scholarly journals sCO2 Power Cycle Component Cost Correlations From DOE Data Spanning Multiple Scales and Applications

2019 ◽  
Author(s):  
Nathan T. Weiland ◽  
Blake W. Lance ◽  
Sandeep R. Pidaparti
Keyword(s):  
High Temperature ◽  
Natural Gas ◽  
Small Sample ◽  
Heat Sources ◽  
Cost Models ◽  
Cost Estimates ◽  
Power Cycles ◽  
Power Cycle ◽  
Wide Range ◽  
Economic Analyses

Abstract Supercritical CO2 (sCO2) power cycles find potential application with a variety of heat sources including nuclear, concentrated solar (CSP), coal, natural gas, and waste heat sources, and consequently cover a wide range of scales. Most studies to date have focused on the performance of sCO2 power cycles, while economic analyses have been less prevalent, due in large part to the relative scarcity of reliable cost estimates for sCO2 power cycle components. Further, the accuracy of existing sCO2 techno-economic analyses suffer from a small sample set of vendor-based component costs for any given study. Improved accuracy of sCO2 component cost estimation is desired to enable a shift in focus from plant efficiency to economics as a driver for commercialization of sCO2 technology. This study reports on sCO2 component cost scaling relationships that have been developed collaboratively from an aggregate set of vendor quotes, cost estimates, and published literature. As one of the world’s largest supporters of sCO2 research and development, the Department of Energy (DOE) National Laboratories have access to a considerable pool of vendor component costs that span multiple applications specific to each National Laboratory’s mission, including fossil-fueled sCO2 applications at the National Energy Technology Laboratory (NETL), CSP at the National Renewable Energy Laboratory (NREL), and CSP, nuclear, and distributed energy sources at Sandia National Laboratories (SNL). The resulting cost correlations are relevant to sCO2 components in all these applications, and for scales ranging from 5–750 MWe. This work builds upon prior work at SNL, in which sCO2 component cost models were developed for CSP applications ranging from 1–100 MWe in size. Similar to the earlier SNL efforts, vendor confidentiality has been maintained throughout this collaboration and in the published results. Cost models for each component were correlated from 4–24 individual quotes from multiple vendors, although the individual cost data points are proprietary and not shown. Cost models are reported for radial and axial turbines, integrally-geared and barrel-style centrifugal compressors, high temperature and low temperature recuperators, dry sCO2 coolers, and primary heat exchangers for coal and natural gas fuel sources. These models are applicable to sCO2-specific components used in a variety of sCO2 cycle configurations, and include incremental cost factors for advanced, high temperature materials for relevant components. Non-sCO2-specific costs for motors, gearboxes, and generators have been included to allow cycle designers to explore the cost implications of various turbomachinery configurations. Finally, the uncertainty associated with these component cost models is quantified by using AACE International-style class ratings for vendor estimates, combined with component cost correlation statistics.

High Efficiency SOFC Power Cycles With Indirect Natural Gas Reforming and CO2 Capture

2014 ◽  
Author(s):  
Stefano Campanari ◽  
Matteo Gazzani
Keyword(s):  
Fuel Cells ◽  
High Temperature ◽  
Fuel Cell ◽  
Natural Gas ◽  
Co2 Capture ◽  
Heat Exchangers ◽  
High Hydrogen ◽  
Power Cycles ◽  
Power Cycle ◽  
Natural Gas Reforming

Driven by the search for the highest theoretical efficiency, several studies have investigated in the last years the adoption of fuel cells in the field of power production from natural gas with CO2 capture. Most of the proposed power cycles rely on high temperature fuel cells, namely Solid Oxide Fuel Cells (SOFC) and Molten Carbonate Fuel Cells (MCFC), based on the concept of hybrid fuel cell plus gas turbine cycles. Accordingly, high temperature fuel cells are integrated with a simple or modified Brayton cycle. As far as SOFC are concerned, two main plant solutions can be identified depending on the integration with the natural gas reforming/shift section: (i) systems where natural gas is — partially or totally — internally reformed in the fuel cell and (ii) systems where natural gas is reformed before the fuel cell and the cell is fed with a high hydrogen syngas. In both cases, CO2 can be separated downstream the fuel cell via a range of available technologies, e.g. chemical or physical separation processes, oxy-combustion and cryogenic methods. Following a literature review on very promising plant configurations, this work investigates the advantages and limits of adopting an external natural gas conversion section with respect to the plant efficiency. As a reference plant we considered a power cycle proposed by Adams and Barton [8], whose performance is the highest found in literature for SOFC-based power cycles, with 82% LHV electrical efficiency. It is based on a pre-reforming concept where fuel is reformed ahead the SOFC which thus works with a high hydrogen content fuel. This plant was firstly reproduced considering all the ideal assumptions proposed by the original authors. As second step, the simulations were focused on revising the power cycle, implementing a complete set of assumptions about component losses and more conservative operating conditions about fuel cell voltage, heat exchangers minimum temperature differences, maximum steam temperature, turbomachinery efficiency, component pressure losses and other adjustments. Considering the consequent modifications with respect to the original layout, the net electric efficiency changes to around 66% LHV with nearly complete (95%+) CO2 capture, a still remarkable but less attractive value, while requiring a very complex and demanding heat exchangers network. Detailed results are presented in terms of energy and material balances of the proposed cycles. All the simulations have been carried out with the proprietary code GS, developed by the GECOS group at Politecnico di Milano.

High Efficiency SOFC Power Cycles With Indirect Natural Gas Reforming and CO2 Capture

2015 ◽  
Vol 12 (2) ◽  
Author(s):  
Stefano Campanari ◽  
Matteo Gazzani
Keyword(s):  
High Temperature ◽  
Natural Gas ◽  
Gas Turbine ◽  
Co2 Capture ◽  
Heat Exchangers ◽  
High Efficiency ◽  
Power Production ◽  
Operating Conditions ◽  
Power Cycles ◽  
Power Cycle

Driven by the search for the highest theoretical efficiency, several studies have investigated in the last years the adoption of fuel cells (FCs) in the field of power production from natural gas with CO2 capture. Most of the proposed power cycles rely on high temperature FCs, namely, solid oxide FCs (SOFCs) and molten carbonate FCs (MCFCs), based on the concept of hybrid FC plus gas turbine cycles. Accordingly, high temperature FCs are integrated with a simple or modified Brayton cycle. As far as SOFCs are concerned, CO2 can be separated downstream the FC via a range of available technologies, e.g., chemical or physical separation processes, oxy-combustion, and cryogenic methods. Following a literature review on promising plant configurations, this work investigates the potential of adopting an external natural gas conversion section with respect to the plant efficiency. As a reference plant, we considered a power cycle proposed by Adams and Barton (2010, “High-Efficiency Power Production From Natural Gas With Carbon Capture,” J. Power Sources, 195(7), pp. 1971–1983), whose performance is the highest found in literature for SOFC-based power cycles, with 82% LHV electrical efficiency. It is based on a prereforming concept where fuel is reformed ahead the SOFC, which thus works with a high hydrogen content fuel. After reproducing the power cycle with the ideal assumptions proposed by the original authors, as second step, the simulations were focused on revising the power cycle, implementing a complete set of assumptions about component losses and more conservative operating conditions about FC voltage, heat exchangers minimum temperature differences (which were previously neglected), maximum steam temperature (set according to heat recovery steam generator (HRSG) practice), turbomachinery efficiency, component pressure losses, and other adjustments. The simulation also required to design an appropriate heat exchangers network, which turned out to be very complex, instead of relying on the free allocation of heat transfer among all components. Considering the consequent modifications with respect to the original layout, the net electric efficiency changes to around 63% LHV with nearly complete (95%+) CO2 capture, a still remarkable but less attractive value. On the other hand, the power cycle requires a complicated and demanding heat exchangers network and heavily relies on the SOFC performances, not generating a positive power output from the gas turbine loop. Detailed results are presented in terms of energy and material balances of the proposed cycles. All simulations have been carried out with the proprietary code GS, developed by the GECOS group at Politecnico di Milano.

Computation of Thermodynamic Properties of Carbon Dioxide in the Range 0–750 Deg C

1970 ◽  
Vol 92 (3) ◽  
pp. 301-309 ◽  
Author(s):  
G. Angelino ◽  
E. Macchi
Keyword(s):  
Carbon Dioxide ◽  
Thermal Properties ◽  
High Temperature ◽  
Thermodynamic Properties ◽  
Thermodynamic Functions ◽  
Critical Region ◽  
Density Measurement ◽  
Working Fluid ◽  
Power Cycles ◽  
Wide Range

The computation of power cycles employing carbon dioxide as working fluid and extending down to the critical region requires the knowledge of the thermodynamic properties of CO2 within a wide range of pressures and temperatures. Available data are recognized to be insufficient or insufficiently accurate chiefly in the vicinity of the critical dome. Newly published density and specific heat measurements are employed to compute thermodynamic functions at temperatures between 0 and 50 deg C, where the need of better data is more urgent. Methods for the computation of thermal properties from density measurement in the low and in the high temperature range are presented and discussed. Results are reported of the computation of entropy and enthalpy of CO2 in the range 150–750 deg C and 40–600 atm. The probable precision of the tables is inferred from an error analysis based on the generation, by means of a computer program of a set of pseudoexperimental points which, treated as actual measurements, yield useful information about the accuracy of the calculation procedure.

scholarly journals Prediction of Auto-Ignition Temperatures and Delays for Gas Turbine Applications

2015 ◽  
Vol 138 (2) ◽  
Author(s):  
Roda Bounaceur ◽  
Pierre-Alexandre Glaude ◽  
Baptiste Sirjean ◽  
René Fournet ◽  
Pierre Montagne ◽  
...  
Keyword(s):  
High Temperature ◽  
Natural Gas ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Equivalence Ratio ◽  
Process Conditions ◽  
Piping System ◽  
Gaseous Fuels ◽  
Auto Ignition ◽  
Wide Range

Gas turbines burn a large variety of gaseous fuels under elevated pressure and temperature conditions. During transient operations, variable gas/air mixtures are involved in the gas piping system. In order to predict the risk of auto-ignition events and ensure a safe operation of gas turbines, it is of the essence to know the lowest temperature at which spontaneous ignition of fuels may happen. Experimental auto-ignition data of hydrocarbon–air mixtures at elevated pressures are scarce and often not applicable in specific industrial conditions. Auto-ignition temperature (AIT) data correspond to temperature ranges in which fuels display an incipient reactivity, with timescales amounting in seconds or even in minutes instead of milliseconds in flames. In these conditions, the critical reactions are most often different from the ones governing the reactivity in a flame or in high temperature ignition. Some of the critical paths for AIT are similar to those encountered in slow oxidation. Therefore, the main available kinetic models that have been developed for fast combustion are unfortunately unable to represent properly these low temperature processes. A numerical approach addressing the influence of process conditions on the minimum AIT of different fuel/air mixtures has been developed. Several chemical models available in the literature have been tested, in order to identify the most robust ones. Based on previous works of our group, a model has been developed, which offers a fair reconciliation between experimental and calculated AIT data through a wide range of fuel compositions. This model has been validated against experimental auto-ignition delay times corresponding to high temperature in order to ensure its relevance not only for AIT aspects but also for the reactivity of gaseous fuels over the wide range of gas turbine operation conditions. In addition, the AITs of methane, of pure light alkanes, and of various blends representative of several natural gas and process-derived fuels were extensively covered. In particular, among alternative gas turbine fuels, hydrogen-rich gases are called to play an increasing part in the future so that their ignition characteristics have been addressed with particular care. Natural gas enriched with hydrogen, and different syngas fuels have been studied. AIT values have been evaluated in function of the equivalence ratio and pressure. All the results obtained have been fitted by means of a practical mathematical expression. The overall study leads to a simple correlation of AIT versus equivalence ratio/pressure.

High-Power Multi-Stage Rankine Cycles

1995 ◽  
Vol 117 (3) ◽  
pp. 192-196 ◽  
Author(s):  
O. M. Ibrahim ◽  
S. A. Klein
Keyword(s):  
Power Output ◽  
Waste Heat ◽  
Thermodynamic Cycle ◽  
Rankine Cycle ◽  
Maximum Power ◽  
Heat Sources ◽  
Power Cycles ◽  
Power Cycle ◽  
Multi Stage ◽  
Limit Power

This paper presents an analysis of the multi-stage Rankine cycle aiming at optimizing the power output from low-temperature heat sources such as geothermal or waste heat. A design methodology based on finite-time thermodynamics and the maximum power concept is used in which the shape and the power output of the maximum power cycle are identified and utilized to compare and evaluate different Rankine cycle configurations. The maximum power cycle provides the upper-limit power obtained from any thermodynamic cycle for specified boundary conditions and heat exchanger characteristics. It also provides a useful tool for studying power cycles and forms the basis for making design improvements.

Cost Estimates of Cellulosic Ethanol Manufacturing: A Literature Review

2011 ◽  
Author(s):  
P. F. Zhang ◽  
Z. J. Pei
Keyword(s):  
Cellulosic Ethanol ◽  
Cost Model ◽  
Cellulosic Biomass ◽  
Data Sources ◽  
Manufacturing Costs ◽  
Cost Estimates ◽  
Transportation Fuels ◽  
Wide Range ◽  
Economic Analyses ◽  
Cost Components

Cellulosic ethanol is one type of renewable energy, and can be used to replace petroleum based transportation fuels. The technologies of converting cellulosic biomass into ethanol are relatively mature. However, the manufacturing costs of cellulosic ethanol are too high to be competitive. Economic analyses of cellulosic ethanol manufacturing have appeared regularly to estimate manufacturing costs of cellulosic ethanol. But the estimated manufacturing costs of cellulosic ethanol have a wide range due to differences in used assumptions. It is very difficult to judge which one is most reliable among the markedly different cost estimates in the literature. This paper reviews the literature on cost estimates in manufacturing of cellulosic ethanol. Cost estimates of each manufacturing process are summarized. Cost components and their data sources are discussed. This review provides a foundation to develop a comprehensive cost model for cellulosic ethanol manufacturing.

Experimental Characterization of the Combustion in Fuel Flexible Humid Power Cycles

2021 ◽  
Author(s):  
Simeon Dybe ◽  
Felix Güthe ◽  
Michael Bartlett ◽  
Panagiotis Stathopoulos ◽  
Christian Oliver Paschereit
Keyword(s):  
Natural Gas ◽  
Equivalence Ratio ◽  
High Efficiency ◽  
Full Potential ◽  
Nox Emissions ◽  
Nox Formation ◽  
Fuel Blend ◽  
Power Cycles ◽  
Wide Range ◽  
Renewable Electricity Generation

Abstract Modified humid power cycles provide the necessary boundary condition for combustion to operate on a wide fuel spectrum in a steam-rich atmosphere comprising hydrogen and syngas from gasification besides natural gas as fuels. Thus, these cycles with their high efficiency and flexibility fit in a carbon-free energy market dominated by renewable electricity generation, providing dispatchable heat and electric power. To realize their full potential, the combustor utilized in such power cycles must fulfill the emission limits as well as demands of stable combustion over a wide range of fuel and steam ratios. The operation is limited by the risk of lean blowout for highly diluted syngas with low reactivity, and flashback for highly reactive hydrogen. Further, the gasification product gas can contain unwanted pollutants such as tars and nitrogen containing species like ammonia (NH3). Tars carry a considerable portion of the feedstock’s energy but are associated with detrimental operational behavior. The presence of ammonia in the combustion increases the risk of high NOx-emission at already small ammonia concentrations in the fuel. In this work, humid hydrogen flames are analyzed for their stability and emissions. Stable hydrogen flames were produced over a wide equivalence ratio and steam ratio range at negligible NOx-emissions. Further, natural gas, and a fuel blend substituting bio-syngas, was doped with ammonia. The combustion is analyzed with a focus on emissions and flame position and stability. The addition of ammonia causes high NOx-formation from fuel bound nitrogen (FBN), which highly increases NOx-emissions. The latter decrease with increasing NH3 content and increasing equivalence ratio.

scholarly journals Supercritical Carbon Dioxide(s-CO2) Power Cycle for Waste Heat Recovery: A Review from Thermodynamic Perspective

Processes ◽  
2020 ◽  
Vol 8 (11) ◽  
pp. 1461
Author(s):  
Liuchen Liu ◽  
Qiguo Yang ◽  
Guomin Cui
Keyword(s):  
High Temperature ◽  
Supercritical Co2 ◽  
Heat Recovery ◽  
Waste Heat Recovery ◽  
Waste Heat ◽  
Combustion Engine ◽  
Power Cycles ◽  
Power Cycle ◽  
Thermodynamic Cycles ◽  
Cogeneration System

Supercritical CO2 power cycles have been deeply investigated in recent years. However, their potential in waste heat recovery is still largely unexplored. This paper presents a critical review of engineering background, technical challenges, and current advances of the s-CO2 cycle for waste heat recovery. Firstly, common barriers for the further promotion of waste heat recovery technology are discussed. Afterwards, the technical advantages of the s-CO2 cycle in solving the abovementioned problems are outlined by comparing several state-of-the-art thermodynamic cycles. On this basis, current research results in this field are reviewed for three main applications, namely the fuel cell, internal combustion engine, and gas turbine. For low temperature applications, the transcritical CO2 cycles can compete with other existing technologies, while supercritical CO2 cycles are more attractive for medium- and high temperature sources to replace steam Rankine cycles. Moreover, simple and regenerative configurations are more suitable for transcritical cycles, whereas various complex configurations have advantages for medium- and high temperature heat sources to form cogeneration system. Finally, from the viewpoints of in-depth research and engineering applications, several future development directions are put forward. This review hopes to promote the development of s-CO2 cycles for waste heat recovery.

scholarly journals Prediction of Auto-Ignition Temperatures and Delays for Gas Turbine Applications

2015 ◽  
Author(s):  
Roda Bounaceur ◽  
Pierre-Alexandre Glaude ◽  
Baptiste Sirjean ◽  
René Fournet ◽  
Pierre Montagne ◽  
...  
Keyword(s):  
High Temperature ◽  
Natural Gas ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Equivalence Ratio ◽  
Large Temperature ◽  
Individual Species ◽  
Gaseous Fuels ◽  
Auto Ignition ◽  
Wide Range

Gas turbines burn a large variety of gaseous fuels under elevated pressure and temperature conditions. During transient operations like maintenance, start-ups or fuel transfers, variable gas/air mixtures are involved in the gas piping system. Therefore, in order to predict the risk of auto-ignition events and ensure a safe and optimal operation of gas turbines, it is of the essence to know the lowest temperature at which spontaneous ignition of fuels may happen. Experimental auto-ignition data of hydrocarbon-air mixtures at elevated pressures are scarce and often not applicable in specific industrial conditions. AIT data correspond to temperature ranges in which fuels display an incipient reactivity, with time scales amounting in seconds or even in minutes instead of milliseconds in flames. In these conditions, the critical reactions are most often different from the ones governing the reactivity in a flame or in high temperature ignition. Some of the critical paths for AIT, especially those involving peroxy radicals, are similar to those encountered in slow oxidation. Therefore, the main available kinetic models that have been developed for fast combustion, are unfortunately unable to represent properly these low temperature processes. In this context, a numerical approach addressing the influence of process conditions on the minimum auto-ignition temperature of different fuel/air mixtures has been developed. For that purpose, several chemical models available in the literature have been tested, in order to identify the most robust ones. Based on previous works of our group, a model covering a large temperature range has been developed, which offers a fair reconciliation between experimental and calculated AIT data through a wide range of fuel compositions. This model has been validated against experimental auto-ignition delay times (AID) corresponding to high temperature in order to ensure its relevance not only for AIT aspects but also for the reactivity of gaseous fuels over the wide range of gas turbine operation conditions. In addition, the AITs of methane, of pure light alkanes and of various blends representative of several natural gas and process-derived fuels were extensively covered. In particular, among alternative gas turbine fuels, hydrogen-rich gases are called to play an increasing part in the future so that their ignition characteristics have been addressed with particular care. Natural gas enriched with hydrogen, and different CO/H2 syngas fuels originating from a blast furnace (BFG) have namely been studied. Globally, the individual species covered are: H2, CO, CO2, N2, CH4, C2H6, C3H8, C4H10, and C5H12. AIT values have been evaluated in function of the equivalence ratio and pressure. All the results obtained have been fitted by means of a practical mathematical expression. The overall study leads to a simple correlation of AIT versus equivalence ratio/pressure that may be of fruitful use for the engineering community.

Application of TEM to Deformation, Wear, and Fracture of Ceramics

1974 ◽  
Vol 32 ◽  
pp. 472-473
Author(s):  
B. J. Hockey
Keyword(s):  
Wear Resistance ◽  
High Temperature ◽  
Mechanical Behavior ◽  
Brittle Materials ◽  
High Temperature Strength ◽  
Wide Range ◽  
Corrosive Environments ◽  
Further Development

Ceramics, such as Al2O3 and SiC have numerous current and potential uses in applications where high temperature strength, hardness, and wear resistance are required often in corrosive environments. These materials are, however, highly anisotropic and brittle, so that their mechanical behavior is often unpredictable. The further development of these materials will require a better understanding of the basic mechanisms controlling deformation, wear, and fracture.The purpose of this talk is to describe applications of TEM to the study of the deformation, wear, and fracture of Al2O3. Similar studies are currently being conducted on SiC and the techniques involved should be applicable to a wide range of hard, brittle materials.

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