Influence of core property on multi-electron process in slow collisions of isocharged sequence ions with neon

2010 ◽  
Vol 19 (11) ◽  
pp. 115202 ◽  
Author(s):  
Rong-Chun Lu ◽  
De-Yang Yu ◽  
Cao-Jie Shao ◽  
Fang-Fang Ruan ◽  
Xiao-Hong Cai
2018 ◽  
Author(s):  
Veejendra Yadav ◽  
Dasari L V K Prasad ◽  
Arpita Yadav ◽  
Maddali L N Rao

<p>The torquoselectivity of conrotatory ring opening of 3-carbomethoxycyclobutene is controlled by p<sub>C1C2</sub>→s*<sub>C3C4</sub> and s<sub>C3C4</sub>→p*<sub>CO</sub> interactions in the transition state in a 4-electron process as opposed to only s<sub>C3C4</sub>→p*<sub>CO</sub> interaction in an apparently 8-electron event in 3-carbomethoxy-1,2-benzocyclobutene. The ring opening of 3-carbomethoxy-1,2-benzocyclobutene is sufficiently endothermic. We therefore argue that the reverse ring closing reaction is faster than the forward ring opening reaction and, thus, it establishes an equilibrium between the two and subsequently allows formation of the more stable species <i>via</i> outward ring opening reaction. Application of this argument to 3-dimethylaminocarbonyl-1,2-benzocyclobutene explains the predominantly observed inward opening.</p>


Author(s):  
Bart J. Wilson

What is property, and why does our species happen to have it? The Property Species explores how Homo sapiens acquires, perceives, and knows the custom of property, and why it might be relevant for understanding how property works in the twenty-first century. Arguing from some hard-to-dispute facts that neither the natural sciences nor the humanities—nor the social sciences squarely in the middle—are synthesizing a full account of property, this book offers a cross-disciplinary compromise that is sure to be controversial: All human beings and only human beings have property in things, and at its core, property rests on custom, not rights. Such an alternative to conventional thinking contends that the origins of property lie not in food, mates, territory, or land, but in the very human act of creating, with symbolic thought, something new that did not previously exist. Integrating cognitive linguistics with the philosophy of property and a fresh look at property disputes in the common law, this book makes the case that symbolic-thinking humans locate the meaning of property within a thing. The provocative implications are that property—not property rights—is an inherent fundamental principle of economics, and that legal realists and the bundle-of-sticks metaphor are wrong about the facts regarding property. Written by an economist who marvels at the natural history of humankind, the book is essential reading for experts and any reader who has wondered why people claim things as “Mine!,” and what that means for our humanity.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Blake W. Saurels ◽  
Wiremu Hohaia ◽  
Kielan Yarrow ◽  
Alan Johnston ◽  
Derek H. Arnold

AbstractPrediction is a core function of the human visual system. Contemporary research suggests the brain builds predictive internal models of the world to facilitate interactions with our dynamic environment. Here, we wanted to examine the behavioural and neurological consequences of disrupting a core property of peoples’ internal models, using naturalistic stimuli. We had people view videos of basketball and asked them to track the moving ball and predict jump shot outcomes, all while we recorded eye movements and brain activity. To disrupt people’s predictive internal models, we inverted footage on half the trials, so dynamics were inconsistent with how movements should be shaped by gravity. When viewing upright videos people were better at predicting shot outcomes, at tracking the ball position, and they had enhanced alpha-band oscillatory activity in occipital brain regions. The advantage for predicting upright shot outcomes scaled with improvements in ball tracking and occipital alpha-band activity. Occipital alpha-band activity has been linked to selective attention and spatially-mapped inhibitions of visual brain activity. We propose that when people have a more accurate predictive model of the environment, they can more easily parse what is relevant, allowing them to better target irrelevant positions for suppression—resulting in both better predictive performance and in neural markers of inhibited information processing.


RSC Advances ◽  
2016 ◽  
Vol 6 (92) ◽  
pp. 89979-89983 ◽  
Author(s):  
Xiaolei Zhu ◽  
Li Qiao ◽  
Pingping Ye ◽  
Beibei Ying ◽  
Jun Xu ◽  
...  

We report the first example of copper(ii) catalyzed remote C–H nitration of 8-aminoquinoline amides by using sodium nitrite as nitration reagent under mild conditions in 1 minute which undergoes single electron process.


Author(s):  
Christina H. Stuelten ◽  
Ying E. Zhang

Transforming Growth Factor-β (TGF-β) is a key regulator of embryonic development, adult tissue homeostasis, and lesion repair. In tumors, TGF-β is a potent inhibitor of early stage tumorigenesis and promotes late stage tumor progression and metastasis. Here, we review the roles of TGF-β as well as components of its signaling pathways in tumorigenesis. We will discuss how a core property of TGF-β, namely its ability to change cell differentiation, leads to the transition of epithelial cells, endothelial cells and fibroblasts to a myofibroblastoid phenotype, changes differentiation and polarization of immune cells, and induces metabolic reprogramming of cells, all of which contribute to the progression of epithelial tumors.


2021 ◽  
Vol 118 (41) ◽  
pp. e2026469118
Author(s):  
Laurel Perkins ◽  
Jeffrey Lidz

The human ability to produce and understand an indefinite number of sentences is driven by syntax, a cognitive system that can combine a finite number of primitive linguistic elements to build arbitrarily complex expressions. The expressive power of syntax comes in part from its ability to encode potentially unbounded dependencies over abstract structural configurations. How does such a system develop in human minds? We show that 18-mo-old infants are capable of representing abstract nonlocal dependencies, suggesting that a core property of syntax emerges early in development. Our test case is English wh-questions, in which a fronted wh-phrase can act as the argument of a verb at a distance (e.g., What did the chef burn?). Whereas prior work has focused on infants’ interpretations of these questions, we introduce a test to probe their underlying syntactic representations, independent of meaning. We ask when infants know that an object wh-phrase and a local object of a verb cannot co-occur because they both express the same argument relation (e.g., *What did the chef burn the pizza). We find that 1) 18 mo olds demonstrate awareness of this complementary distribution pattern and thus represent the nonlocal grammatical dependency between the wh-phrase and the verb, but 2) younger infants do not. These results suggest that the second year of life is a period of active syntactic development, during which the computational capacities for representing nonlocal syntactic dependencies become evident.


2020 ◽  
Vol 139 (4) ◽  
pp. 309-318
Author(s):  
Nihat Ay

AbstractA core property of robust systems is given by the invariance of their function against the removal of some of their structural components. This intuition has been formalised in the context of input–output maps, thereby introducing the notion of exclusion independence. We review work on how this formalisation allows us to derive characterisation theorems that provide a basis for the design of robust systems.


Sign in / Sign up

Export Citation Format

Share Document