scholarly journals FIRST-ORDER RESONANCE OVERLAP AND THE STABILITY OF CLOSE TWO-PLANET SYSTEMS

2013 ◽  
Vol 774 (2) ◽  
pp. 129 ◽  
Author(s):  
Katherine M. Deck ◽  
Matthew Payne ◽  
Matthew J. Holman
2008 ◽  
Vol 73 (3) ◽  
pp. 271-282 ◽  
Author(s):  
Jelena Zvezdanovic ◽  
Dejan Markovic

The stability of chlorophylls toward UV irradiation was studied by Vis spectrophotometry in extracts containing mixtures of photosynthetic pigments in acetone and n-hexane. The chlorophylls underwent destruction (bleaching) obeying first-order kinetics. The bleaching was governed by three major factors: the energy input of the UV photons, the concentration of the chlorophylls and the polarity of the solvent, implying different molecular organizations of the chlorophylls in the two solvents.


1966 ◽  
Vol 21 (11) ◽  
pp. 1953-1959 ◽  
Author(s):  
R. Saison ◽  
H. K. Wimmel

A check is made of a stabilization theorem of ROSENBLUTH and KRALL (Phys. Fluids 8, 1004 [1965]) according to which an inhomogeneous plasma in a minimum-B field (β ≪ 1) should be stable with respect to electrostatic drift instabilities when the particle distribution functions satisfy a condition given by TAYLOR, i. e. when f0 = f(W, μ) and ∂f/∂W < 0 Although the dispersion relation of ROSENBLUTH and KRALL is confirmed to first order in the gyroradii and in ε ≡ d ln B/dx z the stabilization theorem is refuted, as also is the validity of the stability criterion used by ROSEN-BLUTH and KRALL, ⟨j·E⟩ ≧ 0 for all real ω. In the case ωpi ≫ | Ωi | equilibria are given which satisfy the condition of TAYLOR and are nevertheless unstable. For instability it is necessary to have a non-monotonic ν ⊥ distribution; the instabilities involved are thus loss-cone unstable drift waves. In the spatially homogeneous limiting case the instability persists as a pure loss cone instability with Re[ω] =0. A necessary and sufficient condition for stability is D (ω =∞, k,…) ≦ k2 for all k, the dispersion relation being written in the form D (ω, k, K,...) = k2+K2. In the case ωpi ≪ | Ωi | adherence to the condition given by TAYLOR guarantees stability.


2012 ◽  
Vol 32 (1) ◽  
pp. 9-14 ◽  
Author(s):  
Tatiane Regina Albarici ◽  
José Dalton Cruz Pessoa

This study assesses the storage temperature effect on the anthocyanins of pasteurized and unpasteurized açaí pulp. The data was obtained using a pasteurized and lyophilized pulp (PLP) to evaluate the temperature effect (0, 25, and 40 °C). Part of non-pasteurized frozen pulp (NPP) was pasteurized (NPP-P) at 90 °C for 30 seconds; both pulps were stored at 40 °C. The anthocyanin content reduction in the drink was evaluated from the half-life time (t1/2), activation energy (Ea), temperature quotient (Q10), and the reaction rate constant (k). The t1/2 of the PLP anthocyanins stored at 40 °C was 1.8 times less than that stored at 25 °C and 15 times less than that stored at 0 °C; therefore, the higher temperatures decreased the stability of anthocyanins. The pasteurization increased the t1/2 by 6.6 times (10.14 hours for NPP and 67.28 hours for NPP-P). The anthocyanin degradation on NPP-P followed a first order kinetic, while NPP followed a second order kinetic; thus it can be said that the pasteurization process can improve the preservation of anthocyanins in the pulp.


1932 ◽  
Vol 6 (4) ◽  
pp. 417-427 ◽  
Author(s):  
C. C. Coffin

The gaseous decompositions of the esters butylidene diacetate and ethylidene dipropionate have been studied from points of view previously outlined in papers on the decomposition of ethylidene diacetate (2, 3). The decomposition velocities have been measured at initial pressures of from 5 to 56 cm. of mercury and at temperatures between 211 and 265 °C. The reactions are homogeneous and of the first order. They agree with the Arrhenius equation and give 100% yields (within experimental error) of an aldehyde and an anhydride. The preparation of the compounds and improvements in the technique of the velocity measurements are described.While the specific velocities of the three reactions at any temperature are somewhat different, their activation energies are the same. It is suggested that in the case of such simple reactions, which are strictly localized within the molecular structure, the activation energy can be identified as the maximum energy that the reactive bonds may possess and still exist; i.e., it may be taken as a measure of the stability of the bonds which are broken in the reaction. The suggestion is also made that for a series of reactions which have the same activation energy, the specific velocities can be taken as a relative measure of the number of internal degrees of freedom that contribute to the energy of activation. On the basis of these assumptions it becomes possible to use reaction-velocity measurements for the investigation of intramolecular energy exchange. The theoretical significance of the data is further discussed and the scope of future work in this connection is indicated.The monomolecular velocity constants (sec−1) of the decomposition of ethylidene diacetate, ethylidene dipropionate and butylidene diacetate are given respectively by the equations [Formula: see text], [Formula: see text], and [Formula: see text].


2014 ◽  
Vol 34 (3) ◽  
pp. 639 ◽  
Author(s):  
JinRong Wang ◽  
Michal Fečkan ◽  
Yong Zhou

2007 ◽  
Vol 3 (1) ◽  
pp. 133-142 ◽  
Author(s):  
Ishaq Abdullah Zaafarany

Abstract          The kinetics of sol-gel transformation between A13+, La 3+ and Th4+ metal ion electrolytes and sodium alginate sol have been studied complexometrically at various  temperatures. In the presence of a large excess of sodium alginate sol concentration over that of metal ion electrolyte, the pseudo first–order plots of exchange showed sigmoidal curves with two distinct stages. The initial part was relatively fast and curved significantly at early times, followed by a slow decrease in the rates of exchange over longer time periods. The rate constants of gelation showed second-order overall kinetics which was first order in the concentration of both reactants. The thermodynamic parameters have been evaluated and tentative gelation mechanisms consistent with the kinetic results of gelation are suggested. The stability of these ionotropic metal-alginate complexes has been discussed in terms of the coordination geometry and strength of chelated bonds.


2021 ◽  
Vol 50 (6) ◽  
pp. 1799-1814
Author(s):  
Norazak Senu ◽  
Nur Amirah Ahmad ◽  
Zarina Bibi Ibrahim ◽  
Mohamed Othman

A fourth-order two stage Phase-fitted and Amplification-fitted Diagonally Implicit Two Derivative Runge-Kutta method (PFAFDITDRK) for the numerical integration of first-order Initial Value Problems (IVPs) which exhibits periodic solutions are constructed. The Phase-Fitted and Amplification-Fitted property are discussed thoroughly in this paper. The stability of the method proposed are also given herewith. Runge-Kutta (RK) methods of the similar property are chosen in the literature for the purpose of comparison by carrying out numerical experiments to justify the accuracy and the effectiveness of the derived method.


2020 ◽  
Vol 1 (2) ◽  
pp. 54-62
Author(s):  
Naser Al Amery ◽  
Hussein Rasool Abid ◽  
Shaobin Wang ◽  
Shaomin Liu

In this study, two improved versions of UiO-66 were successfully synthesised. Modified UiO-66 and UiO-66-Ce were characterised to confirm the integrity of the structure, the stability of functional groups on the surface and the thermal stability. Activated samples were used for removal harmful anionic dye (methyl orange) (MO) from wastewater. Batch adsorption process was relied to investigate the competition between those MOFs for removing MO from aqueous solution. Based on the results, at a higher initial concentration, the maximum MO uptake was achieved by UiO-66-Ce which was better than modified-UiO-66. They adsorbed 71.5 and 62.5 mg g-1 respectively. Langmuir and Freundlich isotherms were employed to simulate the experimental data. In addition, Pseudo first order and Pseudo second order equations were used to describe the dynamic behaviour of MO through the adsorption process. The high adsorption capacities on these adsorbents can make them promised adsorbents in industrial areas.


1996 ◽  
Vol 27 (3) ◽  
pp. 219-225
Author(s):  
M. S. N. MURTY

In this paper we investigate the close relationships between the stability constants and the growth behaviour of the fundamental matrix to the general FPBVP'S associated with the general first order matrix differential equation.


Sign in / Sign up

Export Citation Format

Share Document