ◽  
Samiran Garain ◽  
Dipankar Mandal ◽  
K. K. Chattopadhyay
Keyword(s):  
Dielectric Properties ◽  
Energy Density ◽  
Phase Formation ◽  
Nanocomposite Film ◽  
Active Phase ◽  
Electrical Energy ◽  
High Energy ◽  
High Energy Density ◽  
Nanocomposite Films ◽  
Energy Harvesters

A significant improvement of dielectric properties and toughness with electrical energy density up to 11 J cm−3 is observed in flexible PVDF–BiVO4 nanocomposite film. It underlines to use as flexible high energy density capacitors and piezoelectric based energy harvesters.

Construction of highly dispersed mesoporous bimetallic-sulfide nanoparticles locked in N-doped graphitic carbon nanosheets for high energy density hybrid flexible pseudocapacitors

2019 ◽  
Vol 7 (29) ◽  
pp. 17435-17445 ◽  
Author(s):  
Muhammad Sufyan Javed ◽  
Hang Lei ◽  
Jinliang Li ◽  
Zilong Wang ◽  
Wenjie Mai
Keyword(s):  
Energy Density ◽  
Power Density ◽  
High Energy ◽  
Graphitic Carbon ◽  
High Energy Density ◽  
Ultrahigh Energy ◽  
Carbon Nanosheets ◽  
Highly Dispersed ◽  
Bimetallic Sulfide ◽  
High Flexibility

The as-fabricated ZCS//MPC-ASC device delivered the ultrahigh energy density of 92.59 W h kg−1 at the power density of 846.02 W kg−1 with high flexibility.

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