Fluorescence sensors for detection of water based on tetraphenylethene–anthracene possessing both solvatofluorochromic properties and aggregation-induced emission (AIE) characteristics

2021 ◽  
Vol 45 (9) ◽  
pp. 4164-4173
Author(s):  
Yuta Mise ◽  
Keiichi Imato ◽  
Takashi Ogi ◽  
Nao Tsunoji ◽  
Yousuke Ooyama

TPE-(An-CHO)4 has been developed as an SFC (solvatofluorochromism)/AIEE (aggregation-induced emission enhancement)-based fluorescence sensor for detection of water over a wide range from low to high water content regions in solvents.

2018 ◽  
Vol 42 (16) ◽  
pp. 13339-13350 ◽  
Author(s):  
Yousuke Ooyama ◽  
Rizumu Sagisaka ◽  
Toshiaki Enoki ◽  
Nao Tsunoji ◽  
Joji Ohshita

RS-1 and RS-2 have been developed as PET/AIEE hybrid fluorescence sensors for detection of water in the low and high water content regions in solvents.


2019 ◽  
Vol 48 (6) ◽  
pp. 2086-2092 ◽  
Author(s):  
Toshiaki Enoki ◽  
Yousuke Ooyama

9-Methyl pyrido[3,4-b]indole-boron trifluoride complex 9-MP-BF3 was developed as a colorimetric and ratiometric fluorescent sensor for the detection of water from the low- to high-water-content regions in solvents.


2021 ◽  
Vol 61 (3) ◽  
pp. 221-238

The main aim of this study was to optimize the QuEChERS methodology for the comprehensive determination of pesticide residues using a simple and inexpensive gas chromatography equipped with selective detectors working simultaneously (GC-ECD/NPD). The method was validated in accordance with the SANTE/11945/2015 guidelines. Representative fruit matrices were chosen from the commodities group with high water content (apples), and with high acidity and high water content (strawberry) for a 160 compounds in the range of 0.005−0.02 mg/kg. The accuracy of the method was as required (recovery: 70–120%, precision: below 20%) for 135 active substances in apples samples and 137 in strawberries samples. The main advantages of the methodology include: good detector response linearity (R2 above 0.995), low limits of detection (0.005 mg/kg for more than 20 compounds, 0.01 mg/kg for about 120 compounds), possibility of simultaneous determination of a wide range of compounds (including some “difficult” ones) without use of a single residue methods. The simultaneous use of two selective detectors allows to obtain more data during a single dose of the sample and confirmation of the result for most compounds, which allows to prevent false positives ones.


2020 ◽  
Vol 8 (3) ◽  
pp. 91
Author(s):  
Mahiastuti Tribuana Tungga Dewi ◽  
Boedi Setya Rahardja ◽  
Agustono Agustono

Catfish (Pangasius sp.) As a source of animal protein. Fish catfish have a thick white meat so that it can be processed into a wide range of diversified products. The process of fried fish cake can result in fat or autooxidation process. Autooxidation can be inhibited by the presence of antioxidant compounds. One source of natural antioxidants are bay leaf Eugenia polyantha.This research was carried out by experimental methods and the use of experimental design of randomized Complete Design (RAL). RAL is used when the material and condition of the experiment are homogeneous. This research consists of four concentrations of extract treatment bay leaf, namely 0%, 10%, 20%, 30%. Fish cake has been fried done soaking for 30 minutes. Water content showed no significant difference (p> 0.05) at 24 hours to 28, this indicated that the addition of bay leaf extract did not affect the moisture content during storage. The high water content at 0 hour is caused by the process of soaking the fish cake  in the extract solution. The highest value is shown by the concentration of 30% at the hour to 0 that is 52.78%, this indicates that the fish cake by soaking can meet the quality score SNI 7757:2013 which is a maximum of 60%. The fat content in the fish cake continues to decrease, indicating the occurrence of oxidation during storage. Levels of TBA in fish cake continue to increase that can be slowed by the extract of bay leaves with a concentration of 30%.


1997 ◽  
Vol 6 (6) ◽  
pp. 585-595 ◽  
Author(s):  
Andrew R. Baker ◽  
Ronald L. Fournier ◽  
Jeffrey G. Sarver ◽  
Jennifer L. Long ◽  
Peter J. Goldblatt ◽  
...  

An immunoisolation membrane formed by incorporating a high water content polyvinyl alcohol (PVA) hydrogel into a microporous polyether sulfone (PES) filter has been investigated in this study. The PVA hydrogel is formed in situ within the filter pores via glutaraldehyde (GA) crosslinking under acidic conditions. The tortuous nature of the microporous filter pores securely anchors the embedded hydrogel to provide excellent structural integrity. The high void fraction of the PES filter support (>80%) and high water content of the PVA hydrogel (>85% water by weight) allow excellent solute transport rates, while an appropriate level of glutaraldehyde crosslinking supplies the required molecular size selectivity. In vitro permeability measurements made with solutes covering a wide range of molecular sizes demonstrate high transport rates for small nutrient molecules with rapidly diminishing permeabilities above a molecular weight of approximately 1,000 Dalton. Implantation experiments show that the membrane properties are not deleteriously affected by prolonged in vivo exposure or common sterilization techniques. Thus, this hybrid hydrogel/filter membrane system offers a promising approach to the immunoisolation of implanted cells.


1998 ◽  
Vol 46 (5) ◽  
pp. 405 ◽  
Author(s):  
Philip C. Withers

Measurements of evaporative water loss (EWL; mg min-1) and resistance (R; sec cm-1) for various Australian frogs indicate three general allometric patterns: non-cocooned and non-‘waterproof’ frogs with EWL ∝ Mass0.30 and R independent of body mass at about 1–3 sec cm-1, cocooned frogs with EWL reduced about 50–200-fold and R about 50–200 sec cm-1, and ‘waterproof’ frogs with EWL reduced about 5–100- fold and R about 5–100 sec cm-1. Cocooned frogs have an exponential reduction in EWL and fairly linear increase in R over time, corresponding to the temporal addition of layers to the cocoon. The biophysical properties of cocoon are generally similar for various species, although there is some variation in both resistance per thickness (5–20 × 104 s cm-2) and diffusion coefficient (0.4–2.4 × 10 –5 cm2 s-1). The hygroscopic property of frog cocoon resembles that of mammalian stratum corneum, hair and wool, and mucopolysaccharides; there is a slight increase in water content of cocoon over a wide range of humidities but a very steep increase in water content and substantial hydration and swelling at >96% RH. This extreme hygroscopic behaviour of frog cocoon at very high RH may reflect less polymer cross-linking in frog cocoon and its high digestibility. The prevention of over-hydration of frog cocoon in vivo may be attributed to the restriction of high water content to only very high RH (>96%).


2018 ◽  
Vol 24 (8) ◽  
pp. 843-854 ◽  
Author(s):  
Weiguo Xu ◽  
Shujun Dong ◽  
Yuping Han ◽  
Shuqiang Li ◽  
Yang Liu

Hydrogels, as a class of materials for tissue engineering and drug delivery, have high water content and solid-like mechanical properties. Currently, hydrogels with an antibacterial function are a research hotspot in biomedical field. Many advanced antibacterial hydrogels have been developed, each possessing unique qualities, namely high water swellability, high oxygen permeability, improved biocompatibility, ease of loading and releasing drugs and structural diversity. In this article, an overview is provided on the preparation and applications of various antibacterial hydrogels. Furthermore, the prospects in biomedical researches and clinical applications are predicted.


2019 ◽  
Vol 67 (7) ◽  
pp. 4803-4810 ◽  
Author(s):  
Xiong Wang ◽  
Tao Qin ◽  
Yexian Qin ◽  
Ahmed H. Abdelrahman ◽  
Russell S. Witte ◽  
...  

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