scholarly journals A Disequilibrium Reactive Transport Model for Mantle Magmatism

2020 ◽  
Author(s):  
Beñat Oliveira ◽  
Juan Carlos Afonso ◽  
Romain Tilhac
Keyword(s):  
Trace Elements ◽  
Rare Earth ◽  
Trace Element ◽  
Chemical Evolution ◽  
Reactive Transport ◽  
Major Elements ◽  
Phase Changes ◽  
Scale Model ◽  
Mid Ocean Ridge ◽  
Ocean Ridge

Abstract Besides standard thermo-mechanical conservation laws, a general description of mantle magmatism requires the simultaneous consideration of phase changes (e.g. from solid to liquid), chemical reactions (i.e. exchange of chemical components) and multiple dynamic phases (e.g. liquid percolating through a deforming matrix). Typically, these processes evolve at different rates, over multiple spatial scales and exhibit complex feedback loops and disequilibrium features. Partially as a result of these complexities, integrated descriptions of the thermal, mechanical and chemical evolution of mantle magmatism have been challenging for numerical models. Here we present a conceptual and numerical model that provides a versatile platform to study the dynamics and nonlinear feedbacks inherent in mantle magmatism and to make quantitative comparisons between petrological and geochemical datasets. Our model is based on the combination of three main modules: (1) a Two-Phase, Multi-Component, Reactive Transport module that describes how liquids and solids evolve in space and time; (2) a melting formalism, called Dynamic Disequilibirum Melting, based on thermodynamic grounds and capable of describing the chemical exchange of major elements between phases in disequilibrium; (3) a grain-scale model for diffusion-controlled trace-element mass transfer. We illustrate some of the benefits of the model by analyzing both major and trace elements during mantle magmatism in a mid-ocean ridge-like context. We systematically explore the effects of mantle potential temperature, upwelling velocity, degree of equilibrium and hetererogeneous sources on the compositional variability of melts and residual peridotites. Our model not only reproduces the main thermo-chemical features of decompression melting but also predicts counter-intuitive differentiation trends as a consequence of phase changes and transport occurring in disequilibrium. These include a negative correlation between Na2O and FeO in melts generated at the same Tp and the continued increase of the melt’s CaO/Al2O3 after Cpx exhaustion. Our model results also emphasize the role of disequilibrium arising from diffusion for the interpretation of trace-element signatures. The latter is shown to be able to reconcile the major- and trace-element compositions of abyssal peridotites with field evidence indicating extensive reaction between peridotites and melts. The combination of chemical disequilibrium of major elements and sluggish diffusion of trace elements may also result in weakened middle rare earth to heavy rare earth depletion comparable with the effect of residual garnet in mid-ocean ridge basalt, despite its absence in the modelled melts source. We also find that the crystallization of basalts ascending in disequilibrium through the asthenospheric mantle could be responsible for the formation of olivine gabbros and wehrlites that are observed in the deep sections of ophiolites. The presented framework is general and readily extendable to accommodate additional processes of geological relevance (e.g. melting in the presence of volatiles and/or of complex heterogeneous sources, refertilization of the lithospheric mantle, magma channelization and shallow processes) and the implementation of other geochemical and isotopic proxies. Here we illustrate the effect of heterogeneous sources on the thermo-mechanical-chemical evolution of melts and residues using a mixed peridotite–pyroxenite source.

Geochemical patterns in Norwegian greenstones

1982 ◽  
Vol 19 (3) ◽  
pp. 385-397 ◽  
Author(s):  
G. H. Gale ◽  
J. A. Pearce
Keyword(s):  
Trace Elements ◽  
Rare Earth ◽  
Trace Element ◽  
Tectonic Setting ◽  
Major Elements ◽  
Island Arc ◽  
Ocean Floor ◽  
Spreading Axis ◽  
Southern Norway ◽  
Representative Samples

Representative samples of Caledonian greenstones from the Grong, Joma, Løkken, Støren, Stavenes, and Bømlo areas in central and southern Norway have been analysed for major elements and over 20 trace elements. Ocean-floor tholeiite-normalized trace-element patterns and chondrite-normalized rare-earth patterns both provide clues to the genesis, original tectonic setting, petrologic character, and effects of alteration of these greenstones. We conclude that the Støren, Stavenes, and Løkken greenstones were generated at spreading axes within the Caledonian ocean, the Grong and possibly the Bømlo submarine greenstones were erupted in an island-arc system, and the Joma and Bømlo subaerial greenstones were erupted in a within-plate setting. The Løkken greenstones may have been generated in a marginal basin, whereas those from Støren and Stavenes were probably generated at a rapidly spreading axis in a major ocean.

Trace element composition of clinopyroxene in gabbros and dolerites of the Tortuga Ophiolitic Complex, southernmost Patagonia.

2021 ◽  
Author(s):  
Fernanda Torres Garcia ◽  
Mauricio Calderón ◽  
Leonardo Fadel Cury ◽  
Thomas Theye ◽  
Joachim Opitz ◽  
...  
Keyword(s):  
Trace Elements ◽  
Trace Element ◽  
Partial Melting ◽  
Mantle Source ◽  
Trace Element Composition ◽  
Element Composition ◽  
Mid Ocean Ridge ◽  
Back Arc ◽  
Ocean Ridge ◽  
Ophiolitic Complex

<p>During the Upper Jurassic-Lower Cretaceous times the western margin of Gondwana in southern Patagonia experienced extreme lithospheric extension and generation of rift and marginal back-arc basins. The ophiolitic complexes of the Rocas Verdes basin comprises incomplete ophiolite pseudostratigraphy lacking ultramafic rocks. The Tortuga Ophiolitic Complex, the southernmost seafloor remnant of the Rocas Verdes basin, record the most advanced evolutionary stage of the back-arc basin evolution in a mid-ocean ridge-type setting. The base of the Tortuga Complex consists of massive and layered gabbros, most of which are two pyroxene and olivine gabbros, leucogabbros, and clinopyroxene troctolites intruded by dikes of basalt and diabase with chilled margins. We present new major and trace element composition of clinopyroxene from the gabbros and sheeted dikes complexes to assess the geochemical affinity of parental basaltic magmas. Clinopyroxene in gabbros is mostly augite and have Al contents of 0.06-0.14 a.p.f.u. and Mg# of 80-92. Clinopyroxene in dolerites in the sheeted dike unit (augite and diopside) have Al content of 0.11-0.12 a.p.f.u. and Mg# of 85-92. Some immobile trace elements (e.g. Zr, Ti, Y) are sensitive to the degree of partial melting and mantle source composition, and can be used as a proxy for distinguishing tectonic environments. The Ti+Cr vs. Ca diagram, coupled with moderate-high TiO<sub>2</sub> content of clinopyroxene (0.4-1.4 wt.%) suggests their generation in mid-oceanic ridge-type environment (cf. Beccaluva et al., 1989).  The high Ti/Zr ratios (of ~4-11) coupled with low Zr contents (~0.2-1.1) are expected for higher degrees of partial melting or for melting of more depleted mantle sources. Conversely, low Zr/Y ratios (0.05-0.13) plot between the range of arc basalts. Chondrite-normalized REE patterns in clinopyroxene display a strong depletion of LREE compared to HREE and have an almost flat pattern in the MREE to HREE with a positive Eu (Eu*= 0.9-1.1) anomaly, indicating that clinopyroxene crystallized from a strongly depleted mid-ocean-ridge-type basalt, formed by extensive fractional melting of the mantle source and/or fractional crystallization and accumulation of anhydrous phases. The general trend of the incompatible trace elements patterns exhibit depletion in LILEs, minor HFSEs depletion, positive anomaly of Rb and negative anomalies in Ba, Zr, Ti and Nb, consistent with their generation from a refractory mantle source barely influenced by subduction components derived from the oceanic slab. This agrees with basalt generation in a back-arc basin located far away from the convergent margin. This study was supported by the Fondecyt grant 1161818 and the Anillo Project ACT-105.</p>

Trace elements in anatectic products at the roof of mid-ocean ridge magma chambers: An experimental study

2017 ◽  
Vol 456 ◽  
pp. 43-57 ◽  
Author(s):  
Martin Erdmann ◽  
Lydéric France ◽  
Lennart A. Fischer ◽  
Etienne Deloule ◽  
Jürgen Koepke
Keyword(s):  
Experimental Study ◽  
Trace Elements ◽  
Magma Chambers ◽  
Mid Ocean Ridge ◽  
Ocean Ridge

Sea-floor evolution: rare-earth evidence

1971 ◽  
Vol 268 (1192) ◽  
pp. 663-706 ◽  
Keyword(s):  
Rare Earth ◽  
Mantle Source ◽  
Upper Mantle ◽  
Gulf Of Aden ◽  
Low Velocity ◽  
East Pacific ◽  
Mid Ocean Ridge ◽  
Low Velocity Layer ◽  
Ocean Ridge ◽  
Velocity Layer

A systematic survey of rare-earth (r.e.) abundances in submarine tholeiitic basalts along mid-oceanic ridges has been made by neutron activation analysis. The r.e. fractionation patterns are remarkably uniform along each mid-oceanic ridge and from one ridge to another (Juan de Fuca Ridge, East Pacific and Chile Rise, Pacific-Antarctic, Mid-Indian and Carlsberg Ridge, Gulf of Aden, Red Sea Trough and Reykjanes Ridge). The patterns are all depleted in light r.e. except for three samples (Gulf of Aden and Mid-Indian Ridge) which are unfractionated relative to chondrites. They contrast markedly with tholeiitic plateau basalt which are shown to be related to the early volcanic phases associated with continental drift. Tholeiitic plateau basalts are light r.e. enriched as are most continental rocks. Mid-ocean ridge basalts are also distinguishable from spatially related oceanic shield volcanoes of tholeiitic composition (Red Sea Trough-Jebel Teir Is., East Pacific Rise-Culpepper Island). Thus on a r.e. basis there are tholeiites within tholeiites. The r.e. difference between mid-ocean ridge tholeiites and tholeiitic plateau basalts can be related to distinct thermal and tectonic régimes and consequently magmatic modes and rates of intrusions from the low velocity layer in the upper mantle. The difference between continental and oceanic volcanism appears to be triggered by: (1) presence or absence of a moving continental lithosphere over the low velocity layer, and (2) whether or not major rifts tap the low velocity layer through the lithosphere. Fractional crystallization during ascent of melts before eruption at the ridge crest does not affect appreciably the relative r.e. patterns. R.e. in mid-ocean ridge basalts appear to intrinsically reflect their distribution in the upper mantle source, i.e. the low velocity layer. Based on secondary order r.e. variation of mid-ocean ridge basalts: (1) If fractional crystallization is invoked for the small r.e. variations, up to approximately 50 % extraction of olivine and Ca-poor orthopyroxene in various combinations can be tolerated. However, only limited amount of plagioclase or Ca-rich clinopyroxene can be extracted, the former because of its effect on the abundance of Eu abundance and the latter because of its effect on the [La/Sm] e.f. ratio, alternatively. (2) If partial melting during ascent is invoked, and a minimum of 10% melting is assumed, the permissible degree of melting of originally a lherzolite upper mantle may vary between 10 and 30% . It is not possible to establish readily to what extent these two processes have been operative as they cannot be distinguished on the basis of r.e. data only. However, there is evidence indicating that both have been operative and are responsible for the small r.e. variations observed in mid-ocean ridge basalts. An attempt to correlate second order r.e. variations along or across mid-oceanic ridges with spreading rate, age, or distance from ridge crests has been made but the results are inconclusive. No r.e. secular variation of the oceanic crust is apparent. R.e. average ridge to ridge variations are attributed to small lateral inhomogeneities of the source of basalts in the low velocity layer, and to a certain extent, to its past history. The remarkable r.e. uniformity of mid-oceanic ridge tholeiites requires a unique and simple volcanic process to be operative. It calls for upward migration of melt or slush from a relatively homogeneous source in the mantle—the low velocity layer, followed by further partial melting during ascent. The model, although consistent with geophysics, may have to be reconciled with some evidence from experimental petrology. Models for r.e. composition of the upper mantle source of ridge basalt, formation of layers 2 and 3, and the moho-discontinuity, are also presented.

Petrogenetic insights from chromite in ultramafic cumulates of the Xiarihamu intrusion, northern Tibet Plateau, China

2020 ◽  
Vol 105 (4) ◽  
pp. 479-497 ◽  
Author(s):  
Xie-Yan Song ◽  
Kai-Yuan Wang ◽  
Stephen J. Barnes ◽  
Jun-Nian Yi ◽  
Lie-Meng Chen ◽  
...  
Keyword(s):  
Trace Elements ◽  
Major And Trace Elements ◽  
Tibet Plateau ◽  
Ultramafic Rocks ◽  
Sulfide Deposit ◽  
Northern Tibet ◽  
Mid Ocean Ridge ◽  
Ultramafic Cumulates ◽  
Positive Correlations ◽  
Ocean Ridge

Abstract Chromite is one of the earliest crystallized minerals from mafic melts and has been used as an important “petrogenetic indicator.” Its composition may be modified by interaction with intercumulate melt and adjacent minerals. Thus, chromite in mafic-ultramafic rocks contains clues to the geochemical affinity, evolution, and mantle source of its parent magmas. The Devonian Xiarihamu intrusion, located in the East Kunlun Orogenic Belt in the northern Tibet Plateau, China, hosts a very large disseminated Ni-Co sulfide deposit. This study focuses on geochemistry of the chromite enclosed in olivine of ultramafic rocks of the intrusion. Enrichments in Mg and Al in the rim of the chromite indicate only minor effects of alteration on the compositions of the chromite. The chromites enclosed in the olivines with forsterite percentage (Fo) lower than 87 are characterized by large variations in major and trace elements, such as large ranges of Cr·100/(Cr+Al) (Cr# = 15–47), Mg·100/(Mg+Fe2+) (Mg# = 41–65), and Al2O3 (= 26–53 wt%) as well as 380–3100 ppm V, 70–380 ppm Ga, and 1100–16300 ppm Zn. The chromites display positive correlations between Cr/(Cr+Al) and Ti, Mn, V, Ga, and Sc, inconsistent with fractional crystallization but indicative of an interaction between the chromites, intercumulate melts and hosting minerals. In contrast, chromites hosted in olivine with Fo > 87 in harzburgite have small variations in Cr# (ranging from 37 to 41), Mg# (48 to 51), and Al2O3 (30 to 35 wt%) as well as restricted variation in trace elements, indicating relatively weak interaction with trapped liquid and adjacent phases; these compositions are close to those of the most primitive, earliest crystallized chromites. The most primitive chromite has similarities with chromite in mid-ocean ridge basalt (MORB) in TiO2 and Al2O3 contents (0.19–0.32 and 27.9–36.3 wt%, respectively) and depletion of Sc and enrichment of Ga and Zn relative to MORB chromite. The geochemistry of the chromite indicates a partial melting of the asthenospheric mantle that was modified by melts derived from the subduction slab at garnet-stable pressures.

Geochemistry and petrogenesis of the early Proterozoic Hemlock volcanic rocks and the Kiernan sills, southern Lake Superior region

1988 ◽  
Vol 25 (4) ◽  
pp. 528-546 ◽  
Author(s):  
W. C. Ueng ◽  
T. P. Fox ◽  
D. K. Larue ◽  
J. T. Wilband
Keyword(s):  
Trace Elements ◽  
Rare Earth ◽  
North Atlantic ◽  
North Atlantic Ocean ◽  
Lake Superior ◽  
Volcanic Rocks ◽  
Wall Rock ◽  
Major Elements ◽  
Chemical Contamination ◽  
Early Proterozoic

During the early Proterozoic, the 2 km thick differentiated gabbroic Kiernan sills were emplaced into a thick accumulation of pillow basalt and associated deep-water strata, the Hemlock Formation, in the southern Lake Superior region. On the basis of major elements and trace elements (including rare-earth-element data), the Kiernan sills and the hosting volcanic rocks of the Hemlock Formation were determined to be comagmatic in origin, and both evolved from assimilation – crystal fractionation processes. The major assimilated components in these igneous rocks are identified as terrigenous sedimentary rocks. Assimilation affected the abundance of Nb, Ta, light rare-earth elements, and most likely P, Rb, Th, and K in the magma. The effect of chemical contamination from wall-rock assimilation accumulates with increasing differentiation.With wall-rock contamination carefully evaluated, a series of tectonic discriminating methods utilizing immobile trace elements indicates that the source magma was a high-Ti tholeiitic basalt similar to present-day mid-ocean-ridge basalts (MORB). It is suggested from this study that most of the enriched large-ion lithophile elements and LREE of the magma were not inherited from the mantle but from assimilation of supracrustal rocks. Chemical signatures of these rocks are distinctively different from those of arc-related volcanics. A rifting tectonic regime analogous to the opening of the North Atlantic Ocean and extrusion of North Atlantic Tertiary volcanics best fits the criteria revealed by this study.

Differentiation and source of the Nipissing Diabase intrusions, Ontario, Canada

1993 ◽  
Vol 30 (6) ◽  
pp. 1123-1140 ◽  
Author(s):  
P. C. Lightfoot ◽  
H. de Souza ◽  
W. Doherty
Keyword(s):  
Trace Element ◽  
Crustal Contamination ◽  
Primitive Mantle ◽  
Magma Source ◽  
Magma Type ◽  
Ni Content ◽  
Chemical Signatures ◽  
Mid Ocean Ridge ◽  
Ocean Ridge

Major and trace element data are presented for 2.2 Ga Proterozoic diabase sills from across the Nipissing magmatic province of Ontario. In situ differentiation of the magma coupled with assimilation of Huronian Supergroup roof sediments is responsible for the variation in composition between quartz diabase and granophyric diabase seen within many of the differentiated intrusions. Uniform trace element and isotope ratio signatures, such as La/Sm (2.8 – 3.7) and εNdCHUR (−2.7 to −5.9) characterize chilled margins and undifferentiated quartz diabases. These chemical signatures suggest the existence of a single magma source that was parental to intrusions throughout the magmatic province; this magma has higher La/Sm and lower Ti/Y than primitive mantle and is displaced towards the composition of shales. Most chilled diabases and quartz diabases have a similar Mg# (0.64 and 0.60) and Ni content (98 and 127 ppm), and it is argued that the magma differentiated at depth and was emplaced as a uniform low-Mg magma. The Wanapitei intrusion and Kukagami Lake sill are an exception in that although the quartz diabase has La/Sm similar to the Nipissing magma type, which suggests that they came from the same source, the Mg# (0.68–0.71) and Ni content (130–141 ppm) are higher, which may suggest that they are either slightly more primitive examples of the normal Nipissing magma or that cumulus hypersthene has been resorbed. The light rare earth element enriched signature of the Nipissing magmas was perhaps introduced from the continental crust as the magma migrated from the mantle to the surface, but a remarkably constant and large amount (>20%) of crustal contamination would be required. An addition of 1 –3% shale to the source of a transitional mid-ocean ridge basalt type magma can broadly reproduce the compositional features of the Nipissing magma type. The source characteristics were perhaps imparted during subduction accompanying the terminal Kenoran orogeny.

Element fluxes associated with subduction related magmatism

1991 ◽  
Vol 335 (1638) ◽  
pp. 393-405 ◽  
Keyword(s):  
Trace Element ◽  
Incompatible Element ◽  
Mantle Wedge ◽  
Isotope Ratios ◽  
Noticeable Effect ◽  
Arc Magmas ◽  
Mid Ocean Ridge ◽  
Ocean Ridge ◽  
Arc Magma ◽  
Subducted Sediment

Destructive plate margin magmas may be subdivided into two groups on the basis of their rare earth element (REE) ratios. Most island arc suites have low Ce/Yb, and remarkably restricted isotope ratios of 87 Sr/ 86 Sr = 0.7033, 143 Nd/ 144 Nd = 0.51302, 206 Pb/ 204 Pb = 18.76 , 207 Pb/ 204 Pb = 15.57, and 208 Pb/ 204 Pb = 38.4. However, they also have Rb/Sr (0.03), Th/U (2.2) and Ce/Yb (8.5) ratios which are significantly less than accepted estimates for the bulk continental crust. The high Ce/Yb suites have higher incompatible element contents, more restricted heavy REE, and much more variable isotope ratios. Such rocks are found in the Aeolian Islands, Grenada, Indonesia and Philippines, and their isotope and trace element features have been attributed both to contributions from subducted sediment, and/or old trace element enriched material in the mantle wedge. It is argued that for isotope and trace element models the slab component can usefully be taken to consist of subducted sediment and altered mid-ocean ridge basalts, since these may contain ca. 80% of the water in the subducted slab, and the distinctive trace element features of arc magmas are generally attributed to the movement of material in hydrous fluids. The isotope data indicate that not more than 15% of the Sr and Th in an average arc magma were derived from subducted material, and that the rest were derived from the mantle wedge. The fluxes of elements which cannot be characterized isotopically are more difficult to constrain, but for most minor and trace elements the slab derived contribution in arc magmas is too small to have a noticeable effect on the residual slab.

Chemical evolution of mid-ocean ridge hot springs

1985 ◽  
Vol 49 (11) ◽  
pp. 2239-2252 ◽  
Author(s):  
Teresa Suter Bowers ◽  
Karen L. Von Damm ◽  
John M. Edmond
Keyword(s):  
Chemical Evolution ◽  
Hot Springs ◽  
Mid Ocean Ridge ◽  
Ocean Ridge

Isotopic and trace element constraints on the genesis of a boninitic sequence in the Thetford Mines ophiolitic complex, Quebec, Canada

1997 ◽  
Vol 34 (9) ◽  
pp. 1258-1271 ◽  
Author(s):  
Valérie Olive ◽  
Réjean Hébert ◽  
Michel Loubet
Keyword(s):  
Trace Element ◽  
Trace Element Composition ◽  
Nd Isotope ◽  
Geodynamic Environment ◽  
The Pacific ◽  
Geochemical Study ◽  
Mid Ocean Ridge ◽  
Isochron Diagram ◽  
Component C ◽  
Ocean Ridge

The Mont Ham Massif (part of the Thetford Mines ophiolite, south Quebec) represents a magmatic sequence made up of tholeiitic and boninitic derived products. A geochemical study confirms the multicomponent mixing models that have been classically advanced for the source of boninites, with slab-derived components added to the main refractory harzburgitic peridotite. An isochron diagram of the boninitic rocks is interpreted as a mixing trend between two components: (i) a light rare earth element (LREE) enriched component (A), interpreted as slab-derived fluid–melts equilibrated with sedimentary materials (εNd = −3, 147Sm/144Nd = 0.140), and (ii) a LREE-depleted component (B) (0.21 < 147Sm/144Nd < 0.23), interpreted as slab-derived fluid–melt equilibrated with recycled Iapetus oceanic crust and equated to the Nd-isotope characteristics of the Iapetus mantle (εNd = 9). A multicomponent source is also necessary to explain the Nd-isotope and trace element composition of the tholeiites, which are explained by the melting of a more fertile, lherzolitic mantle and (or) mid-ocean ridge basalt source (component C), characterized by a large-ion lithophile element depleted pattern and an Iapetus mantle Nd isotopic composition (εNd = 9), mixed in adequate proportions with the two previously infered slab-derived components (A and B). The genesis of the boninites of Mont Ham is not significantly different from those of boninites located in the Pacific. An intraoceanic subduction zone appears to be an appropriate geodynamic environment for the Mont Ham ophiolitic sequence.

Sign in / Sign up

Export Citation Format

Share Document