scholarly journals Enhancement of maltodextrin-based adhesive properties using ammonium dihydrogen phosphate (ADP)

2021 ◽  
Vol 891 (1) ◽  
pp. 012004
Author(s):  
G K Dewi ◽  
R Widyorini ◽  
G Lukmandaru

Abstract Maltodextrin is a new saccharide-based adhesive that can be potentially developed as an alternative for particleboard due to its abundant resources. The addition of ammonium dihydrogen phosphate (ADP) was expected to be able to improve the properties of the maltodextrin, especially the water resistance of the cured adhesive. This study aimed to investigate the properties of maltodextrin/ADP adhesive in the ratios of 100/0, 90/10 and 80/20 wt%. The results showed that the increasing ratio of ADP in maltodextrin-based adhesive can increase not only the insoluble matter rate during boiling condition, but also the other adhesive properties of maltodextrin by lowering the viscosity and increasing the wettability tested in salacca frond particles. The pH adhesive decreased along with the increased ADP ratio. Oneway analysis of variance and Tukey test showed that the maltodextrin/ADP ratios significantly affected the adhesive properties. The thermogravimetric analysis (TGA) of dried mixture adhesive showed the significant changes in the onset and the highest weight reduction temperature of maltodextrin after the ADP addition. The FTIR analysis detected some new peaks that were expected to be related to furan ring and carbonyl groups after the maltodextrin/ADP 90/10 and 80/20 wt% were heated at 200°C for 10 minutes and/or 15 minutes. Maltodextrin/ADP 80/20 wt% had the best adhesive properties for particleboard application.

2020 ◽  
Vol 840 ◽  
pp. 551-557
Author(s):  
Greitta Kusuma Dewi ◽  
Ragil Widyorini ◽  
Ganis Lukmandaru

Ammonium dihydrogen phosphate (ADP) is expected to be an effective catalyst to increase the water-resistance and hasten the curing speed of maltodextrin as wood adhesives. This research investigated the effect of ADP addition on the curing maltodextrin properties. The ratio of maltodextrin/ADP was 100/0 and 90/10 wt%. The heat treatment was 180-220 °C for 10 min. The water-resistance improvement and the chemical changes were analyzed using insoluble matter rate against boiling water and Fourier Transform Infrared (FTIR) analysis, respectively. The thermal behavior of the dried mixture of adhesives was also analyzed through differential scanning calorimetry (DSC) analysis at room temperature until 400 °C. The results showed that the water-resistance properties of maltodextrin increased with the addition of 10 wt% ADP and increasing the heating temperature. FTIR analysis detected a high water-resistant substance of furan in the adhesives with maltodextrin/ADP ratio 90/10 wt% and heat treatment of 220 °C for 10 min. DSC analysis showed that ADP addition can hasten the reaction of maltodextrin as the endotherm peak temperature was shifted from 272 to 204 °C.


Polymers ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 1251 ◽  
Author(s):  
Zhongyuan Zhao ◽  
Shin Hayashi ◽  
Wei Xu ◽  
Zhihui Wu ◽  
Soichi Tanaka ◽  
...  

Development of a bio-based wood adhesive is a significant goal for several wood-based material industries. In this study, a novel adhesive based upon sucrose and ammonium dihydrogen phosphate (ADP) was formulated in hopes of furthering this industrial goal through realization of a sustainable adhesive with mechanical properties and water resistance comparable to the synthetic resins used today. Finished particleboards exhibited excellent mechanical properties and water resistance at the revealed optimal adhesive conditions. In fact, the board properties fulfilled in principle the requirements of JIS A 5908 18 type standard, however this occured at production conditions for the actual state of development as reported here, which are still different to usual industrial conditions. Thermal analysis revealed addition of ADP resulted in decreases to the thermal thresholds associated with degradation and curing of sucrose. Spectral results of FT-IR elucidated that furanic ring chemistry was involved during adhesive curing. A possible polycondensation reaction pathway was proposed from this data in an attempt to explain why the adhesive exhibited such favorable bonding properties.


2020 ◽  
Vol 13 (2) ◽  
pp. 1
Author(s):  
E. M. Samogim ◽  
T. C. Oliveira ◽  
Z. N. Figueiredo ◽  
J. M. B. Vanini

The combine harvest for soybean crops market are currently available two types of combine with header or platform, one of conventional with revolving reel with metal or plastic teeth to cause the cut crop to fall into the auger header and the other called "draper" headers that use a fabric or rubber apron instead of a cross auger, there are few test about performance of this combine header for soybean in Mato Grosso State. The aim of this work was to evaluate the soybean harvesting quantitative losses and performance using two types combine header in four travel speed. The experiment was conducted during soybean crops season 2014/15, the farm Tamboril in the municipality of Pontes e Lacerda, State of Mato Grosso. The was used the experimental design of randomized blocks, evaluating four forward harvesting speeds (4 km h-1, 5 km h-1, 6 km h-1 and 7 km h-1), the natural crops losses were analyzed, loss caused by the combine harvester (combine header, internal mechanisms and total losses) and was also estimated the  field performance of each combine. Data were submitted to analysis of variance by F test and compared of the average by Tukey test at 5% probability. The results show the draper header presents a smaller amount of total loss and in most crop yield when compared with the conventional cross auger.


2014 ◽  
Vol 809-810 ◽  
pp. 477-484
Author(s):  
Zhao Qing Qi ◽  
Hong Tao Wang ◽  
Jun Liang Dang ◽  
Shi Hao Zhang ◽  
Jian Hua Ding

The capacity of 10%, 30%, and 50% ammonium dihydrogen phosphate were replaced with an equal amount of three phosphate (potassium dihydrogen phosphate, sodium dihydrogen phosphate, disodium hydrogen phosphate) respectively. Magnesium phosphate cement was made by phosphate of replaced, which strength, setting time, fluidity, hydration temperature, and the hydration products was researched. The results show that: MPC was made that replaced with the equal amount of three kind of phosphate, which has good mechanical properties. Setting time and fluidity change along with the replacment. Three kind of phosphate replace ammonium dihydrogen phosphate, which change the hydration process of MPC. When ammonium dihydrogen phosphate was replaced by an equal amount of disodium hydrogen phosphate, the temperature of hydration is only 69.4 °C. XRD showed that the diffraction peaks of composite’s magnesium phosphate cement increases.


2016 ◽  
Vol 675-676 ◽  
pp. 573-576 ◽  
Author(s):  
Pratya Thongpanit ◽  
Weerapong Chewpraditkul ◽  
Nakarin Pattanaboonmee

Ammonium dihydrogen phosphate (ADP) crystals is very interesting due to its nonlinear optical property. This study investigated on improving of material for academic use by adding boric acid to modify ADP crystals. Slow evaporation method in aqueous solutions of pure ADP and ADP doped with three concentrations of H3BO3 as 0.1, 1.0, 5.0 %wt were studied. The grown crystals were confirmed tetragonal structure by powder X-ray diffraction studies. The FTIR spectrum analysis presented various functional groups of boron in three conditions of doped ADP. TGA study was comfirned the temperature stability at 220 °C for both pure and doped ADP crytals. The machanical stress was analyzed by Vicker’s hardness measurement. The results of this analysis showed boric acid doped 1.0 %wt had superior machanical stress from 10 to 75 grams. ADP doped with boric acid at 1.0 %wt was accepted in all test properties.


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