Characterization of amine-functionalized electrode for aqueous carbon dioxide (CO2) direct detection

2017 ◽  
Author(s):  
Hiroshi Sato
2018 ◽  
Vol 190 (7) ◽  
pp. 1259-1282 ◽  
Author(s):  
Umi Fazara Md Ali ◽  
Nur Hidayah Azmi ◽  
Khairuddin Md Isa ◽  
Mohamed Kheireddine Aroua ◽  
Tan Ru Shien ◽  
...  

Author(s):  
Feng Zheng ◽  
R. Shane Addleman ◽  
Christopher L. Aardahl, ◽  
Glen E. Fryxell ◽  
Daryl R. Brown ◽  
...  

2019 ◽  
Vol 1349 ◽  
pp. 012100
Author(s):  
N F Mohamad ◽  
N H Abdul Rani ◽  
M Onn ◽  
S I Sayed Jamaludin ◽  
A S I Ahmad Shafiq ◽  
...  

2019 ◽  
Vol 801 ◽  
pp. 179-184
Author(s):  
John Andrew Kane P. Jovellana ◽  
B. Pajarito

Increasing carbon dioxide (CO2) levels in the atmosphere caused by excessive greenhouse gas emissions is strongly associated to global warming and climate change. This study aims to prove the feasibility of using pectin as the backbone for amine functionalization with application as coating on zeolites for carbon dioxide capture. Characterization of the solutions using FTIR and of the adsorbents using SEM demonstrated the successful modification of pectin using NH3 and TETA as alternative amine-functionalized coating for adsorbent. It has been reported for the first time that the polysaccharide pectin can be aminated and modified for CO2 capture upon coated on substrates such as zeolites. The adsorption capacities at 5% breakthrough of the adsorbents coated with the modified pectin are 2.24 mmol/CO2 g adsorbent and 2.28 mmol/CO2 g adsorbent, when coated with NH3-modified and TETA-modified pectin, respectively. It is recommended for further study to synthesize substrates with higher surface area, and optimize the formulations of the pectin modification.


Author(s):  
Feng Zheng ◽  
R. Shane Addleman ◽  
Christopher L. Aardahl ◽  
Glen E. Fryxell ◽  
Daryl R. Brown ◽  
...  

2005 ◽  
Vol 19 (5) ◽  
pp. 494-503 ◽  
Author(s):  
Stefano Zanone Poma ◽  
Stefano Milleri ◽  
Lisa Squassante ◽  
Gianluca Nucci ◽  
Massimo Bani ◽  
...  

2020 ◽  
Vol 21 (1) ◽  
pp. 77
Author(s):  
Putri Nurul Amalia ◽  
Iman Abdullah ◽  
Dyah Utami Cahyaning Rahayu ◽  
Yuni Krisyuningsih Krisnandi

Carbon dioxide (CO2) is a compound that can potentially be used as a carbon source in the synthesis of fine chemicals. However, the utilization of CO2 is still constrained due to its inert and stable nature. Therefore, the presence of a catalyst is needed in CO2 conversion. This study aims to synthesize copper impregnated mesoporous carbon (Cu/MC) as a catalyst for phenylacetylene carboxylation reaction with CO2 to produce phenylpropiolic acid. The synthesis of mesoporous carbon was performed via the soft template method. The as-synthesized Cu/MC material was characterized by FTIR, SAA, XRD, and SEM-EDX. BET surface area analysis of mesoporous carbon showed that the material has a high surface area of 405.8 m2/g with an average pore diameter of 7.2 nm. XRD pattern of Cu/MC indicates that Cu has been successfully impregnated in the form of Cu(0) and Cu(I). Phenylacetylene carboxylation reaction with CO2 was carried out by varying reaction temperatures (25, 50, and 75 °C), amount of catalyst (28.6, 57.2, and 85.8 mg), type of base (Cs2CO3, K2CO3, and Na2CO3), and variation of support. The reaction mixtures were analyzed by HPLC and showed that the highest phenylacetylene conversion of 41% was obtained for the reaction at 75 °C using Cs2CO3 as a base.


Sign in / Sign up

Export Citation Format

Share Document