Low-Temperature Sintered NTC Thermistor Ceramics for Thick-Film Temperature Sensors

2013 ◽  
Vol 10 (3) ◽  
pp. 428-434 ◽  
Author(s):  
Timmy Reimann ◽  
Jörg Töpfer ◽  
Stefan Barth ◽  
Heike Bartsch ◽  
Jens Müller
2012 ◽  
Vol 2012 (CICMT) ◽  
pp. 000536-000541
Author(s):  
T. Reimann ◽  
J. Töpfer ◽  
S. Barth

Printed thick film NTC thermistors and multilayer devices are frequently used for temperature control in hybrid circuits. NiMn2O4 and substituted spinels are the most established materials for this application. For low-temperature sintering at 900 °C the shrinkage behavior of the thermistor material has to be adjusted by the addition of proper sinter additives. We investigated the chemical stability of NiMn2O4 and substituted spinels in air between 25 °C and 1200 °C. The compound NiMn2O4 is stable from 700 °C to 970 °C only and interacts with the sinter additives. Stable cubic spinels were found in the system ZnxNi0,5Co0,5Mn2-zO4. Addition of liquid phase sintering additives to the spinel powders results in complete densification at 900 °C. No chemical interaction between spinel and additive was observed. The effect of Cu-substitution into the spinel was also investigated. Functional NTC pastes were printed on alumina substrates and post-fired at 900 °C. The NTC thermistor films have a sheet resistivity of about 300 kOhm/sq and B = 3300 K. The firing behavior, microstructure formation and electric properties of NTC thick films will be reported.


2001 ◽  
Vol 78 (3) ◽  
pp. 371-373 ◽  
Author(s):  
Jongsoo Yoon ◽  
John Clarke ◽  
J. M. Gildemeister ◽  
Adrian T. Lee ◽  
M. J. Myers ◽  
...  

1986 ◽  
Vol 3 (1) ◽  
pp. 33-35 ◽  
Author(s):  
Q.M. Reynolds ◽  
M.G. Norton

2016 ◽  
Vol 2016 (CICMT) ◽  
pp. 000053-000057
Author(s):  
Jaroslaw Kita ◽  
Sven Wiegärtner ◽  
Alistair Prince ◽  
Peter Weigand ◽  
Ralf Moos

Abstract The application of thermocouples as temperature sensors has been well known and has already been established for many years. However, for classical thick-film technology using screen-printing and firing, no standardized solutions exist. The here-presented newly developed PtRh thick-film compositions (90% Pt,10% Rh) allows to construct thick-film type S thermocouples (Pt/PtRh), following the IEC temperature characteristics. They can be fired in air, and therefore can be easily integrated into existing thick-film components and devices. In an earlier study, the new Pt-Rh composition was successfully tested on alumina substrates. Their electrical characteristics is equal with classical wire type S thermocouples. This study continues the investigations of thick-film thermocouples. We tested the newly developed pastes for high temperature applications on alumina substrates and evaluated the application of the new screen-printable type S thermocouples on LTCC ceramics. Three possible configurations were investigated: deposited on already fired LTCC substrates (post-fired), screen-printed and co-fired with LTCC tapes on the top surface as well as as buried structures. The paper presents the results of our evaluation and discusses further possible applications.


2016 ◽  
Vol 2016 (CICMT) ◽  
pp. 000019-000023
Author(s):  
Franz Schubert ◽  
Jaroslaw Kita ◽  
Michael Gollner ◽  
Florian Linseis ◽  
Ralf Moos

Abstract The paper presents the construction and first tests of a new sensor stack for a Tian-Calvet Calorimeter made in LTCC Technology. In contrast to typical construction where wired thermocouples are directly connected, the here-presented solution replaces wired thermocouples by screen-printed thick-film thermocouples placed on a structured disc made of Low Temperature Co-fired Ceramics (LTCC). The advantage of screen-printed thermocouples is the ease of integration of them into thick-film hybrid structures, and to simplify the device setup. Moreover, using thermocouples integrated into a ceramic disc can increase the sensitivity of the system and simultaneously reduce the production costs. The paper shows the design and fabrication of the sensor stacks. It consists of several LTCC discs and ceramic spacers. On each LTCC disc, 34 Au/Pt thermocouples were deposited. The design of the disc was supported by FEM-modelling under consideration of device specific requirements. The very initial measurements, which we conducted using two sensor stacks already exhibited a sensitivity of 8 μV/mW, which is more than satisfactory in this stage of development.


2014 ◽  
Vol 2014 (HITEC) ◽  
pp. 000172-000177
Author(s):  
Koji Sasaki ◽  
Noritsuka Mizumura

Traditional thick film technology is widely used in various electronics products. There are two type of paste based on thick film technology. Typically, over 400°C is required for high temperature sintering type which contains glass for adhesion function. It shows high electrical and thermal performance. On the other hand, 150–300°C range process is used for low temperature process type as silver epoxy. In last decade, nano silver technology shows amazing progress to address low temperature operation by low temperature sintering. This paper will discuss the results on fundamental study of newly developed nano silver pastes with unique approach which uses MO (Metallo-organic) technology and resin reinforcing technology. Nano silver pastes contain several types of dispersant as surface coating to prevent agglomeration of the particles. Various coating technique has been reported to optimize sintering performance and stability. MO technology provides low temperature sintering capability by minimizing the coating material. The nano silver pastes show high electrical and thermal performance. However, degradation of die shear strength has been found by thermal cycling test due to the fragility of porous sintered structure. To improve the mechanical property, resin reinforcing technology has been developed. By adding special resin to the pastes, the porous area is filled with the resin and the sintered structure is reinforced. Degradation of die shear strength was not found by thermal cycling test to 1000 cycles. Nano silver pastes using MO technology and resin reinforcing technology will meet lots of requirement on various thick film applications.


2012 ◽  
Vol 9 (3) ◽  
pp. 120-125 ◽  
Author(s):  
Darko Belavic ◽  
Marko Hrovat ◽  
Gregor Dolanc ◽  
Kostja Makarovic ◽  
Marina Santo Zarnik

Advanced microsystems or macrosystems are in some cases made with multilayer ceramic technology. Low-temperature cofired ceramic (LTCC) technology is considered to be one of the more suitable technologies for the fabrication of ceramic microsystems that integrate screen-printed, thick-film electronic components as well as three-dimensional buried structures, for example, cavities and channels. One of the applications is a ceramic combustor. The chemical energy of the fuel is converted into thermal energy in a chemical microcombustor through a burning process, while the accompanying high temperatures and, frequently, high pressures, impose harsh conditions on the combustor structure. Therefore, the combustor must be carefully designed not only from the functional, thermal, and chemical points of view, but also with respect to the mechanical strength. The combustor device was prepared by lamination of Du Pont 951PX LTCC green tapes. The fabricated 3D LTCC structures with buried cavities and channels including two inlets (for fuel and air), the evaporator for the fuel, the mixing system of the channels (for mixing the evaporated fuel and air), the distribution channels and eight microburners were realized. The main parts are eight microburners realized as buried cavities. In the burners, a platinum-based catalyst was deposited to assist the oxidation, that is, the burning, of the methanol with the air. Thick-film, platinum-based heaters and temperature sensors are incorporated within the structure. The device was tested with different flow rates of liquid methanol (1 mL/h to 5 mL/h) and air (7 L/h to 15 L/h). The temperatures obtained were between 250°C and 450°C.


2014 ◽  
Vol 2014 (1) ◽  
pp. 000251-000257
Author(s):  
Steven Grabey ◽  
Samson Shahbazi ◽  
Sarah Groman ◽  
Catherine Munoz

An increased interest in low temperature polymer thick film products has become apparent due to the rise of the printed electronics market. The specifications for these products are becoming more demanding with expectations that the low temperature products should perform at a level that is typically reserved for their high temperature counterparts; including solderability with lead free solders, high reliability and strong adhesion. Traditionally, it has only been possible to use leaded solders for soldering to polymer based thick film conductors. Over the last 15 years environmental concerns and legislation have pushed the industry towards a lead free approach. The shift to lead free solders, while beneficial, provides new challenges during processing. The high temperatures required for a lead-free soldering process yield a naturally harsher environment for polymer thick film pastes. In the past these conditions have proven too harsh for the pastes to survive. The polymer thick film discussed in this document aims to address some of these concerns for a highly reliable and easy to process polymer thick film paste. Due to the poor leaching characteristics of polymer thick films, at elevated temperatures, the predecessors of this paste typically soldered at low temperatures with leaded solders. The goal of this paper is to present a low temperature paste that is compatible with a variety of substrates and readily accepts lead-free solder. This paper will discuss a newly formulated low temperature curing (150°C – 200°C) RoHS and REACH compliant paste that shows excellent solderability with SAC305 solder. The paste was evaluated using a dip soldering method at 235°C–250°C on a variety of substrates. The data presented includes solder acceptance, adhesion data, thermal analysis and SEM analysis.


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