scholarly journals An AIE fluorescent switch with multi-stimuli responsive properties and applications for quantitatively detecting pH value, sulfite anion and hydrostatic pressure

2019 ◽  
Vol 3 (6) ◽  
pp. 1052-1061 ◽  
Author(s):  
Tingting Lin ◽  
Xing Su ◽  
Kai Wang ◽  
Minjie Li ◽  
Hongwei Guo ◽  
...  

An AIE fluorescent switch exhibited multi-parameter detection properties for pH, sulfite anion and pressure with good linear relationships.

1975 ◽  
Vol 5 (4) ◽  
pp. 592-598 ◽  
Author(s):  
R. A. Woessner ◽  
C. B. Davey ◽  
B. E. Crabtree ◽  
J. D. Gregory

Nutrient content (P, K, Ca, Mg) of the aboveground tissue of a series of full-sib loblolly crosses was found to vary by genotype. Variability among and within seed sources is indicated for the ability to absorb Ca and Mg. Absorption of P and K was not found to be dependent on seed source, but the full-sib crosses differ. Good linear relationships were found between plant dry weight and weight of element but not between plant dry weight and percentage of element. Certain highly efficient crosses can be expected to be good producers of dry matter on sites low in available nutrients.


RSC Advances ◽  
2015 ◽  
Vol 5 (76) ◽  
pp. 62091-62100 ◽  
Author(s):  
Jinjin Cheng ◽  
Guorong Shan ◽  
Pengju Pan

Poly(N-isopropylacrylamide-co-acrylamide-co-maleic acid) (PNIPAM-AM-MA) hydrogel, which can make the Cu2+ adsorption process stimuli-responsive under temperature and pH value control, has been synthesized by free radical polymerization.


2020 ◽  
Vol 16 ◽  
pp. 2017-2025
Author(s):  
Goutam Ghosh ◽  
Gustavo Fernández

Peptide-based biopolymers represent highly promising biocompatible materials with multiple applications, such as tailored drug delivery, tissue engineering and regeneration, and as stimuli-responsive materials. Herein, we report the pH- and concentration-dependent self-assembly and conformational transformation of the newly synthesized octapeptide PEP-1. At pH 7.4, PEP-1 forms β-sheet-rich secondary structures into fractal-like morphologies, as verified by circular dichroism (CD), Fourier-transform infrared (FTIR) spectroscopy, thioflavin T (ThT) fluorescence spectroscopy assay, and atomic force microscopy (AFM). Upon changing the pH value (using pH 5.5 and 13.0), PEP-1 forms different types of secondary structures and resulting morphologies due to electrostatic repulsion between charged amino acids. PEP-1 can also form helical or random-coil secondary structures at a relatively low concentration. The obtained pH-sensitive self-assembly behavior of the target octapeptide is expected to contribute to the development of novel drug nanocarrier assemblies.


2014 ◽  
Vol 2 (35) ◽  
pp. 7326-7335 ◽  
Author(s):  
Xiaoyun Liu ◽  
Xiuqin Wang ◽  
Liusheng Zha ◽  
Danli Lin ◽  
Jianmao Yang ◽  
...  

Plasmonic property and SERS efficiency of the silver nanoparticles embedded within the microgels with an interpenetrating polymer network structure can be reversibly tuned by temperature and pH value.


2019 ◽  
Vol 9 (1) ◽  
pp. 131
Author(s):  
Haifeng Sun ◽  
Ling Wang ◽  
Hao Zhang ◽  
Ang Wu ◽  
Juanhua Zhu ◽  
...  

The physico-chemical parameters including pH and viscosity, and the fluorescence signal induced by fluorescent compounds presenting in yogurts such as riboflavin and porphyrin were measured during one week’s storage at room temperature when five brands of yogurt samples were exposed to ambient air. The fluorescence spectra of yogurt showed four evident emission peaks, 525 nm, 633 nm, 661 nm, and 672 nm. To quantitatively investigate the quality of yogurt during deteriorating, a calculating method of the average rate of change (ARC) was proposed to study the relative change of fluorescence intensity in the spectral range of 600 to 750 nm associated with porphyrin and chlorin compounds. During the storage, the time evolution of two ARC, pH value, and viscosity were regular. Moreover, the ARC showed a good linear relationship with pH value and viscosity of yogurt. Further, multiple linear regression (MLR) models using two ARC as independent variables were developed to verify the dependence of fluorescence signal with pH value and viscosity, which showed a good linear relationship with an R-square of more than 85% for each class of yogurt. The results demonstrate that fluorescence spectra have a great potential to predict the quality of yogurt.


2011 ◽  
Vol 7 ◽  
pp. 204-209 ◽  
Author(s):  
Sabrina Gingter ◽  
Ella Bezdushna ◽  
Helmut Ritter

In the present work we report the enantioselective recognition of water soluble stimuli-responsive polymers bearing phenylalanine moieties via host-guest interaction with β-cyclodextrin and randomly-methylated-β-cyclodextrin (RAMEB-CD). We synthesised N-acryloyl-D/L-phenylalanine monomers (2 D , 2 L ) which were then copolymerised under free radical conditions with N-isopropylacrylamide (NIPAAm). The resulting copolymers 3 D and 3 L exhibit a lower critical solution temperature (LCST) of 25 °C. As a further benefit, the presence of a free carboxylic group in the copolymer system gives a high sensitivity to the pH value in respect to the LCST value. The enantioselective recognition of the side groups of copolymers 3 D and 3 L and their solubility behaviour were investigated by dynamic light scattering and 2D NMR spectroscopy, respectively.


2016 ◽  
Vol 44 ◽  
pp. 252-264
Author(s):  
Roxanne Gostynski ◽  
Marrigje Marianne Conradie ◽  
Ren Yuan Liu ◽  
Jeanet Conradie

The reduction of the MIII/MII metal couple of complexes Cr (β-diketonato)3, Fe (β-diketonato)3 and Mn (β-diketonato)3 is reviewed and compared. The ease of reduction of the MIII/MII couple of M(β-diketonato)3 complexes increases according to the metal sequence Cr (β-diketonato)3 < Fe (β-diketonato)3 < Mn (β-diketonato)3 (with the most positive reduction potential). Good linear relationships obtained between the reduction potential and different electronic parameters related to the β-diketonato ligand on these MIII(β-diketonato)3 complexes, show that the ease of reduction of the MIII/MII couple increases with decreasing acidic strength (pKa) of the respective β-diketone ligands. It also increases with increasing total group electronegativity of the R and R' groups on the respective β-diketonato ligand (RCOCHCOR')− of the M(β-diketonato)3 complexes, (χR + χR'), as well as with an increase in the total Hammett sigma meta constants (σR + σR'), and also with increasing value of the Lever ligand electronic parameter (EL) of ligand (RCOCHCOR')−.


2013 ◽  
Vol 46 (16) ◽  
pp. 6541-6547 ◽  
Author(s):  
Matthias Reinhardt ◽  
Joachim Dzubiella ◽  
Marcus Trapp ◽  
Philipp Gutfreund ◽  
Martin Kreuzer ◽  
...  

2020 ◽  
Vol 2020 ◽  
pp. 1-14
Author(s):  
Long Xu ◽  
Fusheng Zha ◽  
Congmin Liu ◽  
Bo Kang ◽  
Jingjing Liu ◽  
...  

The carbonation behavior of lime-stabilized expansive soil is important for assessing the stabilization efficiency from the perspective of durability. In this study, the accelerated carbonation tests, measurement of pH value distribution, and the free swell ratio tests were conducted to investigate the evolutions of carbonation depth, carbonation extent, and expansive potential of lime-stabilized expansive soil. XRD, MIP, and SEM techniques were adopted as supplements to reveal the carbonation mechanism. Results demonstrated that the carbonation depth of lime-stabilized expansive soil increased significantly as time elapsed; however, the rate of increase reduced when the carbonation time increased. Higher carbonation depth was obtained at higher temperature and CO2 concentration and lower relative humidity, which was described by an empirical model. Fully, partly, and noncarbonated zones were subsequently presented with an increase in the depth of the soil. The expansive potential of lime-stabilized expansive soil was partially recovered during carbonation. The obtained linear relationships between the free swell ratio and pH value were adopted to describe the evolution of expansive behavior with carbonation time and depth. In microstructural analysis, the conversion of portlandite into calcium carbonate was significant, which resulted in changes in microstructure and controlled the carbonation behavior.


2019 ◽  
Vol 7 (29) ◽  
pp. 9102-9111 ◽  
Author(s):  
Lingyun Wang ◽  
Wei Xiong ◽  
Hao Tang ◽  
Derong Cao

A solid state stimuli-responsive fluorescent switch based on spiro[fluorene-9,9′-xanthene]-spiropyran (SFX-2SP) was reported.


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