Enhanced selective adsorption of CO2 on nitrogen-doped porous carbon monoliths derived from IRMOF-3

The N-doped porous carbon monoliths prepared by direct carbonization of IRMOF-3, through an in situ activation and self-templating process, were found to exhibit significantly enhanced performance for the selective adsorption of CO2 compared to pristine IRMOF-3.

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Zeolite cage-lock strategy for in situ synthesis of highly nitrogen-doped porous carbon for selective adsorption of carbon dioxide gas

RSC Advances ◽

10.1039/c6ra26997d ◽

2017 ◽

Vol 7 (39) ◽

pp. 24195-24203 ◽

Cited By ~ 8

Author(s):

Chunfeng Xue ◽

Hongye Zhu ◽

Tingting Xu ◽

Enyang Wang ◽

Bo Xiao ◽

...

Keyword(s):

Carbon Dioxide ◽

Adsorption Capacity ◽

Porous Carbon ◽

Selective Adsorption ◽

In Situ Synthesis ◽

Organic Template ◽

Nitrogen Doped ◽

Carbon Dioxide Gas ◽

Carbon Structures

Porous carbon structures doped with 18.14% nitrogen and prepared by a carbonizing organic template in ZSM-39 zeolitic cages show high CO2 adsorption capacity.

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In Situ One-Step Synthesis of Hierarchical Nitrogen-Doped Porous Carbon for High-Performance Supercapacitors

ACS Applied Materials & Interfaces ◽

10.1021/am500339x ◽

2014 ◽

Vol 6 (10) ◽

pp. 7214-7222 ◽

Cited By ~ 221

Author(s):

Ju-Won Jeon ◽

Ronish Sharma ◽

Praveen Meduri ◽

Bruce W. Arey ◽

Herbert T. Schaef ◽

...

Keyword(s):

Porous Carbon ◽

High Performance ◽

Nitrogen Doped ◽

One Step

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In situ-formed cobalt nanoparticles embedded nitrogen-doped hierarchical porous carbon as sulfur host for high-performance Li-S batteries

Electrochimica Acta ◽

10.1016/j.electacta.2021.139717 ◽

2021 ◽

pp. 139717

Author(s):

Hongcheng Gao ◽

Shihao Miao ◽

Mengqin Shi ◽

Xiaoxia Mao ◽

Xiaojing Zhu

Keyword(s):

Porous Carbon ◽

High Performance ◽

Cobalt Nanoparticles ◽

Hierarchical Porous Carbon ◽

Nitrogen Doped ◽

Hierarchical Porous ◽

Sulfur Host

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Enhanced N-doped Porous Carbon Derived from KOH-Activated Waste Wool: A Promising Material for Selective Adsorption of CO2/CH4 and CH4/N2

Nanomaterials ◽

10.3390/nano9020266 ◽

2019 ◽

Vol 9 (2) ◽

pp. 266 ◽

Cited By ~ 20

Author(s):

Yao Li ◽

Ran Xu ◽

Binbin Wang ◽

Jianping Wei ◽

Lanyun Wang ◽

...

Keyword(s):

Porous Carbon ◽

Selective Adsorption ◽

Landfill Gas ◽

Pure Component ◽

Mixing Ratios ◽

Ideal Adsorbed Solution Theory ◽

Adsorption Capacities ◽

Adsorbed Solution ◽

Separation Of Co2 ◽

Adsorption Of Co2

Separation of impurities (CO2 and N2) from CH4 is an important issue for natural gas alternatives (such as coalbed gas, biogas, and landfill gas) upgrading. It is notably challenging to synthesize high N-doped porous carbon with an appropriate porous structure. In this work, high N content (14.48 wt %) porous carbon with micropore size of 0.52 and 1.2 nm and specific surface area of 862 m2 g−1 has been synthesized from potassium hydroxide (KOH) activated waste wool upon the urea modification. Pure component adsorption isotherms of CO2, CH4, and N2 are systematically measured on this enhanced N-doped porous carbon at 0 and 25 °C, up to 1 bar, to evaluate the gases adsorption capability, and correlated with the Langmuir model. These data are used to estimate the separation selectivities for binary mixtures of CO2/CH4 and CH4/N2 at different mixing ratios according to the ideal adsorbed solution theory (IAST) model. At an ambient condition of 25 °C and 1 bar, the predicted selectivities for equimolar CO2/CH4 and CH4/N2 are 3.19 and 7.62, respectively, and the adsorption capacities for CO2, CH4, and N2 are 2.91, 1.01, and 0.13 mmol g−1, respectively. This report introduces a simple pathway to obtain enhanced N-doped porous carbon with large adsorption capacities for gas separation of CO2/CH4 and CH4/N2.

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Reversible single-crystal-to-single-crystal transformation from a mononuclear complex to a fourfold interpenetrated MOF with selective adsorption of CO2

Dalton Transactions ◽

10.1039/c5dt03570h ◽

2015 ◽

Vol 44 (46) ◽

pp. 19796-19799 ◽

Cited By ~ 13

Author(s):

Min-Min Liu ◽

Yan-Lin Bi ◽

Qin-Qin Dang ◽

Xian-Ming Zhang

Keyword(s):

Single Crystal ◽

Room Temperature ◽

Selective Adsorption ◽

Low Pressure ◽

Mononuclear Complex ◽

Crystal Transformation ◽

Adsorption Of Co ◽

Adsorption Of Co2

Reversible crystal transformation was observed between a mononuclear complex to a fourfold interpenetrated MOF with selective adsorption of CO2 up to 12.5 wt% at room temperature and low pressure.

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