Synthesis of biobased phenolic resins using catalytic pyrolysis oil and its effect on oriented strand board performance

2018 ◽  
Vol 96 (5) ◽  
pp. 475-489
Author(s):  
Erkan Sami KOKTEN ◽  
Günay Özbay ◽  
Nadir Ayrilmis
2021 ◽  
Vol 21 (7) ◽  
pp. 3955-3959
Author(s):  
Abid Farooq ◽  
Young-Kwon Park

Catalytic pyrolysis oil (CPO) was produced from lignin using the ex-situ mechanism and nanoporous HZSM-5 (SiO2/Al2O3 = 50) as a catalyst. The oil contained phenolics, esters, acids, and benzene derivatives as the major constituents. The emulsification of CPO in diesel was tested with several emulsifier combinations such as Span 80 and Tween 60, Span 80 and Atlox 4916, and Atlox 4916 and Zephrym PD3315 in the HLB range of 5.8–7.3. The HLB value of 5.8 using the combination of Span 80 and Atlox 4916 and the CPO:emulsifier:diesel ratio of 5:2:93 (wt%), provided a stable emulsion for 10 days. The physiochemical properties of that emulsion were comparable to diesel. Hence, emulsions of CPO and diesel can potentially be used as a diesel engine fuel.


2017 ◽  
Vol 167 ◽  
pp. 218-228 ◽  
Author(s):  
Vekes Balasundram ◽  
Norazana Ibrahim ◽  
Rafiziana Md Kasmani ◽  
Mohd. Kamaruddin Abd. Hamid ◽  
Ruzinah Isha ◽  
...  

2013 ◽  
Vol 873 ◽  
pp. 562-566 ◽  
Author(s):  
Juan Liu ◽  
Xia Li ◽  
Qing Jie Guo

Chlorella samples were pyrolysed in a fixed bed reactor with γ-Al2O3 or ZSM-5 molecular sieve catalyst at 600°C. Liquid oil samples was collected from pyrolysis experiments in a condenser and characterized for water content, kinematic viscosity and heating value. In the presence of catalysts , gas yield decreased and liquid yield increased when compared with non-catalytic pyrolysis at the same temperatures. Moreover, pyrolysis oil from catalytic with γ-Al2O3 runs carries lower water content and lower viscosity and higher heating value. Comparison of two catalytic products, the results were showed that γ-Al2O3 has a higher activity than that of ZSM-5 molecular sieve. The acidity distribution in these samples has been measured by t.p.d, of ammonia, the γ-Al2O3 shows a lower acidity. The γ-Al2O3 catalyst shows promise for production of high-quality bio-oil from algae via the catalytic pyrolysis.


2015 ◽  
Vol 29 (6) ◽  
pp. 3707-3714 ◽  
Author(s):  
Christian Lindfors ◽  
Ville Paasikallio ◽  
Eeva Kuoppala ◽  
Matti Reinikainen ◽  
Anja Oasmaa ◽  
...  

BioResources ◽  
2014 ◽  
Vol 9 (4) ◽  
Author(s):  
Valentina D. Ciobanu ◽  
Octavia Zeleniuc ◽  
Adela-Eliza Dumitrascu ◽  
Badea Lepadatescu ◽  
Bogdan Iancu

Molecules ◽  
2020 ◽  
Vol 25 (20) ◽  
pp. 4846
Author(s):  
Emmanouil Karagiannidis ◽  
Charles Markessini ◽  
Eleftheria Athanassiadou

Micro-Fibrillated Cellulose (MFC) is a new type of bio-based additive, coming from wood cellulose. It can compete and substitute oil derived chemicals in several application fields. In the present work, the use of micro-fibrillated cellulose, in waterborne adhesive systems applied in the manufacture of composite wood-based panels was evaluated. Research was conducted to test the potential of improving the performance of wood-based panel types such as particleboard, waferboard or randomly-oriented strand board and plywood, by the application of MFC and the substitution of conventional and non-renewable chemical compounds. The approaches followed to introduce MFC into the adhesive systems were three, i.e., MFC 2% suspension added during the adhesive resin synthesis, MFC 10% paste admixed with the already prepared adhesive resin and MFC 2% suspension admixed with the already prepared resin. It was found that MFC improves not only the performance of the final wood panel products but also the behaviour of the applied adhesive polymer colloids (e.g., rheology improvement), especially when admixed with the already prepared resins. Moreover, it was proven that when MFC is introduced into the adhesive resin system, there is a possibility of decreasing the resin consumption, by maintaining the board performance. MFC’s robustness to pH, shear and temperature makes it a highly interesting new additive for adhesive producers. In addition, its natural origin can give adhesive producers the opportunity to move over to more environmentally friendly product solutions.


Energy ◽  
2017 ◽  
Vol 141 ◽  
pp. 2186-2195 ◽  
Author(s):  
Hossein Jahromi ◽  
Foster A. Agblevor

BioResources ◽  
2021 ◽  
Vol 16 (4) ◽  
pp. 6661-6668
Author(s):  
Fabiane Salles Ferro ◽  
Felipe Nascimento Arroyo ◽  
Edson Fernando Castanheira Rodrigues ◽  
Iuri Fazolin Fraga ◽  
João Paulo Boff Almeida ◽  
...  

Mercury intrusion porosimetry (MIP) is a technique used to characterize the pore size distribution and resin penetration in lignocellulosic materials, such as oriented strand board specimens (OSB), a multilayer panel utilized in structural applications. The method is based on the isostatic injection, under very high pressure, of a non-wetting fluid (mercury) into the porous material to determine parameters such as pore size distribution and percentage of porosity of the specimens. In this study, five different OSB were analyzed; they contained different wood species, resin type, and resin content. The panels manufactured with castor oil polyurethane resin showed porosity values in the range of 54.7 and 27.8%. This was a promising result compared with those obtained for panels made with phenolic resins, which are currently commercialized in Brazil.


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