scholarly journals Hydrogen Gas Production using Electro-activated Carbon Catalyst from Coconut Shells

Author(s):  
C E Rustana ◽  
D S Khaerudini ◽  
D Junia ◽  
F D Dirgantara ◽  
A Badruzzaman ◽  
...  
Author(s):  
Kelechi Angelina Iheonye ◽  
Ifeanyichukwu Edeh ◽  
Ibrahim Kolawole Muritala ◽  
Ayoade Kuye

Aim: The use of synthetic catalysts in pyrolysis of waste plastics into hydrocarbon fuels is the common practice, these synthetic/ commercial catalysts are not readily available in Nigeria. The aim of this research paper is to prepare and characterize and test the catalytic performance of a locally made catalyst for waste plastic to hydrocarbon fuel pyrolysis. Study Design: locally made catalyst was prepared from coconut shells, its elemental composition, structural morphology and pore properties investigated using appropriate instruments and methods. Place and Duration: The experiments were carried out at the Petroleum Development Laboratory, situated at the Gas Engineering building, University of Port-Harcourt Nigeria. It took about 18 months to complete this study. Methodology: Thermal and chemical activation methods were used to prepare the local catalyst from coconut shells. Scanning electron microscopy method was used to investigate the morphology and texture of the coconut shell activated carbon catalyst. Response Surface Method (RSM) in design expert software 12.0 was used to design the experiment, and investigate the effect of operating parameters on the response variable. Results: The assessment of coconut shell activated carbon shows it can be used as an alternate to synthetic catalysts. This is because more than 60 % fuel oil was recovered when it was used in the pyrolysis of waste sac bags Conclusion: Coconut shell activated carbon is effective in the conversion of waste sac bags high purity hydrocarbon fuels such as aviation kerosene.


Materials ◽  
2021 ◽  
Vol 14 (16) ◽  
pp. 4540
Author(s):  
Mahitha Udayakumar ◽  
Renáta Zsanett Boros ◽  
László Farkas ◽  
Andrea Simon ◽  
Tamás Koós ◽  
...  

The suitability of a new type of polyurethane-based composite carbon foam for several possible usages is evaluated and reported. A comparison of the properties of the as-prepared carbon foams was performed with widely available commercial biomass-derived activated carbon. Carbon foams were synthesized from polyurethane foams with different graphite contents through one-step activation using CO2. In this work, a carbon catalyst was synthesized with a moderately active surface (SBET = 554 m2/g), a thermal conductivity of 0.09 W/mK, and a minimum metal ion content of 0.2 wt%, which can be recommended for phosgene production. The composite carbon foams exhibited better thermal stability, as there is a very little weight loss at temperatures below 500 °C, and weight loss is slower at temperatures above 500 °C (phosgene synthesis: 550–700 °C). Owing to the good surface and thermal properties and the negligible metallic impurities, composite carbon foam produced from polyurethane foams are the best alternative to the conventional coconut-based activated carbon catalyst used in phosgene gas production.


2021 ◽  
Vol 1858 (1) ◽  
pp. 012088
Author(s):  
Didi Dwi Anggoro ◽  
Luqman Buchori ◽  
Mohamad Djaeni ◽  
Ratnawati ◽  
Diah Susetyo Retnowati ◽  
...  

2021 ◽  
pp. 106318
Author(s):  
Yong Li ◽  
Hong Zhao ◽  
Siyuan Chen ◽  
Shuhao Bao ◽  
Feifei Xing ◽  
...  

Animals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1784
Author(s):  
Matthias Schilde ◽  
Dirk von Soosten ◽  
Liane Hüther ◽  
Susanne Kersten ◽  
Ulrich Meyer ◽  
...  

Methane (CH4) from ruminal feed degradation is a major pollutant from ruminant livestock, which calls for mitigation strategies. The purpose of the present 4 × 2 factorial arrangement was to investigate the dose–response relationships between four doses of the CH4 inhibitor 3-nitrooxypropanol (3-NOP) and potential synergistic effects with low (LC) or high (HC) concentrate feed proportions (CFP) on CH4 reduction as both mitigation approaches differ in their mode of action (direct 3-NOP vs. indirect CFP effects). Diet substrates and 3-NOP were incubated in a rumen simulation technique to measure the concentration and production of volatile fatty acids (VFA), fermentation gases as well as substrate disappearance. Negative side effects on fermentation regarding total VFA and gas production as well as nutrient degradability were observed for neither CFP nor 3-NOP. CH4 production decreased from 10% up to 97% in a dose-dependent manner with increasing 3-NOP inclusion rate (dose: p < 0.001) but irrespective of CFP (CFP × dose: p = 0.094). Hydrogen gas accumulated correspondingly with increased 3-NOP dose (dose: p < 0.001). In vitro pH (p = 0.019) and redox potential (p = 0.066) varied by CFP, whereas the latter fluctuated with 3-NOP dose (p = 0.01). Acetate and iso-butyrate (mol %) decreased with 3-NOP dose, whereas iso-valerate increased (dose: p < 0.001). Propionate and valerate varied inconsistently due to 3-NOP supplementation. The feed additive 3-NOP was proven to be a dose-dependent yet effective CH4 inhibitor under conditions in vitro. The observed lack of additivity of increased CFP on the CH4 inhibition potential of 3-NOP needs to be verified in future research testing further diet types both in vitro and in vivo.


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