scholarly journals Numerical Investigation of Soot Formation in Turbulent Diffusion Flame With Strong Turbulence–Chemistry Interaction

2015 ◽  
Vol 8 (1) ◽  
Author(s):  
B. Manedhar Reddy ◽  
Ashoke De ◽  
Rakesh Yadav
Keyword(s):  
Mass Fraction ◽  
Volume Fraction ◽  
Soot Formation ◽  
Mixture Fraction ◽  
Soot Volume Fraction ◽  
Turbulent Diffusion Flame ◽  
Flamelet Model ◽  
Soot Mass ◽  
One Step ◽  
Gas Flame

The present work is aimed at examining the ability of different models in predicting soot formation in “Delft flame III,” which is a nonpremixed pilot stabilized natural gas flame. The turbulence–chemistry interactions are modeled using a steady laminar flamelet model (SLFM). One-step and two-step models are used to describe the formation, growth, and oxidation of soot particles. One-step is an empirical model which solves the soot mass fraction equation. The two-step models are semi-empirical models, where the soot formation is modeled by solving the governing transport equations for the soot mass fraction and normalized radical nuclei concentration. The effect of radiative heat transfer due to gas and soot particulates is included using P1 approximation. The absorption coefficient of the mixture is modeled using the weighted sum of gray gases model (WSGGM). The turbulence–chemistry interaction effects on soot formation are studied using a single-variable probability density function (PDF) in terms of a normalized temperature or mixture fraction. The results shown in this work clearly elucidate the effect of radiation and turbulence–chemistry interaction on soot formation. The soot volume fraction decreases with the introduction of radiation interactions, which is consistence with the theoretical predictions. It has also been observed in the current work that the soot volume fraction is sensitive to the variable used in the PDF to incorporate the turbulence interactions.

Analytical Formulation-Based Soot Modelling in Ethylene Laminar Jet Diffusion Flames

2021 ◽  
Author(s):  
Amit Makhija ◽  
Krishna Sesha Giri
Keyword(s):  
Volume Fraction ◽  
Diffusion Flames ◽  
Soot Formation ◽  
Mixture Fraction ◽  
Soot Volume Fraction ◽  
Smoke Point ◽  
Computational Time ◽  
Detailed Model ◽  
Conservation Equations ◽  
Oxidation Rates

Abstract Soot volume fraction predictions through simulations carried out on OpenFOAM® are reported in diffusion flames with ethylene fuel. A single-step global reaction mechanism for gas-phase species with an infinitely fast chemistry assumption is employed. Traditionally soot formation includes inception, nucleation, agglomeration, growth, and oxidation processes, and the individual rates are solved to determine soot levels. However, in the present work, the detailed model is replaced with the soot formation and oxidation rates, defined as analytical functions of mixture fraction and temperature, where the net soot formation rate can be defined as the sum of individual soot formation and oxidation rates. The soot formation/oxidation rates are modelled as surface area-independent processes. The flame is modelled by solving conservation equations for continuity, momentum, total energy, and species mass fractions. Additionally, separate conservation equations are solved to compute the mixture fraction and soot mass fraction consisting of source terms that are identical and account for the mixture fraction consumption/production due to soot. As a consequence, computational time can be reduced drastically. This is a quantitative approach that gives the principal soot formation regions depending on the combination of local mixture fraction and temperature. The implemented model is based on the smoke point height, an empirical method to predict the sooting propensity based on fuel stoichiometry. The model predicts better soot volume fraction in buoyant diffusion flames. It was also observed that the optimal fuel constants to evaluate soot formation rates for different fuels change with fuel stoichiometry. However, soot oxidation strictly occurs in a particular region in the flame; hence, they are independent of fuel. The numerical results are compared with the experimental measurements, showing an excellent agreement for the velocity and temperature. Qualitative agreements are observed for the soot volume fraction predictions. A close agreement was obtained in smoke point prediction for the overventilated flame. An established theory through simulations was also observed, which states that the amount of soot production is proportional to the fuel flow rate. Further validations underscore the predictive capabilities. Model improvements are also reported with better predictions of soot volume fractions through modifications to the model constants based on mixture fraction range.

Prediction of Soot Formation Trends in Turbulent Kerosene-Air Diffusion Jet Flames With Elevated Operating Pressure

2017 ◽  
Author(s):  
Pravin Nakod ◽  
Saurabh Patwardhan ◽  
Ishan Verma ◽  
Stefano Orsino
Keyword(s):  
Environmental Protection Agency ◽  
Volume Fraction ◽  
Soot Formation ◽  
Mixture Fraction ◽  
Soot Volume Fraction ◽  
Operating Pressure ◽  
Jet Flames ◽  
Emission Standard ◽  
Radial Profiles ◽  
Air Diffusion

Emission standard agencies are coming up with more stringent regulations on soot, given its adverse effect on human health. It is expected that Environmental Protection Agency (EPA) will soon place stricter regulations on allowed levels of the size of soot particles from aircraft jet engines. Since, aircraft engines operate at varying operating pressure, temperature and air-fuel ratios, soot fraction changes from condition to condition. Computation Fluid Dynamics (CFD) simulations are playing a key role in understanding the complex mechanism of soot formation and the factors affecting it. In the present work, soot formation prediction from numerical analyses for turbulent kerosene-air diffusion jet flames at five different operating pressures in the range of 1 atm. to 7 atm. is presented. The geometrical and test conditions are obtained from Young’s thesis [1]. Coupled combustion-soot simulations are performed for all the flames using steady diffusion flamelet model for combustion and Mass-Brookes-Hall 2-equation model for soot with a 2D axisymmetric mesh. Combustion-Soot coupling is required to consider the effect of soot-radiation interaction. Simulation results in the form of axial and radial profiles of temperature, mixture fraction and soot volume fraction are compared with the corresponding experimental measured profiles. The results for temperature and mixture fraction compare well with the experimental profiles. Predicted order of magnitude and the profiles of the soot volume fraction also compare well with the experimental results. The correct trend of increasing the peak soot volume fraction with increasing the operating pressure is also captured.

Soot Formation Study in a Rapid Compression Machine

2005 ◽  
Vol 128 (4) ◽  
pp. 942-949 ◽  
Author(s):  
I. Kitsopanidis ◽  
W. K. Cheng
Keyword(s):  
Volume Fraction ◽  
Soot Formation ◽  
Soot Volume Fraction ◽  
Negative Temperature ◽  
Data Interpretation ◽  
Total Carbon ◽  
Rapid Compression Machine ◽  
Soot Mass ◽  
Butane Mixture ◽  
Rapid Compression

A rapid compression machine was used to study the soot formation process under diesel enginelike conditions. The apparatus creates accurately controlled conditions at the end of compression (uniform mixture, temperature, and well-defined mixture composition) and, by decoupling chemistry with mixing, provides an unambiguous data interpretation for kinetics study. The soot evolution was studied by the line-of-sight absorption method (at 632.8nm), which measured the soot volume concentration evolution in the initial stage of soot growth before the optical path became opaque. For a rich butane mixture at fuel equivalence ratio of 3, the ignition delay showed a negative temperature dependence at intermediate temperatures. The soot volume fraction showed an initial exponential growth, with a growth rate depending on the compressed charge fuel concentration. A substantial amount of soot was formed after the soot cloud became opaque. By weighing the total soot particles after the experiment, only ∼10-15% of the soot mass was formed when the beam transmission was reduced to 5%. The final soot mass was ∼15-18% of the total carbon mass for compressed charge density of 250mol∕m3 and temperature from 740to930K.

The Effect of a Mini-Scale Flame-Holder on Nano-Particulate Soot Aerosol Formation and CO/CO2 Emissions From a Jet Fuel Combustion Chamber

2015 ◽  
Author(s):  
Masoud Darbandi ◽  
Majid Ghafourizadeh ◽  
Gerry E. Schneider
Keyword(s):  
Combustion Chamber ◽  
Mass Fraction ◽  
Volume Fraction ◽  
Mixture Fraction ◽  
Radiation Heat Transfer ◽  
Soot Volume Fraction ◽  
Transport Equations ◽  
Flame Holder ◽  
Soot Aerosol ◽  
Mass Fractions

A combustion chamber, burning gaseous kerosene, is simulated to investigate the effects of mini-scale flame-holder geometry and its position on the combustion performance and the resulting nano-particulate soot aerosol, carbon monoxide, and carbon dioxide pollutions. To model the complex process of soot nanoparticle formation including the nucleation, coagulation, surface growth, and oxidation, we use a two-equation soot model to solve the soot mass fraction and soot number density transport equations. Considering a detailed chemical kinetic consisting of 121 species and 2613 elementary reactions, we construct the required flamelets library, i.e. the lookup table, and apply the flamelet combustion model, which solves the transport equations of mixture fraction and its variance. We take into account the turbulence-chemistry interaction using the presumed-shape probability density functions PDFs. Applying the two-equation κ-ε turbulence model with round-jet corrections and suitable wall functions, the transport equations of turbulence kinetic energy and its dissipation rate are solved to close the turbulence closure problem. Since it is required to impose the effects of radiation for the most important radiating species, we include the radiation heat transfer of soot and gases assuming the optically-thin flame consideration. In this regard, the radiation heat transfer is determined locally and only affected by the emissions. We evaluate the achieved solutions through our developed method comparing with the data documented in an experimental test, i.e. a gaseous-kerosene/air turbulent nonpremixed flame. The comparisons are provided for the achieved flame structure, i.e., the experimental data reported on the distributions of mixture fraction, temperature, and soot volume fraction. Next, we consider a disk-type mini-scale flame-holder inside the combustion chamber to study its effects on the flow pattern of reacting flow and the distributions of temperature, soot volume fraction, soot particles diameter, CO, and CO2 mass fractions. Our results show that the mounted flame-holder would increase the inside temperature while reduce the temperature, soot volume fraction, CO, and CO2 mass fractions of the exhaust gases. We also study the geometry and position of mini-scale flame-holder numerically in terms of the average values of temperature, soot volume fraction, soot particles diameter, CO mass fraction, and CO2 mass fraction at the outlet of combustion chamber. Our results indicate that increasing the radius of flame holder would lead to a reduction in carbonaceous emissions, i.e. black carbon, CO, and CO2, and the temperature of exhaust gases. Evidently, a maximum temperature increase inside the combustion chamber would augment the combustion performance. We also show that mounting the flame holder at the lower positions above the fuel nozzle exit would lead to the same consequences. The present study provides good informative advices to the researchers who investigate pollution in aero-engine combustion chambers.

Numerical simulation of soot formation in a turbulent diffusion flame: comparison among three soot formation models

2011 ◽  
Vol 226 (5) ◽  
pp. 1290-1301 ◽  
Author(s):  
R Sarlak ◽  
M Shams ◽  
R Ebrahimi
Keyword(s):  
Diffusion Flame ◽  
Turbulent Diffusion ◽  
Volume Fraction ◽  
Diffusion Flames ◽  
Soot Formation ◽  
Radiation Heat Transfer ◽  
Soot Volume Fraction ◽  
Suitable Model ◽  
Turbulent Diffusion Flame ◽  
Turbulent Diffusion Flames

Combustion and soot formation in a turbulent diffusion flame are simulated. Chemistry of combustion is treated with a detailed reaction mechanism that employs 49 species and 277 reactions. Turbulence is taken into account via the corrected k–ε model. Radiation heat transfer from flame is modelled by the P-1 model. An empirical model proposed by Khan and Greeves and two semi-empirical models proposed by Tesner and Lindstedt are used to simulate the soot formation in the flame. Khan and Greeves model showed to underpredict the maximum soot volume fraction. Nevertheless, the main shortcoming of Khan and Greeves model which undermines the applicability of this model to prediction of soot formation in turbulent diffusion flames is the inability to locate the highly sooting regions of the flame properly. Tesner model underpredicts the soot formation significantly, although the predicted shapes of the soot profiles are in accordance with the experimental measurements. Lindstedt model performs well in predicting both the maximum soot formation and the soot profile shapes in the chamber. Therefore, Lindstedt model can be considered as the most suitable model for the prediction of soot formation in turbulent diffusion flames.

scholarly journals Effect of the Preheated Oxidizer Temperature on Soot Formation and Flame Structure in Turbulent Methane-Air Diffusion Flames at 1 and 3 atm: A CFD Investigation

Energies ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3671
Author(s):  
Subrat Garnayak ◽  
Subhankar Mohapatra ◽  
Sukanta K. Dash ◽  
Bok Jik Lee ◽  
V. Mahendra Reddy
Keyword(s):  
Mole Fraction ◽  
Air Temperature ◽  
Reaction Rate ◽  
Volume Fraction ◽  
Diffusion Flames ◽  
Soot Formation ◽  
Flame Structure ◽  
Soot Volume Fraction ◽  
Computational Domain ◽  
Pressure Elevation

This article presents the results of computations on pilot-based turbulent methane/air co-flow diffusion flames under the influence of the preheated oxidizer temperature ranging from 293 to 723 K at two operating pressures of 1 and 3 atm. The focus is on investigating the soot formation and flame structure under the influence of both the preheated air and combustor pressure. The computations were conducted in a 2D axisymmetric computational domain by solving the Favre averaged governing equation using the finite volume-based CFD code Ansys Fluent 19.2. A steady laminar flamelet model in combination with GRI Mech 3.0 was considered for combustion modeling. A semi-empirical acetylene-based soot model proposed by Brookes and Moss was adopted to predict soot. A careful validation was initially carried out with the measurements by Brookes and Moss at 1 and 3 atm with the temperature of both fuel and air at 290 K before carrying out further simulation using preheated air. The results by the present computation demonstrated that the flame peak temperature increased with air temperature for both 1 and 3 atm, while it reduced with pressure elevation. The OH mole fraction, signifying reaction rate, increased with a rise in the oxidizer temperature at the two operating pressures of 1 and 3 atm. However, a reduced value of OH mole fraction was observed at 3 atm when compared with 1 atm. The soot volume fraction increased with air temperature as well as pressure. The reaction rate by soot surface growth, soot mass-nucleation, and soot-oxidation rate increased with an increase in both air temperature and pressure. Finally, the fuel consumption rate showed a decreasing trend with air temperature and an increasing trend with pressure elevation.

scholarly journals The influence of aliphatics on soot inception modelling

2021 ◽  
Author(s):  
Nemanja Ceranic
Keyword(s):  
Volume Fraction ◽  
Diffusion Flames ◽  
Soot Formation ◽  
Fluid Dynamic ◽  
Soot Volume Fraction ◽  
Surface Reactivity ◽  
Complex Nature ◽  
Laminar Diffusion Flames ◽  
Laminar Diffusion ◽  
Polycyclic Aromatic

Soot models have been investigated for several decades and many fundamental models exist that prescribe soot formation in agreement with experiments and theories. However, due to the complex nature of soot formation, not all pathways have been fully characterized. This work has numerically studied the influence that aliphatic based inception models have on soot formation for coflow laminar diffusion flames. CoFlame is the in-house parallelized FORTRAN code that was used to conduct this research. It solves the combustion fluid dynamic conservation equations for a variety of coflow laminar diffusion flames. New soot inception models have been developed for specific aliphatics in conjunction with polycyclic aromatic hydrocarbon based inception. The purpose of these models was not to be completely fundamental in nature, but more so a proof-of-concept in that an aliphatic based mechanism could account for soot formation deficiencies that exist with just PAH based inception. The aliphatic based inception models show potential to enhance predicative capability by increasing the prediction of the soot volume fraction along the centerline without degrading the prediction along the pathline of maximum soot. Additionally, the surface reactivity that was used to achieve these results lied closer in the range of numerically derived optimal values as compared to the surface reactivity that was needed to match peak soot concentrations without the aliphatic based inception models.

A Numerical Study on the Influence of Hydrogen Addition on Soot Formation in a Laminar Aviation Kerosene (Jet A1) Flame at Elevated Pressure

2021 ◽  
Author(s):  
Mingshan Sun ◽  
Zhiwen Gan
Keyword(s):  
Volume Fraction ◽  
Soot Formation ◽  
Laminar Flame ◽  
Numerical Study ◽  
Soot Volume Fraction ◽  
Elevated Pressure ◽  
Condensation Process ◽  
Hydrogen Addition ◽  
Aviation Kerosene ◽  
Soot Precursor

Abstract The hydrogen addition is a potential way to reduce the soot emission of aviation kerosene. The current study analyzed the effect of hydrogen addition on aviation kerosene (Jet A1) soot formation in a laminar flame at elevated pressure to obtain a fundamental understanding of the reduced soot formation by hydrogen addition. The soot formation of flame was simulated by CoFlame code. The soot formation of kerosene-nitrogen-air, (kerosene + replaced hydrogen addition)-nitrogen-air, (kerosene + direct hydrogen addition)-nitrogen-air and (kerosene + direct nitrogen addition)-nitrogen-air laminar flames were simulated. The calculated pressure includes 1, 2 and 5 atm. The hydrogen addition increases the peak temperature of Jet A1 flame and extends the height of flame. The hydrogen addition suppresses the soot precursor formation of Jet A1 by physical dilution effect and chemical inhibition effect, which weaken the poly-aromatic hydrocarbon (PAH) condensation process and reduce the soot formation. The elevated pressure significantly accelerates the soot precursor formation and increases the soot formation in flame. Meanwhile, the ratio of reduced soot volume fraction to base soot volume fraction by hydrogen addition decreases with the increase of pressure, indicating that the elevated pressure weakens the suppression effect of hydrogen addition on soot formation in Jet A1 flame.

Soot and PAH Formation Characteristics in a Micro Flow Reactor With a Controlled Temperature Profile

2011 ◽  
Author(s):  
Ryu Tanimoto ◽  
Takuya Tezuka ◽  
Susumu Hasegawa ◽  
Hisashi Nakamura ◽  
Kaoru Maruta
Keyword(s):  
Flow Velocity ◽  
Temperature Profile ◽  
Mole Fraction ◽  
Equivalence Ratio ◽  
Flow Reactor ◽  
Volume Fraction ◽  
Soot Formation ◽  
Soot Volume Fraction ◽  
Low Flow ◽  
Micro Flow

To examine soot and PAH formation processes for rich methane/air and acetylene/air mixtures, a micro flow reactor with a controlled temperature profile was employed. In the experiment for a methane/air mixture, four kinds of responses to the variations of flow velocity and equivalence ratio were observed as follows: soot formation without a flame; a flame with soot formation; a flame without soot formation; and neither flame nor soot formation. Soot formations were observed in low flow velocity and high equivalence ratio. Starting point of soot formation shifted to the upstream side, i.e., low-temperature side, of the micro flow reactor with the decrease of flow velocity. One-dimensional steady-state computation was conducted by a flame code. In high flow velocity, low mole fraction of C2H2 and high mole fraction of OH were observed in the whole region of the micro flow reactor. Soot volume fraction did not increase in this case. On the other hand, in low flow velocity, high mole fraction of C2H2 and low mole fraction of OH were observed at the downstream side of the micro flow reactor. Soot volume fraction increased in this case. Since significant soot formation was observed at the low flow velocity and the high equivalence ratio, experiments with gas sampling were conducted for acetylene/air mixture to investigate temperature and equivalence ratio dependence of soot precursor production in such condition. Volume fractions of benzene increased with an increase of temperature. They were larger at higher equivalence ratio at the same temperature. Volume fractions of styrene increased with an increase of temperature. They were larger at higher equivalence ratio when the temperature is less than 1000 K. However the tendency was changed at 1000 K, styrene volume fraction at equivalence ratio of 7.0 was larger than that at equivalence ratio of 8.0.

Fischer-Tropsch Fuel Characterization via Microturbine Testing and Fundamental Combustion Measurements

2008 ◽  
Author(s):  
A. Srinivasan ◽  
B. Ellis ◽  
J. F. Crittenden ◽  
W. E. Lear ◽  
Brandon Rotavera ◽  
...  
Keyword(s):  
Shock Tube ◽  
Volume Fraction ◽  
Soot Formation ◽  
Soot Volume Fraction ◽  
Jet Fuels ◽  
Synthetic Fuels ◽  
Fischer Tropsch ◽  
Ignition Delay Times ◽  
Test Region ◽  
Fuel Characterization

Synthetic fuels such as Fischer-Tropsch (FT) fuels are of interest as a replacement for aviation, diesel, and other petroleum-based fuels, and the present paper outlines a joint program to study the combustion behavior of FT synthetic fuels. To this end, shock-tube spray and high-recirculation combustion rig experiments are being utilized to study the ignition delay times, formation of soot, and emissions of FT jet fuels. Undiluted shock tube spray experiments were conducted using a recently developed heterogeneous technique wherein the fuel is sprayed directly into the test region of a shock tube. The high recirculation combustion rig is a complete gas turbine system where Syntroleum FT jet fuel was combusted, and soot formation and emission characteristics were observed. Reduction of soot volume fraction and unchanged emissions were observed, in agreement with previous investigations. The fundamental shock tube results were found to be consistent with the observations made in the experimental engine.

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