scholarly journals A Triple‐Stack Column Procedure for Rapid Separation of Cu and Zn from Geological Samples

2020 ◽  
Vol 44 (3) ◽  
pp. 407-420 ◽  
Author(s):  
Heye Freymuth ◽  
Callum D. J. Reekie ◽  
Helen M. Williams
2019 ◽  
Vol 47 (7) ◽  
pp. 1054-1060 ◽  
Author(s):  
Wen-Gang LIU ◽  
Zhi-Dan LI ◽  
Shuang WEI ◽  
Ji CHEN ◽  
Yu LIU ◽  
...  

Author(s):  
John T. Armstrong

One of the most cited papers in the geological sciences has been that of Albee and Bence on the use of empirical " α -factors" to correct quantitative electron microprobe data. During the past 25 years this method has remained the most commonly used correction for geological samples, despite the facts that few investigators have actually determined empirical α-factors, but instead employ tables of calculated α-factors using one of the conventional "ZAF" correction programs; a number of investigators have shown that the assumption that an α-factor is constant in binary systems where there are large matrix corrections is incorrect (e.g, 2-3); and the procedure’s desirability in terms of program size and computational speed is much less important today because of developments in computing capabilities. The question thus exists whether it is time to honorably retire the Bence-Albee procedure and turn to more modern, robust correction methods. This paper proposes that, although it is perhaps time to retire the original Bence-Albee procedure, it should be replaced by a similar method based on compositiondependent polynomial α-factor expressions.


Author(s):  
J. M. Paque ◽  
R. Browning ◽  
P. L. King ◽  
P. Pianetta

Geological samples typically contain many minerals (phases) with multiple element compositions. A complete analytical description should give the number of phases present, the volume occupied by each phase in the bulk sample, the average and range of composition of each phase, and the bulk composition of the sample. A practical approach to providing such a complete description is from quantitative analysis of multi-elemental x-ray images.With the advances in recent years in the speed and storage capabilities of laboratory computers, large quantities of data can be efficiently manipulated. Commercial software and hardware presently available allow simultaneous collection of multiple x-ray images from a sample (up to 16 for the Kevex Delta system). Thus, high resolution x-ray images of the majority of the detectable elements in a sample can be collected. The use of statistical techniques, including principal component analysis (PCA), can provide insight into mineral phase composition and the distribution of minerals within a sample.


2015 ◽  
Vol 14 (2) ◽  
pp. 481-486 ◽  
Author(s):  
Saglara S. Mandzhieva ◽  
Tatiana M. Minkina ◽  
Tatiana V. Bauer ◽  
Abdulmalik A. Batukaev ◽  
Marina V. Burachevskaya ◽  
...  
Keyword(s):  

2019 ◽  
Author(s):  
Chem Int

A significant flux of heavy metals, among other toxins, reaches the lungs through smoking. This study reports Cd, Pb, Cu and Zn contents in tobacco of 11 brands of cigarette commonly sold in Ethiopia. The heavy metals were determined by atomic absorption spectrophotometry after wet digestion of cigarette tobacco using HNO3 and H2O2. The concentration of trace metals in the cigarettes ranged (mean) (μg/g), Cd: 1.3−7.6 (2.48±0.32), Pb: 0.50−12.50 (6.24±2.2), Cu: 2.89−25.35 (13.70±4.12) and Zn: 24.40−62.55 (36.22±7.50) while Ni was not detected in all the eleven brands of cigarettes. Comparable levels of trace metals were obtained in the tobacco of both imported and Ethiopian cigarettes. The average trace metal contents of cigarettes available in Ethiopia were Cd 1.82±0.39, Pb 4.23±0.97, Cu 10.2±3.1 and Zn 28.2±7.8 μg/cigarette and a person who smokes 20 cigarettes per day is estimated to increase his/her daily Cd, Pb, Cu and Zn retention by approximately 0.036, 0.085, 0.204, 0.564 mg/day, respectively. The results indicate that smoking and exposure to cigarette smoke is a serious problem to be taken into account when carrying out epidemiological studies on human exposure to trace metals.


Author(s):  
Katya Peycheva ◽  
Katya Peycheva ◽  
Mona Stancheva ◽  
Mona Stancheva ◽  
Stanislava Georgieva ◽  
...  

In this study, the ecosystem marine water-sediment-biota was investigated and the pollution was assessed. The concentrations of eight elements were determined in marine water, sediments and four fish species collected from Black Sea (Varna), Bulgaria during 2013. Marine water recorded the highest concentrations of Zn (15-22 μg/L), As (1.1–1.2 μg/L) and Pb (0.7-0.8 μg/L) while Zn (31-52 μg/g), Pb (21-29 μg/g) and Cu (20-34 μg/g) and show the highest concentrations in sediments. Water and sediments showed similar spatial distribution patterns for the highest mean values of the different metals. In the analysed fish species, the highest concentration of the metals Cu and Zn were found in Trachurus Mediterrneus (0.42 mg/kg w.w) and in Sprattus Sprattus (12.7 mg/kg w.w), respectively while the heavy metals As and Hg were found with maximum values in Pseta Maxima (3.99 mg/kg w.w and 0.08 mg/kg w.w respectively). The results from this study were compared with our data for a previous period (2004-2006) and they show decrease in the levels of heavy metal.


2010 ◽  
Vol 30 (3) ◽  
pp. 292-296 ◽  
Author(s):  
Wei-cheng CHEN ◽  
Da-wei GU ◽  
Hai ZHANG ◽  
Zhen-yu ZHU ◽  
Guo-qing ZHANG ◽  
...  

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