Fast kinetics of Mg2+/Li+ hybrid ions in a polyanion Li3V2(PO4)3 cathode in a wide temperature range

2019 ◽  
Vol 7 (16) ◽  
pp. 9968-9976 ◽  
Author(s):  
Muhammad Rashad ◽  
Hongzhang Zhang ◽  
Xianfeng Li ◽  
Huamin Zhang

A Li3V2(PO4)3 based Mg2+/Li+ hybrid battery with excellent performance both at room temperature and low temperatures (0, −10, −20, −30, and −40 °C) is presented.

Author(s):  
Renata Karpicz ◽  
Nina Ostapenko ◽  
Yura Ostapenko ◽  
Yaroslava Polupan ◽  
Igor Lazarev ◽  
...  

Fluorescence spectra as well as fluorescence decay kinetics of hot-pressed and sublimated films of stilbene has been studied in wide temperature range, from 15 K up to room temperature. Fluorescence...


Science ◽  
2020 ◽  
Vol 367 (6475) ◽  
pp. 309-312 ◽  
Author(s):  
Yo Machida ◽  
Nayuta Matsumoto ◽  
Takayuki Isono ◽  
Kamran Behnia

Allotropes of carbon, such as diamond and graphene, are among the best conductors of heat. We monitored the evolution of thermal conductivity in thin graphite as a function of temperature and thickness and found an intimate link between high conductivity, thickness, and phonon hydrodynamics. The room-temperature in-plane thermal conductivity of 8.5-micrometer-thick graphite was 4300 watts per meter-kelvin—a value well above that for diamond and slightly larger than in isotopically purified graphene. Warming enhances thermal diffusivity across a wide temperature range, supporting partially hydrodynamic phonon flow. The enhancement of thermal conductivity that we observed with decreasing thickness points to a correlation between the out-of-plane momentum of phonons and the fraction of momentum-relaxing collisions. We argue that this is due to the extreme phonon dispersion anisotropy in graphite.


1975 ◽  
Vol 30 (3) ◽  
pp. 381-382 ◽  
Author(s):  
A. Abou- Zeid ◽  
G. Schneider

Various donor doping of ZnSb is investigated. Te-doping yields the most stable n-type crystals at room temperature; the samples show p-type behaviour at low temperatures. The influence of surface effects is demonstrated. It was possible to prepare n-type ZnSb for the whole temperature range.


Our knowledge of the temperature variation of the principal susceptibilities of paramagnetic crystals is as yet fragmentary. The principal susceptibilities of a number of paramagnetic crystals have been determined by Finke and by Rabi at room temperature but the first measurements on orientated crystals over any range of temperature were those of Foëx. He has published the principal susceptibilities of siderose (a mineral which is mainly ferrous carbonate but which contains appreciable quantities of the carbonates of manganese and other metals) over the range 87° to 400°K. and some measurements but not actual principal susceptibilities for manganese sulphate, MnSO 4 .4H 2 O. The writer measured the principal susceptibilities of cobalt ammonium sulphate and nickel sulphate, NiSO 4 . 7H 2 O over the temperature range 14°-290°K. and the writer and de Haas have published measurements on manganese ammonium sulphate crystals over the restricted range 14°-20° K. In addition Dupouy has repeated Foëx’s observations on siderose and has measured the principal susceptibilities of dialogite (a naturally occurring manganese carbonate) and oligist (Fe 2 O 3 ), all over a small range of temperature above 0° C. Quite recently Bartlett has employed Rabi’s method to determine the principal susceptibilities of the following compounds, CoSO 4 . 7H 2 O, CoSO 4 . (NH 4 ) 2 SO 4 . 6H 2 O, CoSO 4 . K 2 SO 4 . 6H 2 O, CuSO 4 . (NH 4 ) 2 SO 4 . 6H 2 O CuSO 4 . K 2 SO 4 . 6H 2 O, NiSO 4 . (NH 4 ) 2 SO 4 . 6H 2 O over the temperature range —45° to +55°C. In the writer’s opinion, however, Bartlett’s procedure is liable to several objections.


1966 ◽  
Vol 44 (20) ◽  
pp. 2435-2443 ◽  
Author(s):  
P. W. M. Jacobs ◽  
A. Russell-Jones

The infrared spectrum of hydrazine perchlorate hemihydrate (HPH) has been determined and an assignment of the absorption bands made. Invacuo, HPH will partially dehydrate even at room temperature; when heated the remainder of the half-mole of water is lost at 61 °C. The dehydrated salt melts at 138 °C and decomposition ensues. The kinetics of decomposition may be followed in the temperature range 180–280 °C. The activation energy is 36.3 kcal/mole. At low temperatures the decomposition is represented by the chemical equation[Formula: see text]but when the temperature is high enough the rate of decomposition of the ammonium perchlorate formed becomes appreciable also. Possible reaction mechanisms are discussed.


2020 ◽  
Vol 56 (8) ◽  
pp. 1187-1190 ◽  
Author(s):  
Tasrina Munmun ◽  
Arif Md. Rashedul Kabir ◽  
Yukiteru Katsumoto ◽  
Kazuki Sada ◽  
Akira Kakugo

Trimethylamine N-oxide (TMAO) is found to be effective in regulating the kinetics of interaction between microtubules and kinesins over a wide temperature range.


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