Interfacial net charge density of nonintimate Schottky junctions

2002 ◽  
Vol 91 (7) ◽  
pp. 4281-4290 ◽  
Author(s):  
B. Cvikl ◽  
D. Korošak
2021 ◽  
Author(s):  
Chao Shen ◽  
Yufei Zhou ◽  
Lai Gao

2020 ◽  
Vol 22 (16) ◽  
pp. 9110-9116
Author(s):  
Xiaoyu Hu ◽  
Yiling Nan ◽  
Xian Kong ◽  
Diannan Lu ◽  
Jianzhong Wu

Schematic illustration of the hybrid method model. ρ is the net charge density calculated from cDFT. v is the velocity calculated from non-equilibrium MD simulation. b and αW are the slipping length and the surface properties, respectively.


1981 ◽  
Vol 59 (13) ◽  
pp. 1888-1897 ◽  
Author(s):  
G. M. Bell ◽  
G. C. Peterson

A method previously developed by the authors is used to study the effects of adsorption of ions on the electric double layer interaction between dissimilar colloidal plates immersed in 1:1 electrolyte. For adsorption models which permit the total charge on a plate to change sign, the double layer force remains finite at all plate separations, including zero. For weak adsorption of the ions on the plates the force between two dissimilar plates tends to be repulsive at small separations, looking rather like a weakened constant surface charge density model. Conversely for strong ionic adsorption the force tends to be attractive at small separations, rather as in the constant surface potential model. In this paper we discuss three adsorption models: (1) fixed primary charge density on the plates with secondary adsorption of both counter-ions and co-ions; (2) fixed primary charge density on the plates with secondary adsorption of the counter-ions only, but including the effects of a Stern layer and self-atmosphere potentials; (3) zero primary charge on both plates with equilibrium adsorption of both anions and cations from solution, the net charge density on the plates arising from differential adsorption of the ion types.


2022 ◽  
Author(s):  
Chao Shen ◽  
Yufei Zhou ◽  
Lai Gao ◽  
Zuyin Pu ◽  
Xiaogang Wang ◽  
...  

1979 ◽  
Vol 177 (1) ◽  
pp. 265-273 ◽  
Author(s):  
M Isern de Caldentey ◽  
K P Wheeler

The basis of the requirement for a net negative charge on phospholipid dispersions able to re-activate lipid-depleted (Na++K+)-dependent adenosine triphosphatase was studied. The origin and density of the charge in phospholipid dispersions were varied before interaction with the adenosine triphosphatase protein, and the charge density on restored phospholipid-adenosine triphosphatase complexes was changed after interaction. The results indicated that: (a) re-activation requires a lamellar arrangement of the lipid molecules with sufficient density of negative charge, but not necessarily negatively charged phospholipid molecules; (b) the net charge appears to be necessary for the correct interaction between the enzyme protein and the phospholipids, although the amount of phospholipid that binds to the protein is also a function of the nature of the acyl chains; (c) it is not possible on the basis of these findings and those in the literature to decide unequivocally if the charge is also required for the enzyme reaction itself. The possible relevance of the findings to the situation in vivo is discussed in terms of the charge being concerned only with lipid-protein interaction.


Langmuir ◽  
2012 ◽  
Vol 28 (6) ◽  
pp. 3159-3166 ◽  
Author(s):  
Eva Beurer ◽  
Nagaiyanallur V. Venkataraman ◽  
Marianne Sommer ◽  
Nicholas D. Spencer

2019 ◽  
Vol 09 (06) ◽  
pp. 1950051
Author(s):  
Amin Shamsi ◽  
Alireza Ganjovi ◽  
Amirabbas Shayegani Akmal

In this paper, a lumped RC circuit model, which is based on the Transmission Line Modeling (TLM) method, is used to describe the space charge production and displacement mechanisms in three different solid dielectric materials (LDPE, PTFE and FR4). Each dielectric material is considered as a transmission line with the capacitive and resistance elements. The obtained circuit equations are solved along with the continuity equations for the various charged species in the bulk of solid dielectric material. The electric potential and field, density of different charged species and their recombination rates, resistive and capacitive properties of the solid dielectric material are calculated. In addition, the effects of the variations in the applied voltage, dielectric permittivity and temperature on these physical parameters are examined. Besides, compared with LDPE and PTFE, the net charge density increment rate in FR4 is much higher. Moreover, the influences of temperature on the net charge density in LDPE are not significant. Furthermore, at the higher applied voltages, the current density is increased. Interestingly, the effects of temperature variations on the recombination rates, net charge and current density in LDPE are much lower. Hence, the suitability of LDPE as solid dielectric material is proved.


1996 ◽  
Vol 432 ◽  
Author(s):  
B.K. Schroth ◽  
G. Sposito

AbstractThe surface charge components of two Georgia kaolinites of differing degree of crystallinity (KGa-1 and KGa-2) were measured using procedures based on charge balance concepts. Permanent structural charge density (Σ0) was determined by measuring the surface excess of Cs, which is highly selective to permanent charge sites. The values of Σ0 determined were -6.3 ± 0.1 and -13.6 ± 0.5 mmol kg-1 for kaolinites KGa-l and KGa-2, respectively. The net proton surface charge density (σH) was determined as a function of pH by potentiometric titration in 0.01 mol dm-3 LiC1. Correction from apparent to absolute values of ΣH was made by accounting for Al release during dissolution, background ion adsorption, and charge balance. Lithium and Cl adsorption accounted for the remainder of the surface charge components. Changes in surface charge properties with time were measured after mixing times of 1, 3, and 15 hours (the latter representing “equilibrium”). Time-dependent behavior is believed to be caused by mineral dissolution followed by readsorption or precipitation of Al on the mineral surface. Both the point of zero net charge (p.z.n.c.) and the point of zero net proton charge (p.z.n.p.c.) changed with mixing time, generally increasing. The “equilibrium” p.z.n.c. values were approximately 3.6 and 3.3 for KGa-1 and KGa-2, respectively, while the corresponding p.z.n.p.c. values were about 5.0 and 5.4. The p.z.n.c. results were in good agreement with previous studies, but the values of p.z.n.p.c. were higher than other values reported for specimen kaolinite.


2010 ◽  
Vol 2010 ◽  
pp. 1-8 ◽  
Author(s):  
Natalita M. Nursam ◽  
Yongling Ren ◽  
Klaus J. Weber

The dependence of surface recombination of boron diffused and undiffused silicon surfaces passivated with a-Si:H on the net charge density is investigated in detail. The films are deposited by plasma-enhanced chemical vapour deposition using a 2.45 GHz microwave remote plasma system. The surface charge density on the samples is varied by depositing charge using a corona discharge chamber. Excess carrier lifetime, capacitance-voltage, and Kelvin probe measurements are combined to determine the surface recombination velocity and emitter saturation current density as a function of net charge density. Our results show that the application of negative charge causes a substantial reduction in the surface recombination of samples with boron diffused emitters, even for high boron surface concentrations of  . The significant difference observed in surface recombination between boron diffused and undiffused sample under accumulation implies that the presence of boron diffusion has results in some degradation of the Si-Si interface. Further, (111) oriented surfaces appear more sensitive to the boron surface concentration than (100) oriented surfaces.


Author(s):  
Hua Shan ◽  
Yu-Tai Lee

There has been an increasing interest in dielectric barrier discharge (DBD) plasma actuation for flow control in the past decade. Compared to other means of active flow controls, the DBD plasma actuations have several advantages, including absence of moving parts, a fast time response for unsteady applications, a very low mass of the device, no cavities or holes on control surfaces, and possibly low energy consumption. These features are especially important for applications with high g-loads, such as turbomachinery blades rotating at high speed. A computational method has been developed to couple a DBD electro-hydrodynamic (EHD) body force model with the Reynolds averaged Navier-Stokes (RANS) model for incompressible flows. The EHD body force model is based on solving the electrostatic equations for the electric potential due to applied voltage and the net charge density due to ionized air. The boundary condition for charge density on the dielectric surface is obtained from a Space-Time Lumped-Element (STLE) circuit model that accounts for time and space dependence of the air ionization on the input voltage amplitude, frequency, electrode geometry, and dielectric properties. Alternatively, an empirical formulation representing a Gaussian distribution of charge density on the dielectric surface can also be used. The EHD body force is calculated using the solutions obtained from solving the electric potential and the net charge density equations. As a comparison, a much simpler Linearized Electric Body Force (LEBF) model is also used to directly specify the spatial distribution of the averaged EHD body force. The coupled computational models have been implemented using a multiple-domain approach. The electric potential equation, the net charge density equation, and the flow equations are solved in separate computational domains. All equations are discretized in space using a cell-centered finite volume method. Parallel computation is implemented using domain-decomposition and message passing interface (MPI). Due to a large disparity in time scales between the electric discharge and the flow, a multiple sub-cycle technique is used in coupling the plasma solver and the flow solver. The DBD plasma induced flow in quiescent air is used as a test case and the computational results are validated against experimental measurement. A comparison between different EHD body force models is also presented. Then, the effect of driving duty-cycles with different waveforms and input voltage amplitudes is investigated in terms of electrical power, EHD thrust, and kinetic energy of induced flow.


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