N-Carbamoylmaleimide-treated carbon dots: stabilizing the electrochemical intermediate and extending it for the ultrasensitive detection of organophosphate pesticides

Nanoscale ◽  
2018 ◽  
Vol 10 (41) ◽  
pp. 19390-19398 ◽  
Author(s):  
Jinjin Xu ◽  
Chaofan Yu ◽  
Tao Feng ◽  
Mingyue Liu ◽  
Fengting Li ◽  
...  

N-Carbamoylmaleimide-treated CDs are used for the sensing of by enriching the electrochemical intermediate through Michael addition for the first time.

2021 ◽  
Author(s):  
Lijuan Liu ◽  
Shengting Zhang ◽  
Xiaodan Zheng ◽  
Hongmei Li ◽  
Qi Chen ◽  
...  

Fusobacterium nucleatum has been employed for the first time to synthesize fluorescent carbon dots which could be applied for the determination of Fe3+ ions in living cells and bioimaging in vitro and in vivo with excellent biocompatibility.


2021 ◽  
Vol 355 ◽  
pp. 129443
Author(s):  
Guangming Li ◽  
Chen Liu ◽  
Xingcai Zhang ◽  
Pengjie Luo ◽  
Guimiao Lin ◽  
...  

Synlett ◽  
2018 ◽  
Vol 29 (12) ◽  
pp. 1589-1592 ◽  
Author(s):  
Abolfazl Olyaei ◽  
Mahnaz Saraei ◽  
Reyhaneh Khoeiniha

A high-yielding cyclocondensation of 4-hydroxycoumarin, phenylglyoxal monohydrate, and heteroarylamines proceeds without catalysis, which gives novel functionalized furo[3,2-c]coumarins and heteroarylamino alkylation of coumarin products in acetonitrile under reflux, is reported for the first time. This tandem process involves sequentially an aldol condensation, Michael addition, a ring closure, and dehydration reaction.


2018 ◽  
Vol 6 (42) ◽  
pp. 6842-6847 ◽  
Author(s):  
Panpan Gai ◽  
Shuxia Zhang ◽  
Wen Yu ◽  
Haiyin Li ◽  
Feng Li

A new light-driven self-powered biosensor based on a photoelectrochemical enzymatic fuel cell was proposed for the ultrasensitive detection of organophosphate pesticides.


2019 ◽  
Vol 15 ◽  
pp. 1262-1267 ◽  
Author(s):  
Jia Gao ◽  
Ming-Xue Wu ◽  
Dihua Dai ◽  
Zhi Cai ◽  
Yue Wang ◽  
...  

Fluorescent N-doped carbon dots (CN-dots) covalently functionalized with carboxylatopillar[5]arene (CP[5]), namely CCDs, have been prepared the first time. Compared with CN-dots without pillarene units, the newly constructed fluorescent CCDs could recognize Fe3+ with high selectivity. Therefore, such CCDs can potentially serve as a promising chemical sensor for Fe3+ ions.


2018 ◽  
Vol 17 (2) ◽  
pp. 245-255 ◽  
Author(s):  
S. A. R. Shahamirifard ◽  
M. Ghaedi ◽  
M. Montazerozohori ◽  
A. Masoudiasl

In this work, the use of carbon dots (CDs) as a complexing agent and sensitizer in a polymeric matrix for determination of copper(ii) by UV-vis spectroscopy is reported for the first time.


ACS Omega ◽  
2019 ◽  
Vol 4 (25) ◽  
pp. 21431-21438 ◽  
Author(s):  
Lai-Di Xu ◽  
Qing Zhang ◽  
Shou-Nian Ding ◽  
Jing-Juan Xu ◽  
Hong-Yuan Chen

2020 ◽  
Vol 56 (49) ◽  
pp. 6692-6695
Author(s):  
Jiao Yang ◽  
Qian Xia ◽  
Longhua Guo ◽  
Fang Luo ◽  
Yongqiang Dong ◽  
...  

CDs have been used to quench the ECL of Ru(bpy)32+–TPA for the first time and a sensitive biosensor was developed.


Nanomaterials ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 464 ◽  
Author(s):  
Sizhe Hu ◽  
Kai Jiang ◽  
Yuci Wang ◽  
Sui Wang ◽  
Zhongjun Li ◽  
...  

Carbon dots (CDs) with a room temperature phosphorescent (RTP) feature have attracted considerable interest in recent years due to their fundamental importance and promising applications. However, the reported matrix-free RTP CDs only show short-wavelength (green to yellow) emissions and have to be triggered by ultraviolet (UV) light (below 400 nm), limiting their applications in certain fields. Herein, visible-light-excited matrix-free RTP CDs (named AA-CDs) with a long-wavelength (orange) emission are reported for the first time. The AA-CDs can be facilely prepared via a microwave heating treatment of L-aspartic acid (AA) in the presence of ammonia and they emit unique orange RTP in the solid state with visible light (420 nm) excitation just being switched off. Through the studies of the carbonization process, the C=O and C=N containing moieties in the AA-CDs are confirmed to be responsible for the observed RTP emission. Finally, the applications of AA-CDs in information encryption and anti-counterfeiting were preliminarily demonstrated.


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