Influence of Temperature-Time Mode of Crystallization on Electrophysical Characteristics of the Polypropylene/Magnetite Nanocomposite

2019 ◽  
Vol 201 (1) ◽  
pp. 218-223
Author(s):  
M. A. Ramazanov ◽  
H. A. Shirinova ◽  
F. V. Hajiyeva ◽  
A. Kh. Karimova
Keyword(s):  
Magnetic Field ◽  
Dielectric Permittivity ◽  
Cooling Rate ◽  
Polymer Nanocomposites ◽  
Hot Pressing ◽  
Nanocomposite Materials ◽  
Negative Magnetoresistance ◽  
Electrophysical Properties ◽  
Influence Of Temperature ◽  
Temperature Time

In the present study, the influence of the temperature–time mode of crystallization (TTC) on the electrophysical properties of polymer-based PP + Fe3O4 nanocomposite materials was investigated. Also, the effect of the temperature-time mode of crystallization of nanocomposites on the negative magnetoresistance (NMR) effect that observed in this material was investigated. It was found that dielectric permittivity of polymer nanocomposites rises with increasing of cooling rate. The cooling rate of nanocomposites after hot-pressing also affects the NMR effect of these materials. The conductivity of the material under the influence of magnetic field improves with increasing of its cooling rate, which leads to increasing of NMR effect.

Negative magnetoresistance of polymer nanocomposites on the basis of PP + Fe3O4 and PVDF + Fe3O4 in the magnetic field

2018 ◽  
Vol 537 (1) ◽  
pp. 191-197 ◽  
Author(s):  
M. A. Ramazanov ◽  
A. M. Maharramov ◽  
Luca Di Palma ◽  
H. A. Shirinova ◽  
F. V. Hajiyeva ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Polymer Nanocomposites ◽  
Negative Magnetoresistance ◽  
The Magnetic Field

scholarly journals Nanocomposites for Food Packaging Applications: An Overview

Nanomaterials ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 10
Author(s):  
Jawad Sarfraz ◽  
Tina Gulin-Sarfraz ◽  
Julie Nilsen-Nygaard ◽  
Marit Kvalvåg Pettersen
Keyword(s):  
Polymer Nanocomposites ◽  
Circular Economy ◽  
Food Packaging ◽  
Antioxidant Properties ◽  
Nanocomposite Materials ◽  
Consumer Acceptability ◽  
Special Focus ◽  
Packaging Materials ◽  
Mechanical And Thermal Properties ◽  
Low Concentrations

There is a strong drive in industry for packaging solutions that contribute to sustainable development by targeting a circular economy, which pivots around the recyclability of the packaging materials. The aim is to reduce traditional plastic consumption and achieve high recycling efficiency while maintaining the desired barrier and mechanical properties. In this domain, packaging materials in the form of polymer nanocomposites (PNCs) can offer the desired functionalities and can be a potential replacement for complex multilayered polymer structures. There has been an increasing interest in nanocomposites for food packaging applications, with a five-fold rise in the number of published articles during the period 2010–2019. The barrier, mechanical, and thermal properties of the polymers can be significantly improved by incorporating low concentrations of nanofillers. Furthermore, antimicrobial and antioxidant properties can be introduced, which are very relevant for food packaging applications. In this review, we will present an overview of the nanocomposite materials for food packaging applications. We will briefly discuss different nanofillers, methods to incorporate them in the polymer matrix, and surface treatments, with a special focus on the barrier, antimicrobial, and antioxidant properties. On the practical side migration issues, consumer acceptability, recyclability, and toxicity aspects will also be discussed.

scholarly journals Synthesis and Characterization of Clay Polymer Nanocomposites of P(4VP-co-AAm) and Their Application for the Removal of Atrazine

Polymers ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 721 ◽  
Author(s):  
Jorge A. Ramírez-Gómez ◽  
Javier Illescas ◽  
María del Carmen Díaz-Nava ◽  
Claudia Muro-Urista ◽  
Sonia Martínez-Gallegos ◽  
...  
Keyword(s):  
Polymer Nanocomposites ◽  
Nanocomposite Materials ◽  
Synthesis And Characterization ◽  
Cross Linking ◽  
X Ray Diffraction ◽  
Numerous Species ◽  
X Ray ◽  
Different Types ◽  
Synthesized Materials

Atrazine (ATZ) is an herbicide which is applied to the soil, and its mechanism of action involves the inhibition of photosynthesis. One of its main functions is to control the appearance of weeds in crops, primarily in corn, sorghum, sugar cane, and wheat; however, it is very toxic for numerous species, including humans. Therefore, this work deals with the adsorption of ATZ from aqueous solutions using nanocomposite materials, synthesized with two different types of organo-modified clays. Those were obtained by the free radical polymerization of 4-vinylpyridine (4VP) and acrylamide (AAm) in different stoichiometric ratios, using tetrabutylphosphonium persulfate (TBPPS) as a radical initiator and N,N′-methylenebisacrylamide (BIS) as cross-linking agent. The structural, morphological, and textural characteristics of clays, copolymers, and nanocomposites were determined through different analytical and instrumental techniques, i.e., X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and thermogravimetric analysis (TGA). Adsorption kinetics experiments of ATZ were determined with the modified and synthesized materials, and the effect of the ratio between 4VP and AAm moieties on the removal capacities of the obtained nanocomposites was evaluated. Finally, from these sets of experiments, it was demonstrated that the synthesized nanocomposites with higher molar fractions of 4VP obtained the highest removal percentages of ATZ.

scholarly journals Effect of cooling rate after hot pressing on electrical conductivity of Si3N4-ceramics with TiO2 and TiH2 additives

2010 ◽  
Vol 4 (2) ◽  
pp. 63-68 ◽  
Author(s):  
Iryna Cherniakova ◽  
Svitlana Zdolnik ◽  
Vitaly Petrovsky
Keyword(s):  
Electrical Conductivity ◽  
Cooling Rate ◽  
Hot Pressing ◽  
Flip Chip ◽  
State Level ◽  
Trap State ◽  
Chip Technology ◽  
Strongly Connected ◽  
Sensitive Property ◽  
Si3n4 Ceramics

It has been established that cooling rate after hot pressing has influence on microstructure, electrical conductivity and charge storage in Si3N4 ceramics with TiO2 and TiH2 additives, which can be used as substrates for the large capacity micro assemblies by Flip-Chip technology. It was shown that the critical cooling rate is 30?C/min for the Si3N4-TiO2 and 50?C/min for the Si3N4-TiH2 ceramics. Electrical conductivity is structurally sensitive property, strongly connected with evolution of Si3N4 microstructure. The best properties are typical for Si3N4 ceramics characterized by mono-trap state level with the activation energy of about 0.8 eV, obtained at the characteristic cooling rates. .

scholarly journals Смена знака магнитоемкости в парамагнитной области в катион-замещенном селениде марганца

2018 ◽  
Vol 60 (4) ◽  
pp. 670
Author(s):  
С.С. Аплеснин ◽  
М.Н. Ситников ◽  
А.М. Живулько
Keyword(s):  
Magnetic Field ◽  
Solid Solution ◽  
Magnetic Susceptibility ◽  
Dielectric Loss ◽  
Dielectric Permittivity ◽  
Room Temperature ◽  
Frequency Range ◽  
Wagner Model ◽  
Paramagnetic Region ◽  
Orbital Electron

AbstractThe capacity and the dielectric loss tangent of a Gd_ x Mn_1– x Se ( x ≤ 0.2) solid solution have been measured in the frequency range 1–300 kHz without a magnetic field and in a magnetic field of 8 kOe in the temperature range 100–450 K, and the magnetic moment of the solid solution has been measured in a field of 8.6 kOe. The magnetocapacity effect and the change in the magnetocapacity sign have been observed in room temperature in the paramagnetic region. A correlation of the changes in the dielectric permittivity and the magnetic susceptibility with temperature has been revealed. The magnetocapacity is described using the model with orbital electron ordering and the Maxwell–Wagner model.

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