SOURCE POTENTIAL OF THE HORN VALLEY SILTSTONE, AMADEUS BASIN

1984 ◽  
Vol 24 (1) ◽  
pp. 66 ◽  
Author(s):  
John D. Gorter

The quantity of organic matter in the source beds within the Horn Valley Siltstone, as defined by the Total Organic Carbon content, increases westward from low values in the south and east of the Basin to maximum values in the Mt Winter and Mereenie areas. This westerly enrichment trend is paralleled by an improvement in source rock quality, as defined by the Hydrogen Index and Tmax crossplot of samples analysed by Rock-Eval pyrolysis.Earlier attempts to measure thermal maturation levels of source rocks in the Basin relied on the reflectivity of coalified graptolites but this method was only applicable to unweathered material obtained from the few and scattered bore holes in the Basin. In this study, conodont colour alteration is used to define organic maturation levels. This technique, newly applied in Australia, was used principally on samples collected from the Horn Valley Siltstone and has the practical advantage of being applicable to samples from both outcrop and subsurface localities.The study indicates that the conodont colour alteration isograds in the Amadeus Basin are primarily related to events of the Alice Springs Orogeny, when the thick mass of molasse sediments (Pertnjara Group) resulting from erosion of the uplifted Arunta Block was deposited. Anomalies in the conodont colour isograds are closely related to timing of structural growth during the orogeny and also possibly to the growth of salt structures.In addition, the study shows that burial at depths below 1500 m will have led to the catagenetic breakdown of reservoired oil and the production of only gaseous hydrocarbons from source beds.In combination, these two factors lead to the conclusion that the most prospective area for oil sourced by the Horn Valley Siltstone is north and west of the Mereenie Oil Field in areas of shallow burial.


Author(s):  
S. L. Fadiya ◽  
S. A. Adekola ◽  
B. M. Oyebamiji ◽  
O. T. Akinsanpe

AbstractSelected shale samples within the middle Miocene Agbada Formation of Ege-1 and Ege-2 wells, Niger Delta Basin, Nigeria, were evaluated using total organic carbon content (TOC) and Rock–Eval pyrolysis examination with the aim of determining their hydrocarbon potential. The results obtained reveal TOC values varying from 1.64 to 2.77 wt% with an average value of 2.29 wt% for Ege-1 well, while Ege-2 well TOC values ranged from 1.27 to 3.28 wt% (average of 2.27 wt%) values which both fall above the minimum threshold (0.5%) for hydrocarbon generation potential in the Niger Delta. Rock–Eval pyrolysis data revealed that the shale source rock samples from Ege-1 well are characterized by Type II–Type III kerogens which are thermally mature to generate oil or gas/oil. The Ege-2 well pyrolysis result showed that some of the ditch cutting samples are comprised of Type II (oil prone) and Type III (gas-prone kerogen) which are thermally immature to marginal maturity (Tmax 346–439 °C). This study concludes that the shale intercalations between reservoir sands of the Agbada Formation are good source rocks in early maturity and also must have contributed to the vast petroleum reserve in the Niger Delta Basin because of the subsidence of the basin.



Energies ◽  
2021 ◽  
Vol 14 (21) ◽  
pp. 6866
Author(s):  
Irena Matyasik ◽  
Małgorzata Labus ◽  
Maria Kierat ◽  
Karol Spunda

The study of the source rocks was carried out with the use of various analytical methods in order to assess their generation potential and to predict the decomposition products of organic matter. The selected samples from the Menilite Beds from the Silesian and Dukla units, as well as the Istebna layers from the Silesian unit, which are classified as weak and medium source rocks in the Carpathian oil system, were examined. The generation potential and type of the products obtained from the pyrolysis of the analyzed source rocks, despite the often comparable overall content of organic matter, are significantly different. Menilite shale generated a higher abundance of hydrocarbons (alkanes, alkenes, and isoalkanes) by stage pyrolysis, which suggested that the organic matter of Menilite shale is different from the Istebna source rocks. Moreover, the thermogravimetric analysis showed a two-stage weight loss in the case of Menilite shales, while the Istebna shales were characterized by a one-stage weight loss at higher temperature. For the Istebna layers, n-alkanes from the C1–C5 range were detected as the main pyrolysis products, which proves the gas-forming type of the organic matter dispersed in these sediments. Rock-Eval analyses showed that the organic matter reached a degree of maturity corresponding to the early thermocatalytic processes (the initial oil window stage) and therefore was able to generate liquid and gaseous hydrocarbons. The comparison of the decomposition temperatures of the organic matter from the Rock-Eval and TG analyses allowed us to conclude that both measurements correlate well and can be equally used to assess the level of thermal transformations of organic matter.



Author(s):  
Lars Stemmerik ◽  
Gregers Dam ◽  
Nanna Noe-Nygaard ◽  
Stefan Piasecki ◽  
Finn Surlyk

NOTE: This article was published in a former series of GEUS Bulletin. Please use the original series name when citing this article, for example: Stemmerik, L., Dam, G., Noe-Nygaard, N., Piasecki, S., & Surlyk, F. (1998). Sequence stratigraphy of source and reservoir rocks in the Upper Permian and Jurassic of Jameson Land, East Greenland. Geology of Greenland Survey Bulletin, 180, 43-54. https://doi.org/10.34194/ggub.v180.5085 _______________ Approximately half of the hydrocarbons discovered in the North Atlantic petroleum provinces are found in sandstones of latest Triassic – Jurassic age with the Middle Jurassic Brent Group, and its correlatives, being the economically most important reservoir unit accounting for approximately 25% of the reserves. Hydrocarbons in these reservoirs are generated mainly from the Upper Jurassic Kimmeridge Clay and its correlatives with additional contributions from Middle Jurassic coal, Lower Jurassic marine shales and Devonian lacustrine shales. Equivalents to these deeply buried rocks crop out in the well-exposed sedimentary basins of East Greenland where more detailed studies are possible and these basins are frequently used for analogue studies (Fig. 1). Investigations in East Greenland have documented four major organic-rich shale units which are potential source rocks for hydrocarbons. They include marine shales of the Upper Permian Ravnefjeld Formation (Fig. 2), the Middle Jurassic Sortehat Formation and the Upper Jurassic Hareelv Formation (Fig. 4) and lacustrine shales of the uppermost Triassic – lowermost Jurassic Kap Stewart Group (Fig. 3; Surlyk et al. 1986b; Dam & Christiansen 1990; Christiansen et al. 1992, 1993; Dam et al. 1995; Krabbe 1996). Potential reservoir units include Upper Permian shallow marine platform and build-up carbonates of the Wegener Halvø Formation, lacustrine sandstones of the Rhaetian–Sinemurian Kap Stewart Group and marine sandstones of the Pliensbachian–Aalenian Neill Klinter Group, the Upper Bajocian – Callovian Pelion Formation and Upper Oxfordian – Kimmeridgian Hareelv Formation (Figs 2–4; Christiansen et al. 1992). The Jurassic sandstones of Jameson Land are well known as excellent analogues for hydrocarbon reservoirs in the northern North Sea and offshore mid-Norway. The best documented examples are the turbidite sands of the Hareelv Formation as an analogue for the Magnus oil field and the many Paleogene oil and gas fields, the shallow marine Pelion Formation as an analogue for the Brent Group in the Viking Graben and correlative Garn Group of the Norwegian Shelf, the Neill Klinter Group as an analogue for the Tilje, Ror, Ile and Not Formations and the Kap Stewart Group for the Åre Formation (Surlyk 1987, 1991; Dam & Surlyk 1995; Dam et al. 1995; Surlyk & Noe-Nygaard 1995; Engkilde & Surlyk in press). The presence of pre-Late Jurassic source rocks in Jameson Land suggests the presence of correlative source rocks offshore mid-Norway where the Upper Jurassic source rocks are not sufficiently deeply buried to generate hydrocarbons. The Upper Permian Ravnefjeld Formation in particular provides a useful source rock analogue both there and in more distant areas such as the Barents Sea. The present paper is a summary of a research project supported by the Danish Ministry of Environment and Energy (Piasecki et al. 1994). The aim of the project is to improve our understanding of the distribution of source and reservoir rocks by the application of sequence stratigraphy to the basin analysis. We have focused on the Upper Permian and uppermost Triassic– Jurassic successions where the presence of source and reservoir rocks are well documented from previous studies. Field work during the summer of 1993 included biostratigraphic, sedimentological and sequence stratigraphic studies of selected time slices and was supplemented by drilling of 11 shallow cores (Piasecki et al. 1994). The results so far arising from this work are collected in Piasecki et al. (1997), and the present summary highlights the petroleum-related implications.



Author(s):  
Sebastian Grohmann ◽  
Susanne W. Fietz ◽  
Ralf Littke ◽  
Samer Bou Daher ◽  
Maria Fernanda Romero-Sarmiento ◽  
...  

Several significant hydrocarbon accumulations were discovered over the past decade in the Levant Basin, Eastern Mediterranean Sea. Onshore studies have investigated potential source rock intervals to the east and south of the Levant Basin, whereas its offshore western margin is still relatively underexplored. Only a few cores were recovered from four boreholes offshore southern Cyprus by the Ocean Drilling Program (ODP) during the drilling campaign Leg 160 in 1995. These wells transect the Eratosthenes Seamount, a drowned bathymetric high, and recovered a thick sequence of both pre- and post-Messinian sedimentary rocks, containing mainly marine marls and shales. In this study, 122 core samples of Late Cretaceous to Messinian age were analyzed in order to identify organic-matter-rich intervals and to determine their depositional environment as well as their source rock potential and thermal maturity. Both Total Organic and Inorganic Carbon (TOC, TIC) analyses as well as Rock-Eval pyrolysis were firstly performed for the complete set of samples whereas Total Sulfur (TS) analysis was only carried out on samples containing significant amount of organic matter (>0.3 wt.% TOC). Based on the Rock-Eval results, eight samples were selected for organic petrographic investigations and twelve samples for analysis of major aliphatic hydrocarbon compounds. The organic content is highly variable in the analyzed samples (0–9.3 wt.%). TS/TOC as well as several biomarker ratios (e.g. Pr/Ph < 2) indicate a deposition under dysoxic conditions for the organic matter-rich sections, which were probably reached during sporadically active upwelling periods. Results prove potential oil prone Type II kerogen source rock intervals of fair to very good quality being present in Turonian to Coniacian (average: TOC = 0.93 wt.%, HI = 319 mg HC/g TOC) and in Bartonian to Priabonian (average: TOC = 4.8 wt.%, HI = 469 mg HC/g TOC) intervals. A precise determination of the actual source rock thickness is prevented by low core recovery rates for the respective intervals. All analyzed samples are immature to early mature. However, the presence of deeper buried, thermally mature source rocks and hydrocarbon migration is indicated by the observation of solid bitumen impregnation in one Upper Cretaceous and in one Lower Eocene sample.



2018 ◽  
Vol 36 (4) ◽  
pp. 971-985
Author(s):  
Qingqiang Meng ◽  
Jiajun Jing ◽  
Jingzhou Li ◽  
Dongya Zhu ◽  
Ande Zou ◽  
...  

There are two kinds of relationships between magmatism and the generation of hydrocarbons from source rocks in petroliferous basins, namely: (1) simultaneous magmatism and hydrocarbon generation, and (2) magmatism that occurs after hydrocarbon generation. Although the influence of magmatism on hydrocarbon source rocks has been extensively studied, there has not been a systematic comparison between these two relationships and their influences on hydrocarbon generation. Here, we present an overview of the influence of magmatism on hydrocarbon generation based on the results of simulation experiments. These experiments indicate that the two relationships outlined above have different influences on the generation of hydrocarbons. Magmatism that occurred after hydrocarbon generation contributed deeply sourced hydrogen gas that improved liquid hydrocarbon productivity between the mature and overmature stages of maturation, increasing liquid hydrocarbon productivity to as much as 451.59% in the case of simulation temperatures of up to 450°C during modelling where no hydrogen gas was added. This relationship also increased the gaseous hydrocarbon generation ratio at temperatures up to 450°C, owing to the cracking of initially generated liquid hydrocarbons and the cracking of kerogen. Our simulation experiments suggest that gaseous hydrocarbons dominate total hydrocarbon generation ratios for overmature source rocks, resulting in a change in petroleum accumulation processes. This in turn suggests that different exploration strategies are warranted for the different relationships outlined above. For example, simultaneous magmatism and hydrocarbon generation in an area means that exploration should focus on targets likely to host large oilfields, whereas in areas with magmatism that post-dates hydrocarbon generation the exploration should focus on both oil and gas fields. In addition, exploration strategies in igneous petroliferous basins should focus on identifying high-quality reservoirs as well as determining the relationship between magmatism and initial hydrocarbon generation.



2022 ◽  
pp. 1-42
Author(s):  
Xiaojun Zhu ◽  
Jingong Cai ◽  
Feng Liu ◽  
Qisheng Zhou ◽  
Yue Zhao ◽  
...  

In natural environments, organic-clay interactions are strong and cause organo-clay composites (a combination between organic matter [OM] and clay minerals) to be one of the predominant forms for OM occurrence, and their interactions greatly influence the hydrocarbon (HC) generation of OM within source rocks. However, despite occurring in nature, dominating the OM occurrence, and having unique HC generation ways, organo-clay composites have rarely been investigated as stand-alone petroleum precursors. To improve this understanding, we have compared the Rock-Eval pyrolysis parameters derived from more than 100 source rocks and their corresponding <2 μm clay-sized fractions (representing organo-clay composites). The results show that all of the Rock-Eval pyrolysis parameters in bulk rocks are closely positively correlated with those in their clay-sized fractions, but in clay-sized fractions the quality of OM for HC generation is poorer, in that the pyrolysable organic carbon levels and hydrogen index values are lower, whereas the residual organic carbon levels are higher than those in bulk rocks. Being integrated with the effects of organic-clay interactions on OM occurrence and HC generation, our results suggest that organo-clay composites are stand-alone petroleum precursors for HC generation occurring in source rocks, even if the source rocks exist in great varieties in their attributes. Our source material for HC generation comprehensively integrates the original OM occurrence and HC generation behavior in natural environments, which differs from kerogen and is much closer to the actual source material of HC generation in source rocks, and it calls for further focus on organic-mineral interactions in studies of petroleum systems.



2019 ◽  
Vol 7 (4) ◽  
pp. 88 ◽  
Author(s):  
Bo Liu ◽  
Liangwen Yao ◽  
Xiaofei Fu ◽  
Bo He ◽  
Longhui Bai

The first member of the Qingshankou Formation, in the Gulong Sag in the northern part of the Songliao Basin, has become an important target for unconventional hydrocarbon exploration. The organic-rich shale within this formation not only provides favorable hydrocarbon source rocks for conventional reservoirs, but also has excellent potential for shale oil exploration due to its thickness, abundant organic matter, the overall mature oil generation state, high hydrocarbon retention, and commonly existing overpressure. Geochemical analyses of the total organic carbon content (TOC) and rock pyrolysis evaluation (Rock-Eval) have allowed for the quantitative evaluation of the organic matter in the shale. However, the organic matter exhibits a highly heterogeneous spatial distribution and its magnitude varies even at the millimeter scale. In addition, quantification of the TOC distribution is significant to the evaluation of shale reservoirs and the estimation of shale oil resources. In this study, well log data was calibrated using the measured TOC of core samples collected from 11 boreholes in the study area; the continuous TOC distribution within the target zone was obtained using the △logR method; the organic heterogeneity of the shale was characterized using multiple fractal models, including the box-counting dimension (Bd), the power law, and the Hurst exponent models. According to the fractal dimension (D) calculation, the vertical distribution of the TOC was extremely homogeneous. The power law calculation indicates that the vertical distribution of the TOC in the first member of the Qingshankou Formation is multi-fractal and highly heterogeneous. The Hurst exponent varies between 0.23 and 0.49. The lower values indicate higher continuity and enrichment of organic matter, while the higher values suggest a more heterogeneous organic matter distribution. Using the average TOC, coefficient of variation (CV), Bd, D, inflection point, and the Hurst exponent as independent variables, the interpolation prediction method was used to evaluate the exploration potential of the study area. The results indicate that the areas containing boreholes B, C, D, F, and I in the western part of the Gulong Sag are the most promising potential exploration areas. In conclusion, the findings of this study are of significant value in predicting favorable exploration zones for unconventional reservoirs.



1982 ◽  
Vol 22 (1) ◽  
pp. 5
Author(s):  
A. R. Martin ◽  
J. D. Saxby

The geology and exploration history of the Triassic-Cretaceous Clarence-Moreton Basin are reviewed. Consideration of new geochemical data ('Rock-Eval', vitrinite reflectance, gas chromatography of extracts, organic carbon and elemental analysis of coals and kerogens) gives further insights into the hydrocarbon potential of the basin. Although organic-rich rocks are relatively abundant, most source rocks that have achieved the levels of maturation necessary for hydrocarbon generation are gas-prone. The exinite-rich oil-prone Walloon Coal Measures are in most parts relatively immature. Some restraints on migration pathways are evident and igneous and tectonic events may have disturbed potentially well-sealed traps. Further exploration is warranted, even though the basin appears gas-prone and the overall prospects for hydrocarbons are only fair. The most promising areas seem to be west of Toowoomba for oil and the Clarence Syncline for gas.



1992 ◽  
Vol 32 (1) ◽  
pp. 289 ◽  
Author(s):  
John Scott

The main potential source rock intervals are generally well defined on the North West Shelf by screening analysis such as Rock-Eval. The type of product from the source rocks is not well defined, owing to inadequacies in current screening analysis techniques. The implications of poor definition of source type in acreage assessment are obvious. The type of product is dependent on the level of organic maturity of the source rock, the ability of products to migrate out of the source rock and on the type of organic material present. The type of kerogen present is frequently determined by Rock-Eval pyrolysis. However, Rock-Eval has severe limitations in defining product type when there is a significant input of terrestrial organic material. This problem has been recognised in Australian terrestrial/continental sequences but also occurs where marine source rock facies contain terrestrially-derived higher plant material. Pyrolysis-gas chromatography as applied to source rock analysis provides, by molecular typing, a better method of estimating the type of products of the kerogen breakdown than bulk chemical analysis such as Rock-Eval pyrolysis.



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