scholarly journals Effect of temperature on moisture sorption phenomena in agricultural products

2005 ◽  
Vol 53 (4) ◽  
pp. 177-184 ◽  
Author(s):  
Jiří Štencl
Keyword(s):  
Water Activity ◽  
Dynamic Method ◽  
Sorption Isotherms ◽  
Moisture Sorption ◽  
Effect Of Temperature ◽  
Relative Air Humidity ◽  
Introductory Part ◽  
Moisture Sorption Isotherms ◽  
Model Equations ◽  
Dehydration Processes

The paper demonstrates importance of temperature influence on dehydration processes using drying model equations in introductory part and further presents results of water sorption tests of parsley leaves. Measurements were carried out under laboratory conditions in the temperature range of 10–40 °C and relative air humidity from 30 to 100%. Moisture sorption isotherms were tested using a gravimetric dynamic method with continuous recording of changes in sample weight. Five mathematical models available in the literature (Chung-Pfost, GAB, Halsey, Henderson, and Oswin) were statistical evaluated. The Henderson equation was found to be a good model both for moisture adsorption and desorption. Part of the sorption isotherms measured in parsley leaves show the type II BET classification shape. An increase in temperature causes an increase in water activity for the same moisture content and, if water activity is kept constant, an increase in temperature causes a decrease in the amount of absorbed water.

scholarly journals Moisture Sorption Behaviour and Mould Ecology of Trade Garri Sold in South Eastern Nigeria

2014 ◽  
Vol 2014 ◽  
pp. 1-10 ◽  
Author(s):  
Tochukwu Samuel ◽  
J. Obeta Ugwuanyi
Keyword(s):  
Moisture Content ◽  
Water Activity ◽  
Central Africa ◽  
Sorption Isotherms ◽  
Moisture Sorption ◽  
Fungal Species ◽  
Temperature Dependent ◽  
Sorption Behaviour ◽  
Moisture Sorption Isotherms ◽  
West And Central Africa

Garri is a creamy white or yellow starchy grit produced by roasting to gelatinization and dryness of peeled, washed, mashed, and fermented dewatered cassava roots. It is the most important product of cassava in West and Central Africa. Mean moisture content of yellow and white garri was 11.11% and 10.81% within 24 hrs of sampling from the market, increasing to 17.27% and 16.14%, respectively, following 3 months of storage at room temperature. The water activity of samples varied from initial 0.587 to 0.934 following storage. Moisture sorption isotherms, determined by static gravimetric techniques at 20° and 30°C, showed temperature dependent BET Sigmoidal type II behaviour typical of carbohydrate rich foods but modulated very slightly by the content of palm oil. Equilibrium moisture content decreased with increase in temperature at constant water activity. A total of 10 fungal species belonging to the generaMucor,Penicillium,Cephalosporium,Aspergillus,Scopulariopsis,Rhizopus, and Paecilomyceswere identified, with range increasing with water activity of samples.

Moisture Sorption Isotherms and Net Isosteric Heats of Sorption of Green Soybean

2012 ◽  
Vol 8 (3) ◽  
Author(s):  
Zhao Yang ◽  
Enlong Zhu ◽  
Zongsheng Zhu
Keyword(s):  
Moisture Content ◽  
Equilibrium Moisture Content ◽  
Sorption Capacity ◽  
Water Activity ◽  
Sorption Isotherms ◽  
Moisture Sorption ◽  
Isosteric Heat ◽  
Model Parameters ◽  
Desorption Process ◽  
Moisture Sorption Isotherms

Abstract Moisture sorption isotherms of green soybean seeds were determined by static gravimetric method and water activity ranging from 0.11to 0.94 at 20, 30 and 40°C. The optimal sorption model of green soybean was determined by using nonlinear regression method. Modified BET multilayer sorption theory model parameters at different temperatures were calculated, isosteric sorption heat was derived by the water activity sorption isosteric model. Results indicated that sorption isotherms were belong to type III behaviour, a notable hysteresis effect was observed, Green soybean monolayer saturated sorption capacity was greater in desorption process than that of adsorption. The monolayer saturated sorption capacity decreased with increasing temperature, while the number of multilayer had a reverse trend with the monolayer saturated sorption capacity, the optimal sorption isotherm model for green soybean is Halsey model, The thermodynamic parameters including net isosteric heat of adsorption and desorption calculated at 40°C were 105.2-1865.4 kJ/kg and 111.62-1939.0 kJ/kg with equilibrium moisture content between 5% and 32% (d.b.), respectively. The net isosteric heat of sorption decreased with increasing equilibrium moisture content.

scholarly journals Moisture Sorption Isotherms And Thermodynamic Properties Of Urtica Dioica Leaves

2016 ◽  
Vol 12 (24) ◽  
pp. 376 ◽  
Author(s):  
Abdelkader Lamharrar ◽  
Ali Idlimam ◽  
Mohammed Kouhila ◽  
Lamya Lahnine ◽  
Hind Mouhanni
Keyword(s):  
Water Activity ◽  
Gravimetric Method ◽  
Sorption Isotherms ◽  
Moisture Sorption ◽  
Storage Conditions ◽  
Urtica Dioica ◽  
Endemic Plant ◽  
Clapeyron Equation ◽  
Moisture Sorption Isotherms ◽  
Different Temperatures

Urtica dioica is a Moroccon endemic plant of used for its virtues in traditional medicine. Thus, it is necessary to study the effect of preservation processes on the storage conditions of the plant. The static gravimetric method was used to determine sorption isotherms of Urtica dioica leaves at three temperatures (40, 50 and 60 °C) and in the range of water activity ( w a ) ranging from 0.0572 to 0.898. Six mathematical models were used to fit the experimental data. The Enderby and Peleg models were found to be the most suitable for describing the sorption curves. The optimal water activity for conservation of Urtica dioica leaves was determined. Isosteric heats of desorption and adsorption were calculated by applying the Clausius- Clapeyron equation to the sorption isotherms at different temperatures; it decreased with increasing moisture content. A linear relation exists between the enthalpy and entropy of the sorption reaction.

Effect of temperature on the moisture sorption isotherms of a heat-treated whole milk product, khoa

1991 ◽  
Vol 58 (3) ◽  
pp. 329-335 ◽  
Author(s):  
Ish K. Sawhney ◽  
Girdhari R. Patil ◽  
Bikram Kumar
Keyword(s):  
Sorption Isotherms ◽  
Moisture Sorption ◽  
Isosteric Heat ◽  
Moisture Level ◽  
Effect Of Temperature ◽  
Milk Product ◽  
Heat Treated ◽  
Moisture Sorption Isotherms ◽  
Monolayer Moisture ◽  
Increasing Temperature

SummaryMoisture sorption isotherms of khoa were determined at 15, 25, 35 and 45 °C over a water activity (aw) range of O·l 1–0·97. The isotherms were sigmoid (Type II) and were fitted to the Guggenheim–Anderson–de Boer (GAB) equation (Bizot, 1983). The aw of freshly made khoa was found to be 0·96. The aw of khoa increased with increasing temperature up to 0·9; above this the effect of temperature on aw diminished. The monolayer moisture content of khoa decreased with increasing temperature. The equations describing the temperature dependence of GAB constants were determined in the form of the Clausius–Clapeyron equation. The net isosteric heat of desorption of khoa decreased rapidly until a moisture level of 0·1 g/g solids, and approached a constant value of 0·43 kJ/mol above a moisture level of 0·25 g/g solids.

scholarly journals Sorption isotherms for oat flakes (Avena sativa L.)

2014 ◽  
Vol 32 (1) ◽  
pp. 52-58 ◽  
Author(s):  
José Edgar Zapata M. ◽  
Oscar Albeiro Quintero C. ◽  
Luis Danilo Porras B.
Keyword(s):  
Sorption Isotherms ◽  
Moisture Sorption ◽  
Storage Conditions ◽  
Percentage Error ◽  
Relative Air Humidity ◽  
Moisture Sorption Isotherms ◽  
Relative Percentage Error ◽  
The Mean ◽  
Best Fit

Moisture sorption isotherms of oat flakes were determined at temperatures of 5, 25 and 37°C, using a gravimetric technique in an aw range of between 0.107 and 0.855. These curves were modeled using six equations commonly applied in food. The quality of the fit was assessed with the regression coefficient (r2) and the mean relative percentage error (MRPE). The best fit were obtained with the Caurie model with r2 of 0.996, 0.901 and 0.870, and MRPE of 7.190, 17.878 and 16.206, at 5, 25 and 37°C, respectively. The equilibrium moisture presented a dependence on temperature in the studied aw range, as did the security moisture (XS). These results suggest that the recommended storage conditions of oat flakes include: a relative air humidity of 50% between 5 and 25°C and of 38% up to 37°C.

scholarly journals Moisture sorption isotherms of raw and extruded wholemeal sorghum flours studied by the dynamic and salt slurry methods

2018 ◽  
Vol 21 (0) ◽  
Author(s):  
Melicia Cintia Galdeano ◽  
Renata Valeriano Tonon ◽  
Carlos Wanderlei Piler de Carvalho ◽  
Neuri Santos Menezes ◽  
Regina Isabel Nogueira ◽  
...  
Keyword(s):  
Water Activity ◽  
Dynamic Method ◽  
Sorption Isotherms ◽  
Moisture Sorption ◽  
High Water ◽  
Grain Sorghum ◽  
Equilibration Time ◽  
Whole Grain ◽  
Sorghum Flour ◽  
Slurry Method

Abstract The saturated salt slurry method has been a standard method for many years, but there are several drawbacks, including long equilibration times, extensive labour and mould growth at high water activity (aw) values. The validity of the dynamic method (automated sorption instrument) was investigated by comparing it with the equilibrium isotherms obtained using the saturated salt slurry method for two food materials (whole sorghum raw flour and whole grain sorghum extrudates), as well as their diffusion coefficients. The sorption isotherms ranged between 11.3% and 84.3%. The equilibration time for the highest water activity (0.843) was about 30 days using the saturated salts method, considerably longer than using the dynamic method (300 min). For raw sorghum flour, the dynamic method values were consistent with the data obtained using the traditional method, which can be confirmed by the similar curves and monolayer values obtained (0.038 and 0.040 g water / g solids for the salt slurry and dynamic methods, respectively). For the sorghum extrudates, the equilibrium moisture values were higher using the dynamic method, which could be related to the low diffusion coefficient of the material (order of 10 -10). The authors suggest the use of the dynamic method as a better alternative to the saturated salt method in order to determine the sorption isotherms of whole grain sorghum-based food materials.

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