Convective Condensation of Vapor in Laminar Flow in a Vertical Parallel Plate Channel in the Presence of a High-Concentration Noncondensable Gas

2008 ◽  
Vol 131 (1) ◽  
Author(s):  
V. Dharma Rao ◽  
V. Murali Krishna ◽  
P. K. Sarma ◽  
K. V. Sharma

The problem of laminar film condensation of a vapor from vapor-gas mixture in laminar flow in a vertical parallel plate channel is formulated theoretically. The flowing gas-vapor mixture contains a noncondensable gas in high concentration. An example of this case is the flow of humid air, in which air is present in high concentration. Vapor condenses at the dew point temperature corresponding to mass fraction of vapor in the gas-vapor mixture and the total pressure. The rate of condensation is controlled by the diffusion of the vapor through the noncondensable gas film. Thus the problem of convective condensation is treated as a combined problem of heat and mass transfer. The problem is governed by the mass, momentum and energy balance equations for the vapor-gas mixture flowing in a channel, and the diffusion equation for the vapor species. The flow of the falling film of condensate is governed by the momentum and energy balance equations for the condensate film. The boundary conditions for the gas phase and the condensate film are considered. The temperature at the gas-to-liquid interface is estimated by making use of the equations of heat and mass balance at the interface. The local condensation Nusselt number, condensation Reynolds number, and temperature at the gas-to-liquid interface are estimated from the numerical results for different values of the system parameters at the channel inlet, such as relative humidity, temperature of vapor-gas mixture, gas phase Reynolds number, and total pressure. The condensation heat transfer coefficients computed from the present theory are compared with the experimental data available in literature, and the agreement is found to be good. The present work is an extension of the earlier work, in which the problem of in-duct condensation of humid air in turbulent flow was solved theoretically. Humid air is considered as the gas-vapor mixture, since various physical and thermal properties have to be specified during the analysis.

2007 ◽  
Vol 129 (12) ◽  
pp. 1627-1637 ◽  
Author(s):  
V. Dharma Rao ◽  
V. Murali Krishna ◽  
K. V. Sharma ◽  
P. K. Sarma

The problem of condensation of water vapor from humid air flowing in a duct in turbulent flow is formulated theoretically. Vapor condensing at the dew-point temperature of the vapor-air mixture diffuses to the wall of the duct through an air film. The flow of the condensate is laminar. The condensing vapor releases both convection and latent heats to the wall of the duct. Thus, it is treated as a combined heat and mass transfer problem. The mass, momentum, and energy balance equations for the vapor-air mixture flowing in the duct and the diffusion equation for the vapor species are considered. Ti, the temperature at gas-to-liquid interface, at which condensation takes place, is estimated with the help of the heat balance and mass balance equations at interface. The local and average values of the condensation Nusselt number, condensate Reynolds number, gas-liquid interface temperature, and pressure drop are estimated from the numerical results for different values of the system parameters, such as relative humidity and temperature of air at inlet, gas phase Reynolds number, and total pressure at inlet. The gas phase convection Nusselt and Sherwood numbers are also computed. A comparison of the present work with experimental data, for the case of in-tube condensation of vapor from humid air, shows satisfactory agreement.


Processes ◽  
2021 ◽  
Vol 9 (6) ◽  
pp. 965
Author(s):  
Zoé Perrin ◽  
Nathalie Carrasco ◽  
Audrey Chatain ◽  
Lora Jovanovic ◽  
Ludovic Vettier ◽  
...  

Titan’s haze is strongly suspected to be an HCN-derived polymer, but despite the first in situ measurements by the ESA-Huygens space probe, its chemical composition and formation process remain largely unknown. To investigate this question, we simulated the atmospheric haze formation process, experimentally. We synthesized analogues of Titan’s haze, named Titan tholins, in an irradiated N2–CH4 gas mixture, mimicking Titan’s upper atmosphere chemistry. HCN was monitored in situ in the gas phase simultaneously with the formation and evolution of the haze particles. We show that HCN is produced as long as the particles are absent, and is then progressively consumed when the particles appear and grow. This work highlights HCN as an effective precursor of Titan’s haze and confirms the HCN-derived polymer nature of the haze.


2011 ◽  
Vol 11 (21) ◽  
pp. 11055-11067 ◽  
Author(s):  
K. Salo ◽  
M. Hallquist ◽  
Å. M. Jonsson ◽  
H. Saathoff ◽  
K.-H. Naumann ◽  
...  

Abstract. The aim of this study was to investigate oxidation of SOA formed from ozonolysis of α-pinene and limonene by hydroxyl radicals. This paper focuses on changes of particle volatility, using a Volatility Tandem DMA (VTDMA) set-up, in order to explain and elucidate the mechanism behind atmospheric ageing of the organic aerosol. The experiments were conducted at the AIDA chamber facility of Karlsruhe Institute of Technology (KIT) in Karlsruhe and at the SAPHIR chamber of Forchungzentrum Jülich (FZJ) in Jülich. A fresh SOA was produced from ozonolysis of α-pinene or limonene and then aged by enhanced OH exposure. As an OH radical source in the AIDA-chamber the ozonolysis of tetramethylethylene (TME) was used while in the SAPHIR-chamber the OH was produced by natural light photochemistry. A general feature is that SOA produced from ozonolysis of α-pinene and limonene initially was rather volatile and becomes less volatile with time in the ozonolysis part of the experiment. Inducing OH chemistry or adding a new portion of precursors made the SOA more volatile due to addition of new semi-volatile material to the aged aerosol. The effect of OH chemistry was less pronounced in high concentration and low temperature experiments when lower relative amounts of semi-volatile material were available in the gas phase. Conclusions drawn from the changes in volatility were confirmed by comparison with the measured and modelled chemical composition of the aerosol phase. Three quantified products from the α-pinene oxidation; pinonic acid, pinic acid and methylbutanetricarboxylic acid (MBTCA) were used to probe the processes influencing aerosol volatility. A major conclusion from the work is that the OH induced ageing can be attributed to gas phase oxidation of products produced in the primary SOA formation process and that there was no indication on significant bulk or surface reactions. The presented results, thus, strongly emphasise the importance of gas phase oxidation of semi- or intermediate-volatile organic compounds (SVOC and IVOC) for atmospheric aerosol ageing.


Author(s):  
Dipanka Bhuyan ◽  
Asis Giri ◽  
Pradip Lingfa

Present paper conducts an extensive numerical study on entropy analysis of mixed convective condensation inside a vertical parallel plate channel. A new approach is proposed to separate pump velocity component/Reynolds number from inlet mixed convection velocity. Influence of inlet governing parameters on condensation heat and mass transfer at different inlet pressure, velocity, channel length, and width are widely studied. The central focus of this paper is to study entropy generation under mixed convective condensation. Variation of local as well as overall entropy generation and second law efficiency for different geometric and environmental conditions are presented. For effective condenser design, present study provides two important correlations of overall volumetric entropy generation due to thermal transport and overall volumetric entropy generation due to mass transport.


2017 ◽  
Vol 743 ◽  
pp. 373-377
Author(s):  
Eugenii V. Nikolayev ◽  
Sergey N. Kharlamov ◽  
Laura Meucci

In this paper the features of separation processes modelling are analyzed in hydrocarbonic media within the limits of thermodynamics of equilibrium states. Approaches to calculation of phase equilibrium in multicomponent systems are discussed. Regularities and peculiarities of composition change of gas mixture depending on the temperature and pressure are studied. It has been established that there are specific conditions of non-monotonic change of composition with extremums for some separation regimes that significantly influences the physical properties and intensity of exchange processes at the heat-and mass transfer in multicomponent hydrocarbon media. In addition, the details of the behavior of gas phase with changing its thermal and physical properties have been discussed. Also, the calculated distributions of Prandtl, Schmidt and Lewis-Semenov numbers essentially influencing on the intensity of transport processes are considered.


1974 ◽  
Vol 52 (2) ◽  
pp. 216-220 ◽  
Author(s):  
Donald M. Kulich ◽  
Jay E. Taylor ◽  
David A. Hutchings

The rates of pyrolysis of cyclopropane in nitrogen have been determined using a wall-less reactor at temperatures of 600–740 °C and a total pressure of 1 atm. In the presence of oxidized stainless steel. quartz, or carbon coated steel rods the rate of conversion to propylene is 1.9 times the rate under homogeneous conditions. A maximum in surface effect was observed at S/V = 0.6 cm−1. A small but increased amount of methane and ethene are formed under surface conditions as compared to homogeneous conditions. Several possible mechanisms for the rate enhancement by surface are discussed. The most likely possibility is surface interaction with the cyclopropane molecule to form the diradical followed by its surface promoted conversion to propene. The importance of determining surface effects by comparing surface rates with totally homogeneous rates is emphasized.


1985 ◽  
Vol 30 (1) ◽  
pp. 1-11 ◽  
Author(s):  
Gerardo A. Argüello ◽  
Esther R. de Staricco ◽  
Eduardo H. Staricco

Author(s):  
Xuehu Ma ◽  
Sifang Wang ◽  
Zhong Lan ◽  
Benli Peng ◽  
Tao Bai ◽  
...  

The steam dropwise condensation (DWC) characteristics on superhydrophobic plates were investigated experimentally in the presence of a high concentration noncondensable gas (NCG, >80mol%). The behaviors of condensate droplets on the roughness-induced superhydrophobic surface were observed with a photron high speed camera attached to a microscope. Pulsating features are found during droplets coalescence movement. Bouncing off of coalesced droplet was also observed induced by the strong effect of pulsating motion to overcome the pinning effect of the surface micro-nanostructures. Induced by the pulsating effect of droplets coalescence, the droplet can move at a long distance to join a coalesced droplet.


Sign in / Sign up

Export Citation Format

Share Document