scholarly journals Gravimetric study and statistical data on the symbiotic effect of organic intermixtures on corrosion inhibition of P4 mold steel

2021 ◽  
Vol 2070 (1) ◽  
pp. 012150
Author(s):  
Roland T. Loto ◽  
Asamaige Ogaga
Keyword(s):  
Inhibition Efficiency ◽  
Statistical Data ◽  
Calculated Data ◽  
Inspection Time ◽  
Inhibition Effect ◽  
Loss Analysis ◽  
Statistical Relevance ◽  
Margin Of Error ◽  
Efficiency Data ◽  
Hcl Solution

Abstract The corrosion protection properties of the intermixed of l-leucine and vanillin (LLVL) on P4 mold steel within 1.5 M H2SO4 and HCl media was studied by weight loss analysis. Calculated data revealed the inhibition effect of the intermixed compound performed poorly at low H2SO4 concentrations due to inability of the combined inhibitor molecules to aggregate and effectively hinder the dispersion of the destructive anions to the steel surface. The inhibition efficiency decreased significantly with time to values below effective inhibitor performance. However, from mid to optimum concentration, inhibition efficiency of the compound was generally stable with time with values generally above 85%. In HCl media, the inhibition efficiency of the intermixture was generally above 80% at all concentrations with respect to the inspection time. The inhibitor compound exhibited greater stability in HCl compared to H2SO4 solution. Calculated values of standard deviation in H2SO4 were broadly greater than the outputs received in HCl due to the degree of variation between LLVL inhibition efficiency values. The margin of error at 95% confidence shows 65% of LLVL inhibition efficiency values obtained in H2SO4 solution have values above 70% inhibition efficiency with margin of error at +12.07% while in HCl solution, 100% of the LLVL inhibition efficiency data obtained is above 70% with margin of error of +1%. Analysis of variance showed the statistical relevance of inhibition efficiency in H2SO4 and HCl solution is significantly higher the corresponding relevance for inspection time with values of 70.45% and 71.18%.

Inhibition Effect of N-Octyl-2-Pyrrolidonium Chloride on the Corrosion of Mild Steel in Acidic Medium

2013 ◽  
Vol 634-638 ◽  
pp. 651-654
Author(s):  
Zi Chong Zhuang ◽  
Bao Hua Huang ◽  
Jun Liu ◽  
Yu Jing Lu ◽  
Zhan Chang Pan ◽  
...  
Keyword(s):  
Weight Loss ◽  
Mild Steel ◽  
Acidic Medium ◽  
Mixed Type ◽  
Inhibition Efficiency ◽  
Electrochemical Techniques ◽  
Inhibition Mechanism ◽  
Inhibition Effect ◽  
Hcl Solution ◽  
Mixed Type Inhibitor

A new ionic liquid, N-octyl-2-pyrrolidonium chloride (NOPC), were synthesized and evaluated as inhibitors for mild steel (Q235) corrosion in 1 mol/L HCl. The adsorption behavior and corrosion inhibition mechanism of NOPC for mild steel in HCl solution were investigated by using weight loss measurements, electrochemical techniques, and SEM. The inhibition efficiency increases with the increasing concentration of NOPC in 1 mol/L HCl and decreases as the temperature increases. The results indicate that NOPC is able to function as a mixed type inhibitor.

scholarly journals Corrosion Inhibition Effect of 1,10-Phenanthroline-5,6-diamine on Mild Steel in Hydrochloric Acid Solution

2018 ◽  
Author(s):  
Ahmed A. Al-Amiery
Keyword(s):  
Weight Loss ◽  
Hydrochloric Acid ◽  
Acid Solution ◽  
Mild Steel ◽  
Inhibition Efficiency ◽  
Inhibition Effect ◽  
Increase With Increase ◽  
Weight Loss Method ◽  
Loss Method ◽  
Hcl Solution

The inhibition impacts of 1,10-Phenanthroline-5,6-diamine (PTDA) on mild steel in 1 M HCl solution were investigated through weight loss method. The inhibition efficiencies of PTDA increase with increase in PTDA concentration at the temperature 303. Weight loss method indicate that PTDA is an excellent inhibitor the inhibition efficiency of 81.5% at the maximum PTDA concentration of 0.5 g/L at the temperature 303K.

scholarly journals Synergistic Inhibition Effect Between Capsella bursa-pastoris Extracts and Iodide Ions for Q235 Mild Steel in 1 M HCl Solution

2014 ◽  
Vol 8 (1) ◽  
pp. 31-38
Author(s):  
Qin Hu ◽  
Yubing Qiu ◽  
Guoan Zhang ◽  
Xingpeng Guo
Keyword(s):  
Mild Steel ◽  
Inhibition Efficiency ◽  
Iodide Ions ◽  
Inhibition Effect ◽  
Synergistic Inhibition ◽  
Adsorption Processes ◽  
Higher Temperature ◽  
Lower Temperature ◽  
Synergistic Inhibition Effect ◽  
Hcl Solution

The inhibition effect of Capsella bursa-pastoris extracts (CBE) and its synergistic effect with KI (CBEK) for Q235 mild steel in 1 M HCl solution were studied by electrochemical measurements. Both CBE and CBEK can serve as eco-friendly, mixed-type inhibitors, and the inhibition efficiency increases with the concentration and temperature. The synergistic parameter (SI) indicates a cooperative mechanism between the iodide anions and CBE molecules at lower temperature. The associated thermodynamic and kinetic data suggest the presence of CBEK on metal surface mainly through chemisorption at higher temperature. The adsorption processes follow Langmuir isotherm.

Corrosion Inhibition of N,N- diethylammonium O,O′- di (p-chlorophenyl) dithiophosphate for Carbon Steel in HCL Solution

2013 ◽  
Vol 781-784 ◽  
pp. 299-303
Author(s):  
Shu Lan Cai ◽  
Kang Quan Qiao ◽  
Fa Mei Feng
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Carbon Steel ◽  
Corrosion Inhibition ◽  
Mixed Type ◽  
Electrochemical Impedance ◽  
Equivalent Circuit Model ◽  
Inhibition Effect ◽  
Inhibition Process ◽  
Hcl Solution ◽  
Mixed Type Inhibitor

A new corrosion inhibior N,N-diethylammonium O,O-di (p-chlorophenyl) dithiophosphate (EDPDP) has been synthesized and its inhibition effect towards the corrosion of carbon steel in 1.0 molL-1 HCl solution at 25 °C has been investigated by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) methods. The obtained results show that EDPDP is a excellent inhibitor and the inhibition efficiencies exceed 90 %. The polarization measurements reveal that EDPDP is a mixed type inhibitor and the equivalent circuit model of the corrosion inhibition process is obtained by the analysis of EIS data.

scholarly journals Study the corrosion inhibition of mix of caffeine and iodua for CT3 steel in 1M HCl solution by electrochemical methods

2017 ◽  
Vol 33 (3) ◽  
Author(s):  
Truong Thao
Keyword(s):  
Carbon Steel ◽  
Corrosion Inhibition ◽  
Inhibition Efficiency ◽  
Electrochemical Methods ◽  
Anodic Reaction ◽  
Mild Carbon Steel ◽  
Current Densities ◽  
Hcl Solution ◽  
Surface Observations

Abstract: Corrosion inhibition of mild carbon steel, CT3,  in 1.0 M HCl solution by iodide  (with different concentrations, from 0.1g/l to 5.0g/l), mix of caffeine and iodide was investigated by electrochemical methods and micro surface observations (SEM). Experiment result showed that: (1) as the concentration of iodide increases, the inhibition efficiency increases;  Iodide acts as a mix – type inhibitor but inhibits anodic reaction is predominant. (2) Mix of 1.0 g/l iodide ang caffeine acts as a typical mix – type inhibitor. the current densities of both of anodic and cathode are decline when concentration of caffeine is 1.0 g/l or more. Inhibition efficiency max is approximately 96% at concentration of 5.0 g/l caffeine, the inhibition efficiency maintained relatively stable within 5 days.  

scholarly journals Inhibitive Effect of Costus afer Extracts on Mild Steel Corrosion in Acidic Medium

2016 ◽  
Vol 7 ◽  
pp. 60-67
Author(s):  
Lebe A. Nnanna ◽  
Wisdom O. John ◽  
Tochukwu E. Esihe ◽  
Kelechi C. Denkoro ◽  
Victor I. Okparaku ◽  
...  
Keyword(s):  
Mild Steel ◽  
Room Temperature ◽  
Inhibition Efficiency ◽  
Gravimetric Method ◽  
Steel Corrosion ◽  
Corrosion Process ◽  
Inhibition Effect ◽  
A Value ◽  
Mild Steel Corrosion ◽  
Costus Afer

Inhibition effect of Costusafer on mild steel in 0.5 M HCl was studied using gravimetric method at room temperature. It was found out that Costusafer inhibited the corrosion of mild steel in the acidic environment and that the efficiency of inhibition increased as the concentration of the inhibitor in the environment increased. The data was used to test different isotherms and it suited the Langmuir isotherm. A value of -15.995 kJmol-1 was gotten for the ∆Goads. This value showed that the extracts of Costusafer inhibited the corrosion process through physiosorption mechanism. The high value of inhibition efficiency of the extract as the concentration increased in rationalized in terms of the increase in herteroatoms, saponnins and tannins which are present in the extract.

Inhibitive Effect of Fatty Amide and Secondary Species on the Corrosion of Carbon Steel

2016 ◽  
Vol 1133 ◽  
pp. 366-370 ◽  
Author(s):  
Izni Mariah Ibrahim ◽  
Junaidah Jai ◽  
Md Amin Hashim
Keyword(s):  
Carbon Steel ◽  
Room Temperature ◽  
Inhibition Efficiency ◽  
Static Condition ◽  
Fatty Amide ◽  
Nacl Solution ◽  
Inhibition Effect ◽  
Linear Polarization Resistance ◽  
Atomic Force ◽  
Polarization Resistance Method

The effect of hydrazine, N2H4 in the presence of fatty amide as corrosion inhibitor on corrosion of carbon steel in 3.5 wt% NaCl solution was studied by linear polarization resistance method (LPRM) at room temperature and static condition. The specimens’ surface analysis was done using atomic force microscope (AFM). The inhibition efficiency improved to more than 80% when 500, 100 and 2000 ppm of hydrazine were added to the inhibited solution containing 20 ppm fatty amide. The results obtained show that the inhibition effect is increased with increase of hydrazine concentration in inhibited solution. It indicates that hydrazine retards the reduction of oxygen in the corrosion process by reacting with dissolved oxygen in the solution and thus, further it reduces the corrosion rate of carbon steel.

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