scholarly journals Micro flow injection ICP-MS analysis of high matrix samples: an investigation of its capability to measure trace elements in iron meteorites

2018 ◽  
Vol 33 (11) ◽  
pp. 1941-1953
Author(s):  
Phil Holdship ◽  
Pierre Bonnand ◽  
David Price ◽  
Paul Watson
Keyword(s):  
Trace Elements ◽  
Trace Element ◽  
Flow Injection ◽  
Sample Introduction ◽  
Iron Meteorites ◽  
Ms Analysis ◽  
Sample Introduction System ◽  
Icp Ms ◽  
Micro Flow ◽  
High Matrix

The coupling of a micro-flow injection sample introduction system to a highly versatile quadrupole ICP-MS (FI-ICP-MS) has been demonstrated to achieve accurate and precise trace element measurements for several iron meteorites.

ICP-MS method for Pu and Np isotopes in population monitoring by a micro-flow injection sample introduction system

2014 ◽  
Vol 29 (9) ◽  
pp. 1708-1713 ◽  
Author(s):  
Youqing Shi ◽  
Xiongxin Dai ◽  
Chunsheng Li ◽  
Roxanne Collins ◽  
Sheila Kramer-Tremblay ◽  
...  
Keyword(s):  
Flow Injection ◽  
Population Monitoring ◽  
Sample Introduction ◽  
Radiological Emergency ◽  
Sample Introduction System ◽  
System P ◽  
Icp Ms ◽  
Micro Flow ◽  
Emergency Monitoring

A micro-flow injection ICP-MS method was applied to radiological emergency monitoring of Plutonium and Neptunium.

Improved validation for single particle ICP-MS analysis using a pneumatic nebulizer / microdroplet generator sample introduction system for multi-mode nanoparticle determination

2020 ◽  
Vol 1099 ◽  
pp. 16-25 ◽  
Author(s):  
Daniel Rosenkranz ◽  
Fabian L. Kriegel ◽  
Emmanouil Mavrakis ◽  
Spiros A. Pergantis ◽  
Philipp Reichardt ◽  
...  
Keyword(s):  
Single Particle ◽  
Sample Introduction ◽  
Ms Analysis ◽  
Sample Introduction System ◽  
Icp Ms ◽  
Pneumatic Nebulizer ◽  
Multi Mode

μ-dDIHEN: a new micro-flow liquid sample introduction system for direct injection nebulization in ICP-MS

2019 ◽  
Vol 34 (8) ◽  
pp. 1553-1563 ◽  
Author(s):  
Pascale Louvat ◽  
Mickaël Tharaud ◽  
Matthieu Buisson ◽  
Claire Rollion-Bard ◽  
Marc F. Benedetti
Keyword(s):  
Direct Injection ◽  
Small Sample ◽  
Sample Introduction ◽  
Liquid Sample ◽  
Flow Rates ◽  
Sample Introduction System ◽  
Icp Ms ◽  
Micro Flow ◽  
Liquid Sample Introduction ◽  
Stable Flow

The μ-dDIHEN feeds low and stable flow rates to the ICP-MS, allowing for analyses of small sample volumes (<100 μL) in various applications.

Trace elements distribution in tropical tree rings through high-resolution imaging using LA-ICP-MS analysis

2021 ◽  
Vol 68 ◽  
pp. 126872
Author(s):  
Renata S. Amais ◽  
Pedro S. Moreau ◽  
Danielle S. Francischini ◽  
Rafael Magnusson ◽  
Giuliano M. Locosselli ◽  
...  
Keyword(s):  
Trace Elements ◽  
High Resolution ◽  
Tree Rings ◽  
Tropical Tree ◽  
High Resolution Imaging ◽  
Ms Analysis ◽  
Icp Ms ◽  
Resolution Imaging

Covellite of the Semenov-2 hydrothermal field (13°31.13′ N, Mid-Atlantic Ridge): Enrichment in trace elements according to LA ICP MS analysis

2017 ◽  
Vol 473 (1) ◽  
pp. 291-295 ◽  
Author(s):  
I. Yu. Melekestseva ◽  
V. V. Maslennikov ◽  
S. P. Maslennikova ◽  
L. V. Danyushevsky ◽  
R. Large
Keyword(s):  
Trace Elements ◽  
Hydrothermal Field ◽  
Ms Analysis ◽  
Icp Ms ◽  
Mid Atlantic Ridge

Laser ablation ICP MS trace element composition of native gold from the Abitibi Greenstone belt, Timmins Ontario.

2021 ◽  
Author(s):  
John D. Greenough ◽  
Alejandro Velasquez ◽  
Mohamed Shaheen ◽  
Joel Gagnon ◽  
Brian J. Fryer ◽  
...  
Keyword(s):  
Trace Elements ◽  
Laser Ablation ◽  
Trace Element ◽  
Greenstone Belt ◽  
Native Gold ◽  
Internal Standard ◽  
Gold Deposits ◽  
Ore Deposits ◽  
Abitibi Greenstone Belt ◽  
Icp Ms

Trace elements in native gold provide a “fingerprint” that tends to be unique to individual gold deposits. Fingerprinting can distinguish gold sources and potentially yield insights into geochemical processes operating during gold deposit formation. Native gold grains come from three historical gold ore deposits; Hollinger, McIntyre (quartz-vein ore), and Aunor near Timmins, Ontario, at the western end of the Porcupine gold camp and the south-western part of the Abitibi greenstone belt. Laser-ablation, inductively-coupled plasma mass spectrometry (LA ICP MS) trace element concentrations were determined on 20 to 25 µm wide, 300 µm long rastor trails in ~ 60 native gold grains. Analyses used Ag as an internal standard with Ag and Au determined by a scanning electron microscope with an energy dispersive spectrometer. The London Bullion Market AuRM2 reference material served as the external standard for 21 trace element analytes (Al, As, Bi, Ca, Cr, Cu, Fe, Mg, Mn, Ni, Pb, Pd, Pt, Rh, Sb, Se, Si, Sn, Te, Ti, Zn; Se generally below detection in samples). Trace elements in native gold associate according to Goldschmidt’s classification of elements strongly suggesting that element behavior in native Au is not random. Such element behavior suggests that samples from each Timmins deposit formed under similar but slightly variable geochemical conditions. Chalcophile and siderophile elements provide the most compelling fingerprints of the three ore deposits and appear to be mostly in solid solution in Au. Lithophile elements are not very useful for distinguishing these deposits and element ABSTRACT CUT OFF BY SOFTWARE

Dating polymetamorphism using titanite: Linking trace elements, textures, and ages

2021 ◽  
Author(s):  
Jesse Walters ◽  
Alicia Cruz-Uribe ◽  
Won Joon Song ◽  
Joshua Stone ◽  
Hanna Brooks ◽  
...  
Keyword(s):  
Trace Elements ◽  
Trace Element ◽  
Bulk Composition ◽  
Granulite Facies ◽  
Compositional Variation ◽  
Excimer Laser Ablation ◽  
Eu Anomaly ◽  
Fluid Infiltration ◽  
Icp Ms ◽  
The University

&lt;p&gt;Here we present titanite U-Pb dates from two banded calc silicate gneisses (SSP18-1A and 1B) from western Maine. Mineral textures and compositions display multiple phases of metamorphism. The peak lower granulite facies assemblage is Di + Kfs + Pl + Ttn, with little to no calcite present. Late Czo + Tr replaces Di + Pl, suggesting an influx of X&lt;sub&gt;H2O&lt;/sub&gt; &gt; 0.90 fluids. Nearby metapelites show the transition from sillimanite-bearing to muscovite-bearing assemblages, indicating that fluid infiltration may be widespread. Compositional maps of clinopyroxene in SSP18-1B show fracturing and rehealing of early Fe-rich diopside with late Mg-rich diopside. Both samples exhibit overprinting of An-rich plagioclase by increasingly Ab-rich plagioclase. Titanite grains in both samples exhibit BSE textures and compositional variation consistent with multiple phases of growth and dissolution-reprecipitation reactions.&lt;/p&gt;&lt;p&gt;Titanite trace element and U-Pb data were collected by LA-ICP-MS at the University of Maine using an ESI NWR193&lt;sup&gt;UC&lt;/sup&gt; excimer laser ablation system coupled to an Agilent 8900 ICP-MS. Single spot ages range from 280 to 400 Ma with 12-20 Ma propagated 2SE. Four composition-date domains are identified in SSP18-1B: A. 400 &amp;#177; 8 Ma (dark BSE cores), B. 372 &amp;#177; 4 Ma (bright BSE cores), C. 342 &amp;#177; 6 Ma (bright BSE cores, no Eu anomaly), and D. 302 &amp;#177; 3 Ma (dark BSE rims, low LREE). Titanite Fe and Y concentrations increase with decreasing date, whereas Sr concentrations decrease. In clinopyroxene, Fe and Y decrease between high Fe-diopside and late Mg-diopside, placing the fracturing and rehealing events between 400 and 372 Ma. Strontium concentrations in titanite decrease between subsequent generations of plagioclase, diopside, and titanite, suggesting a continual fractionation of Sr from the reactive bulk composition. Low LREE in ca. 300 Ma titanite domains in both samples are consistent with the formation of texturally late allanite and clinozoisite, thus constraining the timing of the high X&lt;sub&gt;H2O&lt;/sub&gt; fluid infiltration event. Zr-in-titanite temperatures for rims in the quartz-bearing SSP18-1B give a weighted mean T of 764 &amp;#176;C at 4.5 GPa, consistent with the muscovite-absent sillimanite-bearing assemblage in garnet cores from metapelite samples. However, the 100-150 &amp;#176;C lower Grt-Bt temperatures for metapelites are not consistent with peak metamorphic phase equilibria. Our data demonstrate the utility of linking titanite textures and trace element concentrations with those of other minerals to reveal past metamorphic and deformational events. Additionally, we show that titanite may reliably preserve U and Pb isotopic ratios, trace elements, and textures over subsequent high-T metamorphic events.&lt;/p&gt;

scholarly journals Trace elements geochemistry in high-incidence areas of liver-related diseases, northwestern Ethiopia

2019 ◽  
Vol 42 (5) ◽  
pp. 1235-1254
Author(s):  
Jemal Ahmed
Keyword(s):  
Trace Elements ◽  
Trace Element ◽  
Selenium Deficiency ◽  
Stream Sediments ◽  
Low Grade ◽  
Geochemical Background ◽  
Water Stream ◽  
Icp Ms ◽  
History Of ◽  
Trace Element Contents

Abstract This paper reports the results of trace elements geochemistry from Tigray national state, northwestern Ethiopia. The area is part of the Arabian-Nubian Shield, where the dominant exposure is low-grade metamorphic rocks and has a long history of liver-related diseases. The increase in the number of liver-related disease patients of the area has been an environmental health issue of national concern. The aim of the study is to determine the level of trace element concentrations and distributions in water and stream sediments of the area and identify the possible sources in relation to human health. Water, stream sediment and rocks samples (20 water, 20 stream sediments, and 6 rock samples) were collected in March 2011 and analyzed for major and trace element contents using ICP-MS, ICP-OES, ion Chromatography, and XRF methods. Bromine, aluminum, fluorine, arsenic, and nitrate values exceed the WHO maximum acceptable concentration (MAC) for drinking purpose. Bromine ranges from 0.11 to 1.48 mg/l show higher values in all samples, and fluorine ranges from 0.21 to 16.49 mg/l show higher values in 20% of the samples. Other trace elements are aluminum—30%, arsenic—10%, and nitrate (NO3)—10%, and they are examples of elements which have above MAC for drinking water. Selenium deficiency may be the other problematic element in the area for which its deficiency is associated with liver damage and heart muscle disorder. The concentration of cobalt and chromium exceeded world geochemical background value in average shale at most sample stations indicated that these stations were in potential risk.

Sign in / Sign up

Export Citation Format

Share Document