Spectral Interference of Heavy Metal Contamination on Spectral Signals of Moisture Content for Heavy Metal Contaminated Soils

2020 ◽  
Vol 58 (4) ◽  
pp. 2266-2275
Author(s):  
Haein Shin ◽  
Jaehyung Yu ◽  
Lei Wang ◽  
Yongsik Jeong ◽  
Jieun Kim
Author(s):  
Diana FLORESCU ◽  
Andreea IORDACHE ◽  
Claudia SANDRU ◽  
Elena HORJ ◽  
Roxana IONETE ◽  
...  

As a result of accidental spills or leaks, industrial wastes may enter in soil and in streams. Some of the contaminants may not be completely removed by treatment processes; therefore, they could become a problem for these sources. The use of synthetic products (e.g. pesticides, paints, batteries, industrial waste, and land application of industrial or domestic sludge) can result in heavy metal contamination of soils.


2021 ◽  
Vol 3 (2) ◽  
Author(s):  
Sharhabil Musa Yahaya ◽  
Fatima Abubakar ◽  
Nafiu Abdu

AbstractThe incidence of heavy metal contamination in Zamfara State, northern Nigeria, due to artisanal mining in some villages has resulted in the pollution of a vast area of land and water. This study evaluated the extent of environmental risks caused by heavy metals. It involved five (5) villages (Bagega, Dareta, Sunke, Tunga, and Abare) where mining activities were taking place and Anka town with no record of mining activities served as control. In each of the five villages, three sites (3) were identified as a mining site, processing site, and village making a total of sixteen (16) sites. Bulked soil samples were collected in triplicate and analyzed for iron, lead, cadmium, chromium, zinc, and nickel using flame atomic absorption spectrophotometry. Measured concentrations of the heavy metals in soils were then used to calculate the pollution and ecological risk pose by heavy metals. Their concentrations were in the order Fe > Pb > Cr > Zn > Cd > Ni, with Pb and Cd having a concentration higher than permissible levels for soils and accounted for 98.64% of the total potential ecological risk. Also, all the different pollution indices examined showed that all the sites were polluted with Cd, and all the processing sites were polluted with Pb. This reveals that processing sites pose more risk to heavy metal contamination. Correlation analysis showed a highly significant (p < 0.001) positive correlation between Pb and Zn, Cr and Ni, and a significant (p < 0.01) positive correlation between Fe and Pb, Zn and Cr. The principal component analysis suggested that Pb, Zn, Cr, and Ni likely originated from the same source, i.e., mining activities, and Fe and Cd originated from the abundant parent material in the study area.


Author(s):  
Sukirtee Chejara ◽  
Paras Kamboj ◽  
Y. V. Singh ◽  
Vikas Tandon

Heavy metal contamination has gained popularity worldwide due to their persistent nature in the environment, on the top of that non-biodegradable nature makes its accumulation easy to toxic levels. Understanding the nature of contamination has become a major concern before heavy metals deteriorate the quality of soil; to diagnose heavy metal pollution suitable indices are required. Microbial indices gaining importance because of their sensitive nature towards change in surrounding, which is the imperative quality required to select microbes as environmental indicators. Albeit enough literature is present related to this topic but the information is scattered so role of this chapter is imperative. The chapter will be helpful for the reader to provide a thorough understanding of merits and demerits of microbiological indices for heavy metal contaminated and restituted soils. The changes in microbiological indices and their mechanism of response towards heavy metal stress are effectively summarized. Research gap and future needs of microbial diagnosis of heavy metal contaminated soils are discussed.


2020 ◽  
Vol 11 (6) ◽  
pp. 1-12
Author(s):  
Cleyton Nascimento Makara ◽  
Larissa Kummer ◽  
Maurici Luzia Charnevski Del Monego

Automotive vehicles are a potential source of heavy metal contamination of the soil due to their lead-acid batteries and the use of metals in their structure and paint pigments. Understanding the characteristics of heavy metal soil contamination and identifying their environmental exposure provides important information for making decisions regarding remediation of contaminated soils. The objective of the present work was to evaluate metal contamination (Cd, Pb, Ni, Zn, Cu e Cr) in 35 soil samples (fraction<2 mm). The samples were collected from two unpaved/unsealed storage areas used by the Highway Patrol (Polícia Rodoviária Federal - PRF) for storing apprehended vehicles, one located in Araucária (AR) and one Colombo (CL), in the metropolitan region of Curitiba/PR, Brazil. Assays were performed to determine organic carbon (OC) and pH. For analysis of metals, the samples were prepared by acid digestion (method EPA 3050-B) and measured by ICP-OES. The results were evaluated according to Resolution CONAMA 420, geoaccumulation index (Igeo), contamination factor (CF) and Pearson correlation analysis. The textural composition of the soil at AR and CL reflect a high degree of heterogeneity and distinct chemical and physical characteristics. The AR site had a higher level of sand and a more acidic pH than CL, and concentrations of the analyzed elements between prevention and investigation values according to Resolution CONAMA 420/2009. The CL site had a higher concentration of clay and OC, and a less acidic pH than AR. Only one collected point at CL had a concentration of Cu above the prevention value. In both AR and CL, the element Cd was below detectability with methodology employed. The spatial distribution of the cars associated with the soil texture and the analyzed elements exhibited a random surface distribution of elements. The OC content, soil pH and texture associated with Igeo, CF and Pearson correlation suggests that both environments suffer an input of metals at different points. The input of heavy metals from stored vehicles and the possible anthropogenic impact on the soil is evident.


2018 ◽  
Vol 3 (1) ◽  
Author(s):  
Aulia Rahmaniati M ◽  
Maria Ulfah ◽  
Dewi Andini Kunti Mulangsari

Pegagan leaf (Centella asiatica L.) is one of the potential medicinal plants that are often used for the treatment of analgesics, anti-inflammatory and hepatoprotector. Because of the many benefits of leaf pegagan it is necessary to standardize the extracts to ensure the quality associated with the substance of identity, and the composition of the chemical content whose specifications are contained in the monograph as the quality requirements listed in Materia Medika Indonesia.This research is an experimental research. Samples in this study were obtained from Tawangmangu and Kediri then extract using maceration method with 96% ethanol solvent. Standardization of non-specific parameters of ethanol extract of bay leaf includes determination of moisture content, total ash content, acid unsaturated ash content, drying shrinkage, specific gravity and heavy metal contamination (Pb, As and Hg). The data of the research results are compared with the standard that has been set in the book of Indonesian Herbal Pharmacopoeia and the Book of Standardization of Natural Medicinal Material.The result of non-specific test of extract ethanol extract of gotu kola leaf from Tawangmangu obtained by water content 4,689% ± 2,165%, total ash content 3,12% ± 1,76%, acid soluble ash content 0,97% ± 0,87%, weight Type of 1.631 g / mL ± 1.277 g / mL, shrinkage dried 11.26% ± 3.355% and heavy metal contaminants 0.27 ± 0.519 mg / kg extract, As ˂0.005 μg / mL, Hg <0.001 mg / kg extract. While the result of ethanol extract of pegagan leaf from Kediri is moisture content 6,197% ± 2,489%, total ash content 4,42% ± 2,10%, ash acid unsaturated level 0,97% ± 0,98%, weight of type 1,630 g / ML ± 1,275 g / mL, shrinkage rate 3,51% ± 1,873% and heavy metal contamination Pb 0,30 ± 0,547 mg / kg extract, As ˂0,005 μg / mL, Hg 0,001 mg / kg extract. Based on these results both extracts have met the standard of non-specific parameters but the parameter content of acid soluble ash content of ethanol extract of pegagan leaf from both Tawangmangu and Kediri and drying dried from Tawangmangu does not meet the standard requirements of non-specific parameters. Keywords: ethanol extract of gotu kola leaf, non specific parameter, Standardization.


2013 ◽  
Vol 1 (No. 4) ◽  
pp. 158-163 ◽  
Author(s):  
Akbar Khalid Farooq ◽  
Hale Wiliam HG ◽  
Athar Alistair D Headley and Mohammad

Environmental pollution of heavy metals from automobiles has attained much attention in the recent past. The present research was conducted to study heavy metal contamination in roadside soils of northern England. Roadside soil samples were collected from 35 sites in some counties of northern England and analysed for four heavy metals (cadmium, copper, lead, zinc). Their concentrations and distributions in different road verge zones (border, verge, slope, ditch) were determined. Lead concentration was the highest in the soil and ranged from 25.0 to 1198.0 &mu;g/g (mean, 232.7 &mu;g/g). Zinc concentration ranged from 56.7 to 480.0 &mu;g/g (mean, 174.6 &mu;g/g) and copper concentration ranged from 15.5 to 240.0 &mu;g/g (mean, 87.3 &mu;g/g). Cadmium concentration was the lowest in the soil and varied from 0.3 to 3.8 &mu;g/g (mean, 1.4 &mu;g/g). Though the levels of heavy metals in roadside soils were higher as compared to their natural background levels in British soils, their concentrations in general, however, were below the &lsquo;critical trigger concentrations&rsquo; for the contaminated soils. All the four heavy metals exhibited a significant decrease in the roadside soils with the increasing distance from the road. The border zone had the highest mean concentration of the four metals whereas the ditch zone exhibited the lowest mean concentration.


2013 ◽  
Vol 743-744 ◽  
pp. 732-744 ◽  
Author(s):  
Hui Su ◽  
Zhang Cai ◽  
Qi Xing Zhou

More and more attention has been paid to soil contamination by heavy metals in recent years. Heavy metal contamination includes heavy metal - heavy metal contamination, heavy metal - organic contamination, and heavy metal nutrient contamination. In particular, soil contamination by cadmium (Cd) is the most typical one. In terms of the current remediation technologies, phytoremediation of Cd contaminated soil remains popular due to its low cost, environmental aesthetics and in-situ effective treatment. Therefore, screening-out and identification of Cd hyperaccumulators becomes a hotspot in this researching domain. In order to further improve the efficiency of phytoremediation, we have developed a variety of joint remediation technologies. Based on these work at home and abroad, we summed up the studying progress in this field. Some main researching contents and directions of phytoremediation for Cd contaminated soils were also proposed.


2018 ◽  
Vol 5 (1) ◽  
pp. 26-32
Author(s):  
Olamilekan L Awotedu ◽  
Paul O Ogunbamowo ◽  
Bolajoko F Awotedu ◽  
Ileri-Oluwa B Emmanuel

This study investigated the comparative phytotoxcity effect of heavy metal contamination on Jatropha curcas, Jatropha gossypifolia and Jatropha multifida in contaminated soil from a dump site in Ibadan Nigeria. Seeds of J. curcas, J. gossypifolia and J. multifida were planted in a germination tray and later transplanted into polythene pots filled with 2kg of either control soil or heavy metal contaminated soil, a 3 × 2 factorial experiment laid out in complete randomized design (CRD) replicated four times was adopted; treatments imposed include T1 – J. curcas/Control Soil, T2 – J. gossypifolia/Control Soil, T3 – J. multifida/Control Soil, T4 – J. curcas/Contaminated soil, T5 – J. gossypifolia/Contaminated Soil, and T6 – J. multifida/Contaminated Soil. Weekly variation in growth parameters: the plant height, leave production and stem diameter were measured over the course of 12 weeks. The growth parameters were dependent on a combination of both specie type and level of heavy metal contamination of soil. J. multifida (T3) (36.93cm) performed best, comparable with J. gossypiifolia (T2) (34.1cm) after 12 weeks while J. multifida (T6) had the lowest mean plant height (7.23cm) which is not significantly (p<0.05) different from other species on the contaminated soil; for leave production, J. gossypiifolia (T2) produced the highest mean number of leaves (9.67) which is comparable with J. multifida (T3) (9.00) and less so with J. curcas (T1) (6.67) with significant leave losses on the contaminated soils after 12 weeks; variation in stem diameter shows that J. curcas (T1) had the highest stem girth (1.96 mm) which is comparable to the value obtained for J. curcas (T4) (1.95mm), while J. multifida (T6) had the lowest stem girth (1.09 mm). J. gossypiifolia (T2) and J. multifida (T3) had comparable stem girth of 1.57mm and 1.47mm respectively. Toxicity of heavy metals in the contaminated soil greatly affect the growth parameters of the Jatropha.


1999 ◽  
Vol 65 (8) ◽  
pp. 3293-3297 ◽  
Author(s):  
Ruth-Anne Sandaa ◽  
Øivind Enger ◽  
Vigdis Torsvik

ABSTRACT The impact of heavy-metal contamination on archaean communities was studied in soils amended with sewage sludge contaminated with heavy metals to varying extents. Fluorescent in situ hybridization showed a decrease in the percentage of Archaea from 1.3% ± 0.3% of 4′,6-diamidino-2-phenylindole-stained cells in untreated soil to below the detection limit in soils amended with heavy metals. A comparison of the archaean communities of the different plots by denaturing gradient gel electrophoresis revealed differences in the structure of the archaean communities in soils with increasing heavy-metal contamination. Analysis of cloned 16S ribosomal DNA showed close similarities to a unique and globally distributed lineage of the kingdom Crenarchaeota that is phylogenetically distinct from currently characterized crenarchaeotal species.


2019 ◽  
pp. 1-14 ◽  
Author(s):  
Arpita Ghosh ◽  
Nikita Manchanda

Heavy metal contamination is a worldwide problem, causing many serious diseases and the levels of contamination varied from place to place. Heavy metals like cadmium (Cd), mercury (Hg), zinc (Zn), chromium (Cr), and lead (Pb) etc. are very injurious even at low concentration and are present in Yamuna river water. Phytoremediation has great potential as an efficient cleanup technology for contaminated soils, groundwater, and wastewater. It is a cheap and very efficient technique for metal removal. A study had been carried out to detect the efficiency of phytoremediation technique for removal of heavy toxic metals from water of Yamuna river. This study also focused on the phytoremediation capacity of all of three selected plants: Tagetes patula, Bassica scoparia, and Portulaca grandiflora. Bioaccumulation of heavy metals in various parts of plants has also been checked.


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