Surfactant Effect on the Electrorheological Performance and Colloidal Stability

Soft Matter ◽  
2021 ◽  
Author(s):  
Hanqi Xu ◽  
Jinbo Wu ◽  
Yaying Hong ◽  
Weijia Wen
Keyword(s):  
Nonionic Surfactants ◽  
Colloidal Stability ◽  
Silicone Oil ◽  
Surfactant Effect ◽  
Barium Titanyl Oxalate ◽  
The Impact ◽  
Titanyl Oxalate

The impact of two nonionic surfactants, namely Span 20 and Span 85, on the electrorheological response and colloidal stability of urea-coated barium titanyl oxalate (BTRU)/silicone oil suspensions is investigated. We...

The Impact of Bioconjugation on the Interfacial Activity of a Protein Biosurfactant

2018 ◽  
Author(s):  
Hossam H Tayeb ◽  
Marina Stienecker ◽  
Anton Middelberg ◽  
Frank Sainsbury
Keyword(s):  
Polyethylene Glycol ◽  
Colloidal Stability ◽  
Point Mutations ◽  
Pharmaceutical Formulations ◽  
Industrial Processes ◽  
Parent Molecule ◽  
Site Specific ◽  
Interfacial Activity ◽  
Surface Active ◽  
The Impact

Biosurfactants, are surface active molecules that can be produced by renewable, industrially scalable biologic processes. DAMP4, a designer biosurfactant, enables the modification of interfaces via genetic or chemical fusion to functional moieties. However, bioconjugation of addressable amines introduces heterogeneity that limits the precision of functionalization as well as the resolution of interfacial characterization. Here we designed DAMP4 variants with cysteine point mutations to allow for site-specific bioconjugation. The DAMP4 variants were shown to retain the structural stability and interfacial activity characteristic of the parent molecule, while permitting efficient and specific conjugation of polyethylene glycol (PEG). PEGylation results in a considerable reduction on the interfacial activity of both single and double mutants. Comparison of conjugates with one or two conjugation sites shows that both the number of conjugates as well as the mass of conjugated material impacts the interfacial activity of DAMP4. As a result, the ability of DAMP4 variants with multiple PEG conjugates to impart colloidal stability on peptide-stabilized emulsions is reduced. We suggest that this is due to constraints on the structure of amphiphilic helices at the interface. Specific and efficient bioconjugation permits the exploration and investigation of the interfacial properties of designer protein biosurfactants with molecular precision. Our findings should therefore inform the design and modification of biosurfactants for their increasing use in industrial processes, and nutritional and pharmaceutical formulations.

Measurement of foliar spray retention on creeping bentgrass

2019 ◽  
Vol 33 (6) ◽  
pp. 827-832
Author(s):  
Pingyuan Zhang ◽  
Bruce E. Branham
Keyword(s):  
Nonionic Surfactants ◽  
Foliar Spray ◽  
Creeping Bentgrass ◽  
Seed Oils ◽  
Retention Efficiency ◽  
Food Dye ◽  
Spray Volume ◽  
The Impact ◽  
Application Volume ◽  
Foliar Retention

AbstractExperiments were conducted to evaluate the impact of spray volume, nozzle type, adjuvants, the presence of dew, and their interactions on foliar retention of creeping bentgrass. Tartrazine, a common food dye, was used as a tracer in this study. Increasing spray volume from 95 L ha−1 to 1,500 L ha−1 decreased foliar retention efficiency from 98% to approximately 85%. Compared with flat-fan nozzles, air-induction nozzles delivered similar retention efficiency at all spray volumes evaluated. However, flat-fan nozzles provided higher uniformity and more thorough coverage. Adding nonionic surfactants, organosilicone adjuvants, or methylated seed oils at typical concentrations yielded retention efficiency of approximately 90% to 93% regardless of spray volumes. In contrast, with water alone, increasing spray volume reduced retention efficiency from 95.9% to 87.3%. Simulated dew applied at 1,950 L ha−1 increased retention efficiency by approximately 3% when spray application volume was 190 L ha−1, while no difference was observed at 750 L ha−1. The presence of dew reduced the impact of adjuvants on retention efficiency. Large quantities of dew, 3,800 L ha−1, did reduce retention efficiency.

Mechanochemical synthesis of BaTiO3 from barium titanyl oxalate

2008 ◽  
Vol 44 (6) ◽  
pp. 641-645 ◽  
Author(s):  
V. A. Zazhigalov ◽  
V. V. Sidorchuk ◽  
S. V. Khalameida ◽  
L. S. Kuznetsova
Keyword(s):  
Mechanochemical Synthesis ◽  
Barium Titanyl Oxalate ◽  
Titanyl Oxalate

Effects of impurities on the properties of BaTiO3 synthesized from barium titanyl oxalate

2010 ◽  
Vol 36 (6) ◽  
pp. 1997-2002 ◽  
Author(s):  
Won-Sik Jung ◽  
Jiho Park ◽  
Yunjung Park ◽  
Dang-Hyok Yoon
Keyword(s):  
Barium Titanyl Oxalate ◽  
Titanyl Oxalate

On the Impact of Liquid Drops on Immiscible Liquids

2016 ◽  
Author(s):  
Eduardo Castillo-Orozco ◽  
Ashkan Davanlou ◽  
Pretam K. Choudhury ◽  
Ranganathan Kumar
Keyword(s):  
Oil Spills ◽  
Silicone Oil ◽  
Density Ratio ◽  
High Viscosity ◽  
Impact Behavior ◽  
Immiscible Fluid ◽  
Liquid Droplets ◽  
Liquid Drops ◽  
Low Viscosity ◽  
The Impact

The release of liquid hydrocarbons into the water is one of the environmental issues that have attracted more attention after deepwater horizon oil spill in Gulf of Mexico. The understanding of the interaction between liquid droplets impacting on an immiscible fluid is important for cleaning up oil spills as well as the demulsification process. Here we study the impact of low-viscosity liquid drops on high-viscosity liquid pools, e.g. water and ethanol droplets on a silicone oil 10cSt bath. We use an ultrafast camera and image processing to provide a detailed description of the impact phenomenon. Our observations suggest that viscosity and density ratio of the two media play a major role in the post-impact behavior. When the droplet density is larger than that of the pool, additional cavity is generated inside the pool. However, if the density of the droplet is lower than the pool, droplet momentary penetration may be facilitated by high impact velocities. In crown splash regime, the pool properties as well as drop properties play an important role. In addition, the appearance of the central jet is highly affected by the properties of the impacting droplet. In general, the size of generated daughter droplets as well as the thickness of the jet is reduced compared to the impact of droplets with the pool of an identical fluid.

Impact of Molecular Chain Structure of Suspension Phase on Giant Electrorheological Performance

2022 ◽  
Author(s):  
Hanqi Xu ◽  
Jinbo Wu ◽  
Yaying Hong ◽  
Weijia Wen
Keyword(s):  
Yield Stress ◽  
Chain Length ◽  
Colloidal Stability ◽  
Chain Structure ◽  
Solid Particles ◽  
High Yield ◽  
Suspension Stability ◽  
Chain Lengths ◽  
The Impact ◽  
Oil Particles

Abstract We demonstrate the impact of diester structure, in particular the alkyl chain length and branching structure, on the giant electrorheological (GER) effect and suspension stability. The existence of oil-particles interaction is of critical importance to induce the GER effect. To quantify GER performance and colloidal stability, we examine the yield stress, current density, field-off viscosity and sedimentation ratio with respect to the variation of chain length and branching structure. The oil-particles interaction is quantitatively analyzed by investigating the cluster size of particles in different diesters by a multiple light scattering analyzer, along with the wettability of different chain lengths of diesters and solid particles by the Washburn method. Our results indicate that long chain lengths favor the formation of particle agglomerates, thereby enhancing the GER effect (such as high yield stress). The attachment of branches on diester causes the formation of electronic correlation between branches and main chain, depending on the position of branches located, and hence results in superior GER performance and favorable suspension stability. An optimal GER fluid constituted by bis(2-ethylhexyl) sebacate is acquired with the achieved yield stress of 113 kPa at electric field strength of 4 kV/ mm and the prominent integrated GER properties.

Effects of Increased Tooth Clearance on the Performance of a Labyrinth Seal With Oil-Rich Bubbly Laminar Flow

2021 ◽  
Author(s):  
Min Zhang ◽  
Dara W. Childs
Keyword(s):  
Smooth Surface ◽  
Volume Fraction ◽  
Silicone Oil ◽  
Bubbly Flow ◽  
Labyrinth Seal ◽  
Test Fluid ◽  
Axial Thrust ◽  
Rotordynamic Coefficients ◽  
Piston Seal ◽  
The Impact

Abstract In recent years, multiphase pumps have become more and more popular because of the capability to simplify the process, reduce the footprint, and lower the cost. To compensate for the axial thrust force, an annular seal is normally used as a balance piston seal, and the labyrinth seal is one of the choices. A typical labyrinth seal consists of a surface with teeth and a smooth surface. The teeth are either on the rotor or the stator. To protect the machine, one side (either the teeth or the smooth surface) is made of a material that can be safely sacrificed during a rub. After the rub, the teeth clearance is increased. This paper studies the impact of the increased teeth clearance on the performance of the labyrinth seal under oil-rich bubbly flow conditions. The test fluid is a mixture of silicone oil (PSF 5cSt) and air with inlet Gas Volume Fraction GVF up to 9%. Tests are conducted with pressure drop PD = 34.5 bars, rotor speed ω = 5 krpm, and radial tooth clearance Cr = 0.102 mm and 0.178 mm. Test results show that, for all test conditions (before and after injecting air bubbles into the oil flow), increasing Cr from 0.102 mm to 0.178 mm increases the mass flow rate by about 40% but barely changes the test seal’s rotordynamic coefficients; i.e., the increased tooth clearance would not change the pump vibration performance.

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