scholarly journals Thermal conductivity of polyvinylpolymethylsiloxane aerogels with high specific surface area

RSC Advances ◽  
2019 ◽  
Vol 9 (14) ◽  
pp. 7833-7841 ◽  
Author(s):  
Lukai Wang ◽  
Junzong Feng ◽  
Yonggang Jiang ◽  
Liangjun Li ◽  
Jian Feng

The traditional SiO2 aerogels are difficult to apply in the fields of energy storage and heat insulation due to their poor mechanical properties.

Metals ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 345 ◽  
Author(s):  
Lianzan Yang ◽  
Yongyan Li ◽  
Zhifeng Wang ◽  
Weimin Zhao ◽  
Chunling Qin

High-entropy alloys (HEAs) present excellent mechanical properties. However, the exploitation of chemical properties of HEAs is far less than that of mechanical properties, which is mainly limited by the low specific surface area of HEAs synthesized by traditional methods. Thus, it is vital to develop new routes to fabricate HEAs with novel three-dimensional structures and a high specific surface area. Herein, we develop a facile approach to fabricate nanoporous noble metal quasi-HEA microspheres by melt-spinning and dealloying. The as-obtained nanoporous Cu30Au23Pt22Pd25 quasi-HEA microspheres present a hierarchical porous structure with a high specific surface area of 69.5 m2/g and a multiphase approximatively componential solid solution characteristic with a broad single-group face-centered cubic XRD pattern, which is different from the traditional single-phase or two-phase solid solution HEAs. To differentiate, these are named quasi-HEAs. The synthetic strategy proposed in this paper opens the door for the synthesis of porous quasi-HEAs related materials, and is expected to promote further applications of quasi-HEAs in various chemical fields.


2019 ◽  
Vol 7 (16) ◽  
pp. 9656-9664 ◽  
Author(s):  
Nadeem Hussain ◽  
Wenjuan Yang ◽  
Jianmin Dou ◽  
Yanan Chen ◽  
Yitai Qian ◽  
...  

Two-dimensional (2D) nanomaterials with a high specific surface area and mesoporous nature are attractive and have wide applications in catalysis, energy storage systems, etc.


Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 2074
Author(s):  
Huibin Cheng ◽  
Xiaoli Sun ◽  
Baoquan Huang ◽  
Liren Xiao ◽  
Qinghua Chen ◽  
...  

Tuning the high properties of segregated conductive polymer materials (CPCs) by incorporating nanoscale carbon fillers has drawn increasing attention in the industry and academy fields, although weak interfacial interaction of matrix-filler is a daunting challenge for high-loading CPCs. Herein, we present a facile and efficient strategy for preparing the segregated conducting ultra-high molecular weight polyethylene (UHMWPE)-based composites with acceptable mechanical properties. The interfacial interactions, mechanical properties, electrical properties and electromagnetic interference (EMI) shielding effectiveness (SE) of the UHMWPE/conducting carbon black (CCB) composites were investigated. The morphological and Raman mapping results showed that UHMWPE/high specific surface area CCB (h-CCB) composites demonstrate an obviously interfacial transition layer and strongly interfacial adhesion, as compared to UHMWPE/low specific surface area CCB (l-CCB) composites. Consequently, the high-loading UHMWPE/h-CCB composite (beyond 10 wt% CCB dosage) exhibits higher strength and elongation at break than the UHMWPE/l-CCB composite. Moreover, due to the formation of a densely stacked h-CCB network under the enhanced filler-matrix interfacial interactions, UHMWPE/h-CCB composite possesses a higher EMI SE than those of UHMWPE/l-CCB composites. The electrical conductivity and EMI SE value of the UHMWPE/h-CCB composite increase sharply with the increasing content of h-CCB. The EMI SE of UHMWPE/h-CCB composite with 10 wt% h-CCB is 22.3 dB at X-band, as four times that of the UHMWPE/l-CCB composite with same l-CCB dosage (5.6 dB). This work will help to manufacture a low-cost and high-performance EMI shielding material for modern electronic systems.


2019 ◽  
Vol 7 (15) ◽  
pp. 9163-9172 ◽  
Author(s):  
Lifeng Zhang ◽  
Yu Guo ◽  
Kechao Shen ◽  
Jinghao Huo ◽  
Yi Liu ◽  
...  

Polypyrrole (PPy)-derived porous carbons with an ion-matching micropore diameter exhibit ultra-high specific surface area and capacitance when used in supercapacitors.


2019 ◽  
Vol 5 (2) ◽  
pp. 16 ◽  
Author(s):  
Nikolas Natter ◽  
Nikolaos Kostoglou ◽  
Christian Koczwara ◽  
Christos Tampaxis ◽  
Theodore Steriotis ◽  
...  

Several crucial problems, such as rapid population growth and extended demands for food, water and fuels, could lead to a severe lack of clean water and an energy crisis in the coming decade. Therefore, low-cost and highly-efficient technologies related to filtration of alternative water supplies (e.g., purification of wastewater and water-rich liquids) and advanced energy storage (e.g., supercapacitors) could play a crucial role to overcome such challenges. A promising class of solid materials for these purposes is exfoliated graphene, and more specifically, its nanoporous forms that exhibit large specific surface areas and pore volumes. In the current work, two plasma-exfoliated graphene-based materials with distinctive morphological and porosity features, including non-porous and low-specific surface area platelets versus nanoporous and high-specific surface area flakes, were tested as filters for water purification purposes (i.e., decolourization and deacidification) and as electrodes for supercapacitors (i.e., ion electrosorption). The findings of this study suggest that a nanoporous and large specific surface area graphene-based material promotes the water purification behaviour by removing contaminants from water-based solutions as well as the energy storage performance by confining ions of aqueous electrolytes.


2020 ◽  
Vol 8 (26) ◽  
pp. 12887-12927 ◽  
Author(s):  
Xiang Yu ◽  
Weiyuan Liang ◽  
Chenyang Xing ◽  
Keqiang Chen ◽  
Jianming Chen ◽  
...  

A rising kind of 2D pnictogens has drawn a great deal of attention in the field of catalytic application owing to their high specific surface area, mechanical properties, biocompatibility, optical and electrical performance.


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