Valorisation of Glycerol through Catalytic Hydrogenolysis Routes for Sustainable Production of Value-Added C3 Chemicals: Current and Future Trends

Author(s):  
Adrian Loy Chun Minh ◽  
Shanthi Priya Samudrala ◽  
Sankar Bhattacharya

The search of sustainable routes for the production of C3 chemicals from renewable feedstocks have attracted significant interest from academic and industrial communities to alleviate the dependence on fossil fuels....

Nanoscale ◽  
2021 ◽  
Author(s):  
Wei Shao ◽  
Xiaodong Zhang

Carbon dioxide (CO2) from the excessive consumption of fossil fuels has exhibited a huge threat to the planet’s ecosystem. Electrocatalytic CO2 reduction into value-added chemicals have been regarded as a...


2021 ◽  
Vol 405 ◽  
pp. 126705
Author(s):  
Javier Remón ◽  
Marina Casales ◽  
Jesús Gracia ◽  
María S. Callén ◽  
José Luis Pinilla ◽  
...  

2014 ◽  
Vol 59 (3) ◽  
pp. 575-590 ◽  
Author(s):  
Piotr Czaja ◽  
Paweł Kamiński ◽  
Jerzy Klich ◽  
Antoni Tajduś

Abstract Learning to control fire changed the life of man considerably. Learning to convert the energy derived from combustion of coal or hydrocarbons into another type of energy, such as steam pressure or electricity, has put him on the path of scientific and technological revolution, stimulating dynamic development. Since the dawn of time, fossil fuels have been serving as the mankind’s natural reservoir of energy in an increasingly great capacity. A completely incomprehensible refusal to use fossil fuels causes some local populations, who do not possess a comprehensive knowledge of the subject, to protest and even generate social conflicts as an expression of their dislike for the extraction of minerals. Our times are marked by the search for more efficient ways of utilizing fossil fuels by introducing non-conventional technologies of exploiting conventional energy sources. During apartheid, South Africa demonstrated that cheap coal can easily satisfy total demand for liquid and gaseous fuels. In consideration of current high prices of hydrocarbon media (oil and gas), gasification or liquefaction of coal seems to be the innovative technology convergent with contemporary expectations of both energy producers as well as environmentalists. Known mainly from literature reports, underground coal gasification technologies can be brought down to two basic methods: - shaftless method - drilling, in which the gasified seam is uncovered using boreholes drilled from the surface, - shaft method, in which the existing infrastructure of underground mines is used to uncover the seams. This paper presents a hybrid shaft-drilling approach to the acquisition of primary energy carriers (methane and syngas) from coal seams located at great depths. A major advantage of this method is the fact that the use of conventional coal mining technology requires the seams located at great depths to be placed on the off-balance sheet, while the hybrid method of underground gasification enables them to become a source of additional energy for the economy. It should be noted, however, that the shaft-drilling method cannot be considered as an alternative to conventional methods of coal extraction, but rather as a complementary and cheaper way of utilizing resources located almost beyond the technical capabilities of conventional extraction methods due to the associated natural hazards and high costs of combating them. This article presents a completely different approach to the issue of underground coal gasification. Repurposing of the already fully depreciated mining infrastructure for the gasification process may result in a large value added of synthesis gas production and very positive economic effect.


2021 ◽  
Author(s):  
M. Amin Farkhondehfal ◽  
Juqin Zeng

The CO2 that comes from the use of fossil fuels accounts for about 65% of the global greenhouse gas emission, and it plays a critical role in global climate changes. Among the different strategies that have been considered to address the storage and reutilization of CO2, the transformation of CO2 into chemicals and fuels with a high added-value has been considered a winning approach. This transformation is able to reduce the carbon emission and induce a “fuel switching” that exploits renewable energy sources. The aim of this chapter is to categorize different heterogeneous electrocatalysts which are being used for CO2 reduction, based on the desired products of the above mentioned reactions: from formic acid and carbon monoxide to methanol and ethanol and other possible by products. Moreover, a brief description of the kinetic and mechanism of the CO2 reduction reaction) and pathways toward different products have been discussed.


World reserves of fossil fuels are sufficient for many decades of increasing usage. During the next few decades at least, fossil fuels will be much the most important energy source. These fuels should be exploited in a complementary manner. Coal represents much the largest potential reserve, followed probably by hydrocarbons less easily utilized than those commonly being exploited now. Techniques exist for the conversion of coal into coke and carbons, electricity, gas and substitute oil-feed stock. Improvements in these processes are possible but their large-scale introduction depends on economics. Where coal burning can meet a requirement (local heat or steam, or electricity generation) fluidized combustion can be the most efficient process; better integration with mining techniques are possible and environmental considerations are favourable. Fluidized combustion would be a high priority unit in a ‘ Coalplex ’ which could have electricity, gas and oil as possible products. The best mix could depend on the value ascribed to the products and this in turn invokes consideration of the overall economics of energy storage, transport and demand flexibility. Looking farther ahead, coal will certainly remain a vital chemical component for various proposed energy systems and will also probably be able to compete as the energy input into conversion schemes. The technology of coal utilization may also have applications for other fossil fuels.


1997 ◽  
Vol 37 (1) ◽  
pp. 722
Author(s):  
N.G. Grollman

The oil and gas reserves of Australia and the East Asian region fall well short of the region's long-term requirements, even for a scenario that phases out all fossil fuels by the end of the 21st century. There is, therefore, no contradiction between vigorous exploration for oil and gas and the process of transition to renewable energy sources. However, to be an independent player in environmental policy-making, the Australian petroleum exploration industry should focus on its particular role within the energy sector as a whole, whose nature will change radically over the next several decades. This role will combine concerns over long term oil supply security with, in particular, the objective of reducing greenhouse gas emissions from oil and gas consumption to levels commensurate with Australia's international obligations. The role extends to Australian involvement in the region as a whole through the accrual of emissions credits from projects implemented jointly with developing countries. It also envisages that Australian explorers, especially those focussed on gas, will form alliances with downstream companies, power generators, appliance manufacturers and energy marketers as links in an integrated chain of operations with value added and emissions reduced at each stage. This re-orientation should lead the industry to question the extent to which its interests correspond with those of the coal and mineral industries, which do not face the same resource limitations.


Author(s):  
K.M.P. Mokatse ◽  
J.P.H. van Wyk

Environmental pollution and the exploitation of fossil-based products are topical issues that should be a matter of concern to the global population. The production of bio-based substances from waste biomass is a way to reduce the consumption of fossil fuels and limit environmental pollution. Enzymatic catalysed saccharification of cellulose is an important step for the bio-conversion of biomass such as waste paper into glucose that could be utilized as a feedstock for the production of value added bioproducts and this process can also be considered as an alternative route of waste management. During this study, fresh cellulase enzyme from Trichoderma viride was incubated separately with seven different waste paper materials during twelve successive incubation periods of 2 h each. The amount of sugar released from each paper material during each incubation period was determined. The highest sugar concentration released from each paper materials was produced during the first incubation period except the filter paper for which the highest amount of sugar was produced during the 9th period of incubation. During these optimum sugar producing incubation periods the highest total sugar concentration was released from brown envelope paper (3.3 mg.mL-1 followed by foolscap paper (3.0 mg.mL-1) and office paper (2.8 mg.mL-1) while the lowest amount of sugar was released from Pick ’n Pay paper (0.6 mg.mL-1). The relative saccharification percentage was also calculated which showed that filter paper produced the highest amounts of sugar followed by newspaper, and foolscap paper with advertising paper from a retailer. Pick ’n Pay offered the highest resistance towards cellulase catalysed bio-conversion into sugar.


Author(s):  
Marta Goliszek ◽  
Beata Podkościelna

<p>The overutilization of fossil fuels will inevitably cause the global environmental problems and dwindling of available resources. For that reason, identifying renewable sustainable alternatives has attracted an increasing attention. Lignocellulosic biomass has been considered to be one of the most logical feedstock to replace traditional fossil resources as one of the most accessible renewable forms of carbon. One of the primary components of lignocellulosic biomass, next to hemicellulose and cellulose is lignin. It is a by-product in paper and pulp industry. Lignin is mainly used as fuel directly, without further utilization which is suggested to be a waste of natural resources. With this purpose, the valorization of lignin into value-added products needs particular attention of researchers. This review article focuses on chosen possible applications of lignin in chemical industry.</p>


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