Evaluation of acid corrosion resistance of Portland cement composites impregnated with polymer sulfur composite

2017 ◽  
Vol 64 (3) ◽  
pp. 273-285 ◽  
Author(s):  
Mariusz M.K. Książek
Keyword(s):  
Portland Cement ◽  
Mechanical Strength ◽  
Cement Composite ◽  
Exact Nature ◽  
Cement Composites ◽  
Portland Cement Concrete ◽  
Cent Solution ◽  
Specific Chemical ◽  
Content Type ◽  
Composite Samples

Purpose Specific chemical environments step out in the industry objects. Portland cement composites (concrete and mortar) were impregnated by using the special polymerized sulfur and technical soot as a filler (polymer sulfur composite). Sulfur and technical soot were applied as the industrial waste. Portland cement composites were made of the same aggregate, cement and water. The durability of prepared cement composite samples was tested in 5 per cent solution of HCl and 5 per cent solution of H2SO4 as a function of immersion time. The changes in mechanical strength and mass of the samples were periodically measured. Cement composites impregnated with sulfur composite exhibited limited mechanical strength and mass loss, whereas physico-mechanical properties of Portland cement concrete regressed rapidly. The loss in weight of ordinary concrete impregnated with sulfur composite, kept in aqueous solutions of acids, hydroxides, salts and in water for a year was determined using 100 × 100 × 100 mm samples. The same samples were then used in compressive strength tests. Design/methodology/approach Specific chemical environments affect industrial objects. Portland cement composites (concrete and mortar) were impregnated with a special polymerized sulfur and technical soot as a filler (polymer sulfur composite). Sulfur and technical soot were applied as industrial waste. Portland cement composites were made of the same aggregate, cement and water. The durability of the prepared cement composite samples was tested in 5 per cent solution of HCl and 5 per cent solution of H2SO4 as a function of immersion time. The changes in mechanical strength and mass of the samples were periodically measured. Cement composites impregnated with sulfur composite exhibited limited mechanical strength and mass loss, whereas the physico-mechanical properties of the Portland cement concrete regressed rapidly. The loss in weight of ordinary concrete impregnated with sulfur composite, kept in aqueous solutions of acids, hydroxides, salts and in water for a year was determined using 100 × 100 × 100 mm samples. The same samples were then used in compressive strength tests. The image analysis used for surface destruction monitoring, performed by scanning microscopy for the determination of damaged surface area and the original surface area before acid resistance testing, showed similar results. Based on the image analysis results, a model for predicting the degradation of mechanical strength during durability testing was established. The fact that the calculated and experimental strength values were not vastly different proved the validity of the proposed model. A brief summary of new products related to the special sulfur composite is given as follows: impregnation, repair, overlays and precast polymer concrete will be presented. Sulfur composite as a polymer coating impregnation, which has received little attention in recent years, currently has some very interesting applications. Findings Author comments: The article is original. The article has been written by the stated authors who are all aware of its content and approve its submission. 3. The article has not been published previously. 4. The article is not under consideration for publication elsewhere. 5. No conflict of interest exists, or if such conflict exists, the exact nature must be declared. 6. If accepted, the article will not be published elsewhere in the same form, in any language, without the written consent of the publisher. Originality/value Author comments: 1. The article is original. 2. The article has been written by the stated authors who are all aware of its content and approve its submission. 3. The article has not been published previously. 4. The article is not under consideration for publication elsewhere. 5. No conflict of interest exists, or if such conflict exists, the exact nature must be declared. 6. If accepted, the article will not be published elsewhere in the same form, in any language, without the written consent of the publisher.

Resistance to chemical attack of cement composites impregnated with a special polymer sulfur composite

2016 ◽  
Vol 34 (4) ◽  
pp. 211-229 ◽  
Author(s):  
Mariusz Książek
Keyword(s):  
Image Analysis ◽  
Portland Cement ◽  
Mechanical Strength ◽  
Surface Area ◽  
Cement Composite ◽  
Resistance Testing ◽  
Polymer Concrete ◽  
Cement Composites ◽  
Portland Cement Concrete ◽  
Specific Chemical

AbstractSpecific chemical environments affect industrial objects. Portland cement composites (concrete and mortar) were impregnated with a special polymerized sulfur and technical soot as a filler (polymer sulfur composite). Sulfur and technical soot were applied as industrial waste. Portland cement composites were made of the same aggregate, cement, and water. The durability of the prepared cement composite samples was tested in 5% solution of HCl and 5% solution of H2SO4 as a function of immersion time. The changes in mechanical strength and mass of the samples were periodically measured. Cement composites impregnated with sulfur composite exhibited limited mechanical strength and mass loss, while the physico-mechanical properties of the Portland cement concrete regressed rapidly. The loss in weight of ordinary concrete impregnated with sulfur composite, kept in aqueous solutions of acids, hydroxides, salts, and in water for a year was determined using 100×100×100 mm samples. The same samples were then used in compressive strength tests. The image analysis used for surface destruction monitoring, performed by scanning microscopy for the determination of damaged surface area and the original surface area before acid resistance testing, showed similar results. Based on the image analysis results, a model for predicting the degradation of mechanical strength during durability testing was established. The fact that the calculated and experimental strength values were not vastly different proved the validity of the proposed model. A brief summary of new products related to the special sulfur composite is given as follows: impregnation, repair, overlays, and precast polymer concrete will be presented. Sulfur composite as a polymer coating impregnation, which has received little attention in recent years, currently has some very interesting applications.

scholarly journals Using scanned images to estimate salt formation on the surface of cement composites

Vestnik MGSU ◽  
2020 ◽  
pp. 1523-1533
Author(s):  
Vladimir T. Erofeev ◽  
Victor V. Afonin ◽  
Tatiana F. Elchishcheva ◽  
Marina M. Zotkina ◽  
Irina V. Erofeeva
Keyword(s):  
Building Materials ◽  
Control Sample ◽  
Cement Composite ◽  
Operating Conditions ◽  
Cement Composites ◽  
High Humidity ◽  
Grayscale Image ◽  
Salt Formation ◽  
Scanned Images ◽  
Composite Samples

Introduction. An engineering method is proposed for assessing salt formation on the surface of cement composites exposed to adverse operating conditions. The technique is based on the histogram method used to determine the dominant brightness of the half-tone image of scanned cement composites. The criterion for ranking composites is a relative dimensionless value –– a metric obtained by comparing the brightness of a grayscale image with the brightness level of white. Materials and methods. We selected three types of compositions of composites in the amount of 21 items; each of them contains three samples –– a control sample and samples exposed to high humidity and positive temperatures for 15 and 45 days. Each composition is represented by a scanned raster image of the sample surface. The images are further subjected to digital processing using a software program written in the C++ programming language and the OpenCV technical vision library. This allows you to use the available methods and classes to develop algorithms to solve the problem in question and to convert a full-color RGB image to a grayscale image. Such images are used to analyze histograms, which determine the dominant level of brightness to determine the numerical metric for quantifying the salt formation on the surface of cement composite samples on the basis of their scanned images. Results. A description of the software algorithm, used to detect salt formation on the surface of cement composite specimens that have passed performance tests under high humidity conditions at positive temperatures, is presented. The method of ranking cement composite samples using the values of their dominant brightness relative to the brightness of control samples is shown. The comparative analysis of the study is presented in the form of numerical data and explanatory diagrams. Conclusions. Software modeling is employed to demonstrate the expediency of the methodology for the assessment of salt formation on the surface of cement composites and other building materials prone to salt formation.

Structure and Mechanical Properties of Portland Cement-Polyacrylnitril Fiber Composites

1987 ◽  
Vol 114 ◽  
Author(s):  
I. Odler
Keyword(s):  
Mechanical Properties ◽  
Composite Materials ◽  
Portland Cement ◽  
Fracture Mechanism ◽  
Cement Composite ◽  
Fiber Composites ◽  
Cement Composites ◽  
Cement Ratio ◽  
Variable Water ◽  
Pan Fibers

ABSTRACTA series of fiber-cement composite materials was prepared by dispersing different amounts of polyacrylnitril (PAN) fibers in portland cement suspensions of variable water/solid ratios. The samples were used to study the effect of the volume of fibers and the water-cement ratio on the physico-mechanical properties of the material. The distribution of the fibers within the cementitious matrix and the fracture mechanism were studied by SEM and compared with those existing in glass fiber-cement composites.

Gypsum-Cement Composites Based on Volcanic Ash

2020 ◽  
Vol 1011 ◽  
pp. 136-143
Author(s):  
Tolya Khezhev ◽  
Tamerlan Badziev ◽  
Talib Soblirov ◽  
Timur Tamashev
Keyword(s):  
Portland Cement ◽  
Volcanic Ash ◽  
Water Resistance ◽  
Central Area ◽  
Cement Composite ◽  
Strength Properties ◽  
Cement Composites ◽  
Basalt Fibers ◽  
Initial Matrix ◽  
Optimization Parameters

The studies’ results to determine the gypsum, ash and Portland cement components proportions, which would ensure a decrease in the specific binder consumption, as well as the ash grain composition’s effect on the properties of the gypsum cement pozzolan composite, are presented. It was revealed that the use of volcanic ash together with Portland cement in gypsum concrete composites allows reducing gypsum consumption by up to 50% without a significant decrease in strength characteristics. At the same time, the developed gypsum concrete composites have increased water resistance. The influence of the ash particle size distribution on the strength properties of the composite is ambiguous; in the compositions with a high ash content it is advisable to use larger fractions, and with a content of less than 50% ash in the composite, - the small fractions. To study the parameters’ effect of the dispersed reinforcement with basalt fibers on the properties of a gypsum-cement composite, an experiment with such a second-order composite rotatable plan as regular hexagon was conducted. It was found that the maximum values ​​of optimization parameters are observed in the central area of ​​the plan with and . The compressive strength of a fiber gypsum cement pozzolan composite increases by 1.15-1.18 times, when bending, by 1.56-1.72 times with respect to the strength of the initial matrix.

Development of sustainable construction material from fly ash class C

2020 ◽  
Vol 18 (6) ◽  
pp. 1615-1640
Author(s):  
Eric Asa ◽  
Monisha Shrestha ◽  
Edmund Baffoe-Twum ◽  
Bright Awuku
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Portland Cement ◽  
Alkaline Solution ◽  
Sustainable Construction ◽  
Geopolymer Concrete ◽  
Curing Time ◽  
Portland Cement Concrete ◽  
Cement Concrete ◽  
Content Type

Purpose Environmental issues caused by the production of Portland cement have led to it being replaced by waste materials such as fly ash, which is more economical and safer for the environment. Also, fly ash is a material with sustainable properties. Therefore, this paper aims to focus on the development of sustainable construction materials using 100% high-calcium fly ash and potassium hydroxide (KOH)-based alkaline solution and study the engineering properties of the resulting fly ash-based geopolymer concrete. Laboratory tests were conducted to determine the mechanical properties of the geopolymer concrete such as compressive strength, flexural strength, curing time and slump. In phase I of the study, carbon nanotubes (CNTs) were added to determine their effect on the strength of the geopolymer mortar. The results derived from the experiments indicate that mortar and concrete made with 100% fly ash C require an alkaline solution to produce similar (comparable) strength characteristics as Portland cement concrete. However, it was determined that increasing the amount of KOH generates a considerable amount of heat causing the concrete to cure too quickly; therefore, it is notable to forming a proper bond was unable to form a stronger bond. This study also determined that the addition of CNTs to the mix makes the geopolymer concrete tougher than the traditional concrete without CNT. Design/methodology/approach Tests were conducted to determine properties of the geopolymer concrete such as compressive strength, flexural strength, curing time and slump. In Phase I of the study, CNTs were studied to determine their effect on the strength of the geopolymer mortar. Findings The results derived from the experiments indicate that mortar and concrete made with 100% fly ash C require an alkaline solution to produce the same strength characteristics as Portland cement concrete. However, it was determined that increasing the amount of KOH generates too much heat causing the concrete to cure too quickly; therefore, it is notable to forming a proper bond. This study also determined that the addition of CNTs to the mix makes the concrete tougher than concrete without CNT. Originality/value This study was conducted at the construction engineering and management concrete laboratory at North Dakota State University in Fargo, North Dakota. All the experiments were conducted and analyzed by the authors.

3D printing of Portland cement-containing bodies

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Asif Ur Rehman ◽  
Vincenzo M. Sglavo
Keyword(s):  
Mechanical Properties ◽  
3D Printing ◽  
Portland Cement ◽  
Pure Water ◽  
Diffusion Mechanism ◽  
Dimensional Accuracy ◽  
Portland Cement Concrete ◽  
Content Type ◽  
Polymeric Binders ◽  
Practical Implications

Purpose Recent advances in 3D printing construction elements have focused on ordinary Portland cement (OPC) concrete using polymeric binders; herein, this study aims to produce the same using pure water. Design/methodology/approach A binder jet printer prototype was used to fabricate specimens that are used to assess geometric and mechanical properties. Two distinct water-based binder formulations, compatible with OPC chemistry and piezoelectric jetting device, were used: pure water and water-polyvinyl alcohol (98:2 w/w) solution. Findings This study examines the effect of binder flow rate on dimensional accuracy. Furthermore, the changes in the mechanical properties over time with hydration have been investigated. Practical implications Results indicate that the increase in mechanical strength of Portland cement concrete with pure water was consistent; however, it was delayed by the water: PVA (98:2 w/w) solution. Post-curing by water vapor hardened the structure with the removal of layering native to 3DP and decreased infilling porosity by diffusion mechanism. Originality/value This paper has used pure water jetting for BJT of Portland cement-containing bodies.

Development of a Capacitor Probe to Detect Subsurface Deterioration in Concrete

1997 ◽  
Vol 503 ◽  
Author(s):  
B. K. Diefenderfer ◽  
I. L. Al-Qadi ◽  
J. J. Yoho ◽  
S. M. Riad ◽  
A. Loulizi
Keyword(s):  
Dielectric Constant ◽  
Portland Cement ◽  
Electromagnetic Waves ◽  
Low Cost ◽  
Complex Dielectric Constant ◽  
Life Cycle Costs ◽  
Parallel Plates ◽  
Portland Cement Concrete ◽  
Cement Concrete ◽  
Set Up

ABSTRACTPortland cement concrete (PCC) structures deteriorate with age and need to be maintained or replaced. Early detection of deterioration in PCC (e.g., alkali-silica reaction, freeze/thaw damage, or chloride presence) can lead to significant reductions in maintenance costs. However, it is often too late to perform low-cost preventative maintenance by the time deterioration becomes evident. By developing techniques that would enable civil engineers to evaluate PCC structures and detect deterioration at early stages (without causing further damage), optimization of life-cycle costs of the constructed facility and minimization of disturbance to the facility users can be achieved.Nondestructive evaluation (NDE) methods are potentially one of the most useful techniques ever developed for assessing constructed facilities. They are noninvasive and can be performed rapidly. Portland cement concrete can be nondestructively evaluated by electrically characterizing its complex dielectric constant. The real part of the dielectric constant depicts the velocity of electromagnetic waves in PCC. The imaginary part, termed the “loss factor,” describes the conductivity of PCC and the attenuation of electromagnetic waves.Dielectric properties of PCC have been investigated in a laboratory setting using a parallel plate capacitor operating in the frequency range of 0.1 to 40.1MIHz. This capacitor set-up consists of two horizontal-parallel plates with an adjustable separation for insertion of a dielectric specimen (PCC). While useful in research, this approach is not practical for field implementation. A new capacitor probe has been developed which consists of two plates, located within the same horizontal plane, for placement upon the specimen to be tested. Preliminary results show that this technique is feasible and results are promising; further testing and evaluation is currently underway.

Mechanism of Cement Paste with Different Particle Sizes of Bottom Ash as Partial Replacement in Portland Cement

2017 ◽  
Vol 68 (10) ◽  
pp. 2367-2372 ◽  
Author(s):  
Ng Hooi Jun ◽  
Mirabela Georgiana Minciuna ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
Tan Soo Jin ◽  
Andrei Victor Sandu ◽  
...  
Keyword(s):  
Portland Cement ◽  
Construction Material ◽  
Bottom Ash ◽  
High Volume ◽  
Cement Composite ◽  
Pozzolanic Reaction ◽  
High Specific Surface Area ◽  
Partial Replacement ◽  
Natural Aggregates ◽  
Pozzolanic Properties

Manufacturing of Portland cement consists of high volume of natural aggregates which depleted rapidly in today construction field. New substitutable material such as bottom ash replace and target for comparable properties with hydraulic or pozzolanic properties as Portland cement. This study investigates the replacement of different sizes of bottom ash into Portland cement by reducing the content of Portland cement and examined the mechanism between bottom ash (BA) and Portland cement. A cement composite developed by 10% replacement with 1, 7, 14, and 28 days of curing and exhibited excellent mechanical strength on day 28 (34.23 MPa) with 63 mm BA. The porous structure of BA results in lower density as the fineness particles size contains high specific surface area and consume high quantity of water. The morphology, mineralogical, and ternary phase analysis showed that pozzolanic reaction of bottom ash does not alter but complements and integrates the cement hydration process which facilitate effectively the potential of bottom ash to act as construction material.

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