Ultrafast “end-on”-to-“side-on” binding-mode isomerization of an iron-carbon dioxide complex

Author(s):  
Steffen Straub ◽  
Peter Vöhringer

Carbon dioxide (CO2) binding by transition metals is a captivating phenomenon with tremendous impact in environmental science and technology, most notably, for establishing circular economies based on greenhouse gas emissions....

Author(s):  
Lisa Kemmerer

Cheap meat, dairy, and eggs are an illusion—we pay for each with depleted forests, polluted freshwater, soil degradation, and climate change. Diet is the most critical decision we make with regard to our environmental footprint—and what we eat is a choice that most of us make every day, several times a day. Dietary choice contributes powerfully to greenhouse gas emissions (GHGE) and water pollution. Animal agriculture is responsible for an unnerving quantity of greenhouse gas emissions. Eating animal products—yogurt, ice cream, bacon, chicken salad, beef stroganoff, or cheese omelets—greatly increases an individual’s contribution to carbon dioxide, methane, and nitrous oxide emissions. Collectively, dietary choice contributes to a classic “tragedy of the commons.” Much of the atmosphere’s carbon dioxide (CO2) is absorbed by the earth’s oceans and plants, but a large proportion lingers in the atmosphere—unable to be absorbed by plants or oceans (“Effects”). Plants are not harmed by this process, but the current overabundance of carbon dioxide in the atmosphere causes acidification of the earth’s oceans. As a result of anthropogenic carbon dioxide emissions, the “acidity of the world’s ocean may increase by around 170% by the end of the century,” altering ocean ecosystems, and likely creating an ocean environment that is inhospitable for many life forms (“Expert Assessment”). Burning petroleum also leads to wars that devastate human communities and annihilate landscapes and wildlife—including endangered species and their vital habitats. Additionally, our consumption of petroleum is linked with oil spills that ravage landscapes, shorelines, and ocean habitat. Oil pipelines run through remote, fragile areas—every oil tanker represents not just the possibility but the probability of an oil spill. As reserves diminish, our quest for fossil fuels is increasingly environmentally devastating: Canada’s vast reserves of tar sands oil—though extracted, transported, and burned only with enormous costs to the environment—are next in line for extraction. Consuming animal products creates ten times more fossil fuel emission per calorie than does consuming plant foods directly (Oppenlander 18). (This is the most remarkable given that plant foods are not generally as calorically dense as animal foods.) Ranching is the greatest GHGE offender.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Xue Hao ◽  
Yu Ruihong ◽  
Zhang Zhuangzhuang ◽  
Qi Zhen ◽  
Lu Xixi ◽  
...  

AbstractGreenhouse gas (GHG) emissions from rivers and lakes have been shown to significantly contribute to global carbon and nitrogen cycling. In spatiotemporal-variable and human-impacted rivers in the grassland region, simultaneous carbon dioxide, methane and nitrous oxide emissions and their relationships under the different land use types are poorly documented. This research estimated greenhouse gas (CO2, CH4, N2O) emissions in the Xilin River of Inner Mongolia of China using direct measurements from 18 field campaigns under seven land use type (such as swamp, sand land, grassland, pond, reservoir, lake, waste water) conducted in 2018. The results showed that CO2 emissions were higher in June and August, mainly affected by pH and DO. Emissions of CH4 and N2O were higher in October, which were influenced by TN and TP. According to global warming potential, CO2 emissions accounted for 63.35% of the three GHG emissions, and CH4 and N2O emissions accounted for 35.98% and 0.66% in the Xilin river, respectively. Under the influence of different degrees of human-impact, the amount of CO2 emissions in the sand land type was very high, however, CH4 emissions and N2O emissions were very high in the artificial pond and the wastewater, respectively. For natural river, the greenhouse gas emissions from the reservoir and sand land were both low. The Xilin river was observed to be a source of carbon dioxide and methane, and the lake was a sink for nitrous oxide.


2018 ◽  
Vol 32 (1) ◽  
pp. 29-37 ◽  
Author(s):  
Robert Czubaszek ◽  
Agnieszka Wysocka-Czubaszek

AbstractDigestate from biogas plants can play important role in agriculture by providing nutrients, improving soil structure and reducing the use of mineral fertilizers. Still, less is known about greenhouse gas emissions from soil during and after digestate application. The aim of the study was to estimate the emissions of carbon dioxide (CO2) and methane (CH4) from a field which was fertilized with digestate. The gas fluxes were measured with the eddy covariance system. Each day, the eddy covariance system was installed in various places of the field, depending on the dominant wind direction, so that each time the results were obtained from an area where the digestate was distributed. The results showed the relatively low impact of the studied gases emissions on total greenhouse gas emissions from agriculture. Maximum values of the CO2and CH4fluxes, 79.62 and 3.049 µmol s−1m−2, respectively, were observed during digestate spreading on the surface of the field. On the same day, the digestate was mixed with the topsoil layer using a disc harrow. This resulted in increased CO2emissions the following day. Intense mineralization of digestate, observed after fertilization may not give the expected effects in terms of protection and enrichment of soil organic matter.


2020 ◽  
pp. 94-110
Author(s):  
N.V. Dvoeglazova ◽  
B.V. Chubarenko ◽  
Y.A. Kozlova

The increase in greenhouse gases in the atmosphere is influenced to a greater extent by a degree of development of industry, a growth of electrification, deforestation, and the burning of fuel for the production of heating and electricity. The contribution of emissions of each of these factors and the ratio of greenhouse gases in them should be taken into account when developing the measures to prevent climate change. According to calculations of emissions from the territory of the Kaliningrad region the burning of fuel and energy resources are supposed to be playing the main role in the greenhouse gas emission from the territory of the Kaliningrad region. In statistical reference books this activity is described as the “activities for the production and distribution of electricity, gas and water.” The usage of this fuel in the energy sector is increasing: from 1742.4 thousand tons of standard fuel in 1991 up to 2193.9 in 2016. Such little increase in total emissions is due to the general technology improvement in the country. Carbon dioxide makes up the bulk of greenhouse gas emissions from the territory of the Kaliningrad region. The percentage of the gases in the total volume is as follows: CO2 - 96.7%, CH4 - 1%, N2 O - 2.3%. Its emissions for the period from 2013 to 2016 varied from 3,757.4 in 2014 to 4,091.7 in 2015 thousand tons of standard fuel, reaching its maximum value in 2015. The estimate presented in this paper is a lower estimate, since it does not take into account emissions from industrial processes, leaks, land use, waste, etc., as well as from some categories of emission sources due to the lack of data on the use of fuel in the Kaliningrad region. Among other things, the calculations of emissions of carbon dioxide, methane and nitrous oxide from the use of fuel by vehicles in 2016, which have shown to be 1.86 times less than from burning of fossil fuels for the same year (2032.87 Gg CO2 eq. and 3914.79 Gg CO2 eq., respectively) and to account for 34.5% of the total emissions, have been made. Moreover, according to the methodology for calculating emissions the factor of carbon dioxide absorption by the region’s forests has been taken into account. The amount of carbon dioxide absorbed by forests has shown to be only 11.9% of the emissions of this gas during the combustion of boiler and furnace fuel.


Author(s):  
Natasha Doyle ◽  
◽  
Philiswa Mbandlwa ◽  
Sinead Leahy ◽  
Graeme Attwood ◽  
...  

This chapter aims to outline the strategy of using feed supplements for the reduction of greenhouse gas emissions (GHG) in ruminants, including methane (CH4), carbon dioxide and nitrous oxide, given that feed intake is an important variable in predicting these emissions. Focus will be given to direct-fed microbials, a term reserved for live microbes which can be supplemented to feed to elicit a beneficial response. The viability of such methods will also be analysed for their use in large scale on-farm operations.


2014 ◽  
Vol 3 (2) ◽  
pp. 252 ◽  
Author(s):  
Mohamed Mourad

Because of their high efficiency and low emissions, fuel cell vehicles are undergoing extensive research and development. When considering the introduction of advanced vehicles, a complete evaluation must be performed to determine the potential impact of a technology on carbon dioxide (CO2) and greenhouse gases emissions. However, the reduction of CO2 emission from the vehicle became the most important objective for all researches institutes of vehicle technologies worldwide. There interest recently to find unconventional methods to reduce greenhouse gas emission from vehicle to keep the environment clean. This paper offers an overview and simulation study to fuel cell vehicles, with the aim of introducing their main advantages and evaluates their influence on emissions of carbon dioxide from fuel cell vehicle and compares advanced propulsion technologies on a well-to-wheel energy basis by using current technology for conventional and fuel cell. The results indicate that the use of fuel cells, and especially fuel cells that consume hydrogen, provide a good attempt for enhancing environment quality and reducing greenhouse gas (GHG) emissions. Moreover, the emission reduction percentage of fuel cell vehicle reaches to 64% comparing to the conventional vehicle. Keywords: Fuel Cell Electric Vehicle, Performance, Simulation, Driving Cycle, CO2 Emissions, Greenhouse Gas Emissions, Fuel Consumption.


Chemosphere ◽  
2003 ◽  
Vol 52 (3) ◽  
pp. 609-621 ◽  
Author(s):  
Jari T. Huttunen ◽  
Jukka Alm ◽  
Anu Liikanen ◽  
Sari Juutinen ◽  
Tuula Larmola ◽  
...  

1998 ◽  
Vol 49 (1) ◽  
pp. 1 ◽  
Author(s):  
K. L. Weier

The quantities of greenhouse gases emitted into the atmosphere from sugarcane fields, and their contribution to the total emissions from Australian agriculture, have never been estimated with any degree of certainty. This review was conducted to collate the available information on greenhouse gas emissions from the Australian sugarcane crop. Estimates were made for the emissions of the 3 major greenhouse gases―carbon dioxide (CO2), methane (CH4), and nitrous oxide (N2O)―from known or suspected sources. Sinks for the sequestration of the gases also have been identified. CO2 was found to be emitted during burning of the crop and from trash-blanketed and bare sugarcane fields. Total emissions from these sources in the 1994 season were estimated at 7·6 Mt CO2-C/year. However, the sugarcane crop was identified as a major sink for C, with uptake by the crop in 1994 estimated at 13· 4 Mt CO2-C/year. N2O emanating from sugarcane soils via denitrification following application of fertiliser accounted for 45-78% of total gaseous N emissions. Estimates of N2O emissions from all land under sugarcane in 1994 totalled 4·4 kt N2O-N/year from denitrification with a further 6·3 kt N2O-N emitted from areas that are still burnt. This review suggests changes in management procedures that should limit the opportunities for denitrification in the soil and thus reduce N2O emissions. Methane evolution occurs during the smouldering phase, following burning of the crop, with production estimated at 6·7 kt CH4-C/year in 1994. CH4 oxidation in soil was identified as an important process for removal of atmospheric CH4, as were trash-blanketed soils. Although these figures are our best estimate of gaseous production from sugarcane fields, there still remains a degree of uncertainty due to sampling variability and because of the extrapolation to the entire sugarcane area. However, the coupling of new laser techniques with known micrometeorological methods will allow for a more precise sampling of greenhouse gas emissions over a larger area. Estimates would thus be more representative, resulting in a greater degree of confidence being placed in them by the sugar industry.


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