Torque Transient of Magnetically Driven Flow for Viscosity Measurement

Volume 1 ◽  
2004 ◽  
Author(s):  
Heng Ban ◽  
Bochuan Lin ◽  
Chao Li ◽  
Rosalia N. Scripa ◽  
Ching-Hua Su ◽  
...  

Viscosity is a good indicator of structural changes for complex liquids, such as semiconductor melts with chain or ring structures. This paper discusses the theoretical and experimental results of the transient torque technique for non-intrusive viscosity measurement. Such a technique is essential for the high temperature viscosity measurement of high pressure and toxic semiconductor melts. In this paper, our previous work on oscillating cup technique was expanded to the transient process of a magnetically driven melt flow in a damped oscillation system. Based on the analytical solution for the fluid flow and cup oscillation, a semi-empirical model was established to extract the fluid viscosity. The analytical and experimental results indicated that such a technique has the advantage of short measurement time and straight forward data analysis procedures.

Gels ◽  
2021 ◽  
Vol 7 (1) ◽  
pp. 20
Author(s):  
Matan Mussel ◽  
Peter J. Basser ◽  
Ferenc Horkay

Incremental changes in ionic composition, solvent quality, and temperature can lead to reversible and abrupt structural changes in many synthetic and biopolymer systems. In the biological milieu, this nonlinear response is believed to play an important functional role in various biological systems, including DNA condensation, cell secretion, water flow in xylem of plants, cell resting potential, and formation of membraneless organelles. While these systems are markedly different from one another, a physicochemical framework that treats them as polyelectrolytes, provides a means to interpret experimental results and make in silico predictions. This article summarizes experimental results made on ion-induced volume phase transition in a polyelectrolyte model gel (sodium polyacrylate) and observations on the above-mentioned biological systems indicating the existence of a steep response.


2002 ◽  
Vol 24 (3) ◽  
pp. 296-305
Author(s):  
T. B. Ferrari ◽  
S. H. Hara ◽  
J. L. Aziani ◽  
L. Rocha ◽  
E. de Paula ◽  
...  

In this work we analyze an undergraduate experiment used to determine the thermal conductivity of metals (K). We introduce few modifications in order to offer the student the chance to explore dierent models, learning the basic scientiffic method of developing appropriate and improved explanations for each experiment in order to better link theory and empirical results. Semi-empirical corrections are introduced in the system in order to check the experimental results according to previously reported K values. As specific cases we use copper [K = 0.92 cal /(°C s cm)], aluminum [K = 0.49 cal /(°C s cm)] and brass [K = 0.26 cal /(°C s cm)] cylinders.


2020 ◽  
Vol 142 (11) ◽  
Author(s):  
Xiaodong Han ◽  
Liguo Zhong ◽  
Yigang Liu ◽  
Tao Fang ◽  
Cunliang Chen

Abstract Fine migration is always considered as one of the major mechanisms that are responsible for formation damage. The unwanted reduction of reservoir permeability would result in the decline of water injection and consequent oil production, especially for the unconsolidated sandstone reservoir. For better understanding, the mechanisms of formation damage in pore-scale, a new three-dimensional pore-scale network model (PNM) is proposed and developed to simulate formation damage caused by particle detachment, migration, and capture in pore throats based on force analysis. Experiments are also conducted on the formation damage characteristics of an unconsolidated core. Both X-ray diffraction and scanning electron microscope (SEM) are applied to understand the microscopic reservoir properties. The experimental results show that the studied core has a strong flowrate sensitivity. A comparison between experimental results and PNM simulation results is conducted. The simulated results agree well with the experimental data, which approves the efficiency and accuracy of the PNM. Sensitivity analysis results show that larger particle sizes, higher flowrate, higher fluid viscosity, and lower ion concentration of the fluids would contribute to the formation damage, which could provide guidance for the development of unconsolidated sandstone reservoirs with strong sensitivity.


Author(s):  
Victorita Radulescu

Abstract The thermal pollution, with major effects on the water quality degradation by any process involving the temperature transfer, represents nowadays a major concern for the entire scientific world. The turbulent heat and the mass transfer have an essential role in the processes of thermal pollution, mainly in problems associated with the transport of hot fluids in long heating pipes, thermal flows associated with big thermo-electric power plants, etc. In the last decades, the problems of the turbulent heat and mass transfer were analyzed for different dedicated applications. The present paper, in the first part, estimates the universal law of the velocity distribution near a solid wall, with a specific interpretation of the fluid viscosity, valid for all types of flows. Most of the scientific researches associate nowadays both the turbulent heat and the mass transfer with the Prandtl number. In the turbulent fluid flow near a solid and rigid surface, there are three flowing domains, laminar, transient, and fully turbulent, each one with its characteristics. In this paper, it is assumed that the friction effort at the wall remains valid at any distance from the wall, but with different forms associated with the dynamic viscosity. By using the superposition of the molecular and turbulent viscosity and by creating the interdependence between the molecular and turbulent transfer coefficients is estimated the mathematical model of the velocity profile for the fluid flow and temperature distribution. Three supplementary hypotheses have been assumed to estimate the dependence between the laminar and thermal sub-layer and the hydrodynamic sub-layer. The theoretical obtained distribution was compared with some experimental results from the literature and it was observed there is a good agreement between them; the differences are smaller than 3%. In the second part of the paper is determined the temperature field for a fluid flowing also in presence of the solid surfaces with different temperatures, associated not only with the Prandtl number but also with the fluid viscosity and its dependence with the temperature, correlated with the Grashoff number. In the next paragraph is used the concept of the laminar substrate with different thicknesses for the hydrodynamic flows with thermal transfer to the solid walls, and also the inverse transfer from the solid walls affecting the fluid flow and the mass transfer. The obtained mathematical model is correlated with the semi-empirical data from the literature. By numerical modeling, the obtained results were compared with the experimental measurements and it was determined the dependence between the Stanton number and the Prandtl number. The numerical results demonstrate a good agreement with the experimental results in a wide range of the Prandtl numbers from 0.5 to 3000. Finally, are mentioned some conclusions and references.


1992 ◽  
Vol 47 (9) ◽  
pp. 971-973 ◽  
Author(s):  
A. Kawski ◽  
P. Bojarski ◽  
A. Kubicki

Abstract The influence of the moment of inertia on the rotational fluorescence depolarization is discussed. Based on experimental results obtained for five luminescent compounds: 2,5-diphenyloxazole (PPO), 2,2'-p-phenylene-bis(5-phenyloxazole) (POPOP), p-bis[2-(5-α-naphthyloxazolyl)]-benzene (α-NOPON), 4-dimethylamino-ω-methylsulphonyl-trans-styrene (3a) in n-parafines at low viscosity (from 0.22 x 10-3 Pa • s to 0.993 x 10-3 Pa • s) and diphenylenestilbene (DPS) in different solvents, a semi-empirical equation is proposed, yielding moments of inertia that are only two to five times higher than those estimated from the molecular geometry


2014 ◽  
Vol 6 ◽  
pp. 532797 ◽  
Author(s):  
Zhentao Wang ◽  
Qingming Dong ◽  
Yonghui Zhang ◽  
Junfeng Wang ◽  
Jianlong Wen

A model based on the volume of fluid (VOF) method and leaky dielectric theory is established to predict the deformation and internal flow of the droplet suspended in another vicious fluid under the influence of the electric field. Through coupling with hydrodynamics and electrostatics, the rate of deformation and internal flow of the single droplet are simulated and obtained under the different operating parameters. The calculated results show that the direction of deformation and internal flow depends on the physical properties of fluids. The numerical results are compared with Taylor's theory and experimental results by Torza et al. When the rate of deformation is small, the numerical results are consistent with theory and experimental results, and when the rate is large the numerical results are consistent with experimental results but are different from Taylor's theory. In addition, fluid viscosity hardly affects the deformation rate and mainly dominates the deformation velocity. For high viscosity droplet spends more time to attain the steady state. The conductivity ratio and permittivity ratio of two different liquids affect the direction of deformation. When fluid electric properties change, the charge distribution at the interface is various, which leads to the droplet different deformation shapes.


2015 ◽  
Vol 11 ◽  
pp. 1441-1446 ◽  
Author(s):  
Armando Navarro-Vázquez

The base-catalyzed isomerization of N-propargylamides or carbamates may furnish N-allenyl compounds (allenamides/allencarbamates) or further evolve to N-alkynyl compounds (ynamides or yncarbamates). The particular fate of this reaction varies from experiment to experiment and there is no clear rule for predicting the reaction outcome for a particular structure. With the support of ab initio and DFT computations, this work shows that observed results can be explained by assuming an exchange equilibrium between energetically close N-propargyl, allenyl and N-alkynyl forms and that the reaction outcome correlates to a particular equilibrium mixture. Due to the very small energy gap between the N-allenyl and N-alkynyl forms, small structural changes may easily alter the equilibrium position, explaining the variety of observed experimental results. Based on CBS-QB3 computations, the ωB97 functional provided reasonably accurate isomerization energies and could successfully predict the experimentally observed behavior for several examples from the literature.


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