Formulation of Sasol IPK Surrogate Fuel for Diesel Engine Application Using an Ignition Quality Tester (IQT)

2016 ◽  
Author(s):  
Ziliang Zheng ◽  
Tamer Badawy ◽  
Naeim Henein ◽  
Peter Schihl ◽  
Eric Sattler
Keyword(s):  
Diesel Engine ◽  
Ignition Delay ◽  
Cetane Number ◽  
Combustion Gas ◽  
Surrogate Fuels ◽  
Aspen Hysys ◽  
Ignition Quality ◽  
Apparent Activation Energies ◽  
Surrogate Fuel ◽  
Ignition Quality Tester

This paper presents an approach to develop Sasol IPK (Iso-Paraffinic Kerosene) surrogate fuels for diesel engine application using Ignition Quality Tester (IQT). The methodology includes: 1) in-house developed MATLAB code to formulate the appropriate mixture blends, 2) Aspen HYSYS to develop the distillation curve and compares it to the target Sasol IPK fuel, 3) IQT to measure the derived cetane number (DCN) of surrogate fuels and compare it with the target Sasol IPK fuel, 4) analysis of autoignition and combustion characteristics for Sasol IPK surrogate fuels. The ignition delay, combustion gas pressure, and rate of heat release of Sasol IPK and its formulated surrogate fuel are analyzed and compared at five different charge temperatures. Furthermore, the apparent activation energies derived from chemical ignition delay of the surrogate fuel and Sasol IPK are determined and compared.

Formulation of Sasol Isomerized Paraffinic Kerosene Surrogate Fuel for Diesel Engine Application Using an Ignition Quality Tester

2017 ◽  
Vol 139 (9) ◽  
Author(s):  
Ziliang Zheng ◽  
Tamer Badawy ◽  
Naeim Henein ◽  
Peter Schihl ◽  
Eric Sattler
Keyword(s):  
Diesel Engine ◽  
Ignition Delay ◽  
Alternative Fuels ◽  
Internal Combustion Engines ◽  
Cetane Number ◽  
Surrogate Fuels ◽  
Cycle Simulation ◽  
Ignition Quality ◽  
Surrogate Fuel ◽  
Ignition Quality Tester

Sasol isomerized paraffinic kerosene (IPK) is a coal-derived synthetic fuel under consideration as a blending stock with jet propellant 8 (JP-8) for use in military equipment. However, Sasol IPK is a low ignition quality fuel with derived cetane number (DCN) of 31. The proper use of such alternative fuels in internal combustion engines (ICEs) requires the modification in control strategies to operate engines efficiently. With computational cycle simulation coupled with surrogate fuel mechanism, the engine development process is proved to be very effective. Therefore, a methodology to formulate Sasol IPK surrogate fuels for diesel engine application using ignition quality tester (IQT) is developed. An in-house developed matlab code is used to formulate the appropriate mixture blends, also known as surrogate fuel. And aspen hysys is used to emulate the distillation curve of the surrogate fuels. The properties of the surrogate fuels are compared to those of the target Sasol IPK fuel. The DCNs of surrogate fuels are measured in the IQT and compared with the target Sasol IPK fuel at the standard condition. Furthermore, the ignition delay, combustion gas pressure, and rate of heat release (RHR) of Sasol IPK and its formulated surrogate fuels are analyzed and compared at five different charge temperatures. In addition, the apparent activation energies derived from chemical ignition delay of the surrogate fuel and Sasol IPK are determined and compared.

scholarly journals Relationship between Fuel Properties and Cetane Response of Cetane Improver for Non-Aromatic and Aromatic Fuels Used In A Single Cylinder Heavy Duty Diesel Engine

2019 ◽  
Vol 2 (1) ◽  
Keyword(s):  
Sensitivity Analysis ◽  
Diesel Engine ◽  
Ignition Delay ◽  
Cetane Number ◽  
Fuel Properties ◽  
Heavy Duty ◽  
Heavy Duty Diesel Engine ◽  
Ignition Quality ◽  
Main Factors ◽  
Heavy Duty Diesel

Ignition improver additives are used to improve the ignition quality, or reduce the ignition delay; i.e. the time between when fuel is injected and time when combustion start is different this difference in time is minimize by additive is called cetane improver (CN). The Cetane Number (CN) is the most widely accepted measure of ignition quality to get desired value of centane number some additive are used hence ignition improvers are usually characterized by the fact that at what extent they can increase CN. By increasing cetane number we have two benefits that it helps smoother combustion and lower emissions. Fuel properties are always considered as one of the main factors to diesel engines concerning performance of cetane improver. There are still challenges for researchers to identify the most correlating and non-correlating fuel properties and their effects on cetane improver .In this study to derive the most un-correlating and correlating properties. In parallel, sensitivity analysis was performed for the fuel properties as well as to effect on performance of cetane improver

Experimental Validation of a 3-Component Surrogate for Sasol-IPK in Single Cylinder Diesel Engine and IQT

2017 ◽  
Author(s):  
Samy A. Alkhayat ◽  
Manan J. Trivedi ◽  
Naeim A. Henein ◽  
Sampad Mukhopadhyay ◽  
Peter Schihl
Keyword(s):  
Diesel Engine ◽  
Ignition Delay ◽  
Experimental Validation ◽  
Peak Pressure ◽  
Single Cylinder ◽  
Pressure Peak ◽  
Ignition Quality ◽  
Surrogate Fuel ◽  
Three Components

The goal of this investigation is to compare the validation of Sasol-IPK and its surrogate fuel in the IQT and in an actual diesel engine. The surrogate fuel is composed of three components (46% iso-cetane, 44% decalin and 10% n-nonane on a volume basis). IQT experiments were conducted as per ASTM D6890-10a. Engine experiments were conducted at 1500 RPM, two engine loads, and two injection timings. Analysis of the ignition delay, peak pressure, peak RHR and other combustion phasing parameters, showed a closer match in IQT than in the diesel engine. This investigation suggests that validation in a single cylinder diesel engine should be a part of the surrogate validation, particularly for low ignition quality fuels.

An Investigation on Sensitivity of Ignition Delay and Activation Energy in Diesel Combustion

2015 ◽  
Vol 137 (9) ◽  
Author(s):  
Umashankar Joshi ◽  
Ziliang Zheng ◽  
Amit Shrestha ◽  
Naeim Henein ◽  
Eric Sattler
Keyword(s):  
Activation Energy ◽  
Ignition Delay ◽  
Cetane Number ◽  
Ignition Process ◽  
Start Of Injection ◽  
Auto Ignition ◽  
Time Period ◽  
Ignition Quality ◽  
Ignition Quality Tester ◽  
Start Of Combustion

The auto-ignition process plays a major role in the combustion, performance, fuel economy, and emission in diesel engines. The auto-ignition quality of different fuels has been rated by its cetane number (CN) determined in the cooperative fuel research engine, according to ASTM D613. More recently, the ignition quality tester (IQT), a constant volume vessel, has been used to determine the derived cetane number (DCN) to avoid the elaborate, time consuming, and costly engine tests, according to ASTM D6890. The ignition delay (ID) period in these two standard tests and many investigations has been considered to be the time period between start of injection (SOI) and start of combustion (SOC). The ID values determined in different investigations can vary due to differences in instrumentation and definitions. This paper examines the different definitions and the parameters that effect ID period. In addition, the activation energy dependence on the ID definition is investigated. Furthermore, results of an experimental investigation in a single-cylinder research diesel engine will be presented, while the charge density is kept constant during the ID period. The global activation energy is determined and its sensitivity to the charge temperature is examined.

Experimental Validation of a Three-Component Surrogate for Sasol-Isoparaffinic Kerosene in Single Cylinder Diesel Engine and Ignition Quality Tester

2018 ◽  
Vol 140 (8) ◽  
Author(s):  
Samy Alkhayat ◽  
Manan Trivedi ◽  
Naeim Henein ◽  
Sampad Mukhopadhyay ◽  
Peter Schihl
Keyword(s):  
Diesel Engine ◽  
Experimental Validation ◽  
Cetane Number ◽  
Negative Temperature ◽  
Single Cylinder ◽  
Combustion Behavior ◽  
Auto Ignition ◽  
Temperature Combustion ◽  
Ignition Quality ◽  
Ignition Quality Tester

Surrogates development is important to extensively investigate the combustion behavior of fuels. Development of comprehensive surrogates has been focusing on matching chemical and physical properties of their target fuel to mimic its atomization, evaporation, mixing, and auto-ignition behavior. More focus has been given to matching the derived cetane number (DCN) as a measure of the auto-ignition quality. In this investigation, we carried out experimental validation of a three-component surrogate for Sasol-Isoparaffinic Kerosene (IPK) in ignition quality tester (IQT) and in an actual diesel engine. The surrogate fuel is composed of three components (46% iso-cetane, 44% decalin, and 10% n-nonane on a volume basis). The IQT experiments were conducted as per ASTM D6890-10a. The engine experiments were conducted at 1500 rpm, two engine loads, and two injection timings. Analysis of ignition delay (ID), peak pressure, peak rate of heat release (RHR), and other combustion phasing parameters showed a closer match in the IQT than in the diesel engine. Comparison between the surrogate combustion behavior in the diesel engine and IQT revealed that matching the DCN of the surrogate to its respective target fuel did not result in the same negative temperature coefficient (NTC) profile—which led to unmatched combustion characteristics in the high temperature combustion (HTC) regimes, despite the same auto-ignition and low temperature combustion (LTC) profiles. Moreover, a comparison between the combustion behaviors of the two fuels in the IQT is not consistent with the comparison in the diesel engine, which suggests that the surrogate validation in a single-cylinder diesel engine should be part of the surrogate development methodology, particularly for low ignition quality fuels.

An Investigation on Sensitivity of Ignition Delay and Activation Energy in Diesel Combustion

2014 ◽  
Author(s):  
Umashankar Joshi ◽  
Ziliang Zheng ◽  
Amit Shrestha ◽  
Naeim Henein ◽  
Eric Sattler
Keyword(s):  
Activation Energy ◽  
Ignition Delay ◽  
Cetane Number ◽  
Ignition Process ◽  
Start Of Injection ◽  
Auto Ignition ◽  
Time Period ◽  
Ignition Quality ◽  
Ignition Quality Tester ◽  
Start Of Combustion

The auto-ignition process plays a major role in the combustion, performance, fuel economy and emission in diesel engines. The auto-ignition quality of different fuels has been rated by its cetane number (CN) determined in the CFR engine, according to ASTM D613. More recently, the Ignition Quality Tester (IQT), a constant volume vessel, has been used to determine the derived cetane number (DCN) to avoid the elaborate, time consuming and costly engine tests, according to ASTM D6890. The ignition delay period in these two standard tests and many investigations has been considered to be the time period between start of injection (SOI) and start of combustion (SOC). The ignition delay (ID) values determined in different investigations can vary due to differences in instrumentation and definitions. This paper examines the different definitions and the parameters that effect ID period. In addition the activation energy dependence on the ID definition is investigated. Furthermore, results of an experimental investigation in a single-cylinder research diesel engine will be presented while the charge density is kept constant during the ID period. The global activation energy is determined and its sensitivity to the charge temperature is examined.

scholarly journals Rational Design and Testing of Anti-Knock Additives

Energies ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 4923
Author(s):  
Andrew D. Ure ◽  
Manik K. Ghosh ◽  
Maria Rappo ◽  
Roland Dauphin ◽  
Stephen Dooley
Keyword(s):  
Rational Design ◽  
Reaction Pathway ◽  
Cetane Number ◽  
Research Octane Number ◽  
Ignition Quality ◽  
Ignition Quality Tester ◽  
Generic Design ◽  
The Relationship ◽  
Design And Testing

An innovative and informed methodology for the rational design and testing of anti-knock additives is reported. Interaction of the additives with OH● and HO2● is identified as the key reaction pathway by which non-metallic anti-knock additives are proposed to operate. Based on this mechanism, a set of generic design criteria for anti-knock additives is outlined. It is suggested that these additives should contain a weak X-H bond and form stable radical species after hydrogen atom abstraction. A set of molecular structural, thermodynamic, and kinetic quantities that pertain to the propensity of the additive to inhibit knock by this mechanism are identified and determined for a set of 12 phenolic model compounds. The series of structural analogues was carefully selected such that the physical thermodynamic and kinetic quantities could be systematically varied. The efficacy of these molecules as anti-knock additives was demonstrated through the determination of the research octane number (RON) and the derived cetane number(DCN), measured using an ignition quality tester (IQT), of a RON 95 gasoline treated with 1 mole % of the additive. The use of the IQT allows the anti-knock properties of potential additives to be studied on one tenth of the scale, compared to the analogous RON measurement. Using multiple linear regression, the relationship between DCN/RON and the theoretically determined quantities is studied. The overall methodology reported is proposed as an informed alternative to the non-directed experimental screening approach typically adopted in the development of fuel additives.

A Proposed Biodiesel Combustion Kinetics Based on the Computational Fluid Dynamics Results in an Ignition Quality Tester

2019 ◽  
Vol 141 (8) ◽  
Author(s):  
Mahmoud Elhalwagy ◽  
Chao Zhang
Keyword(s):  
Methyl Ester ◽  
Ignition Delay ◽  
Methyl Esters ◽  
Direct Injection ◽  
Combustion Process ◽  
Major Fatty Acid ◽  
Combustion Behavior ◽  
Ignition Quality ◽  
Reaction Constants ◽  
Ignition Quality Tester

In this paper, five biodiesel global combustion decomposition steps are added to a surrogate mechanism to accurately represent the chemical kinetics of the decomposition of different levels of saturation of biodiesel, which are represented by five major fatty acid methyl esters. The reaction constants were tuned based on the results from the numerical simulations of the combustion process in an ignition quality tester (IQT) in order to obtain accurate cetane numbers. The prediction of the complete thermophysical properties of the five constituents is also carried out to accurately represent the physics of the spray and vaporization processes. The results indicated that the combustion behavior is controlled more by the spray and breakup processes for saturated biodiesel constituents than by the chemical delay, which is similar to the diesel fuel combustion behavior. The chemical delay and low temperature reactions were observed to have greater effects on the combustion and ignition delay for the cases of the unsaturated biodiesels. The comparison between the physical ignition delay and overall ignition delay between the saturated and unsaturated biodiesel constituents has also confirmed those stronger effects for the physical delay in the saturated compounds as compared to the unsaturated compounds. The validation of the proposed model is conducted for the simulations of two direct injection diesel engines using palm methyl ester and rape methyl ester.

Effect of Cetane Improver on Combustion and Emission Characteristics of Coal-Derived Sasol Isomerized Paraffinic Kerosene in a Single Cylinder Diesel Engine

2015 ◽  
Vol 137 (7) ◽  
Author(s):  
Ziliang Zheng ◽  
Umashankar Joshi ◽  
Naeim Henein ◽  
Eric Sattler
Keyword(s):  
Diesel Engine ◽  
Cetane Number ◽  
Control Unit ◽  
Injection System ◽  
Oxides Of Nitrogen ◽  
Single Cylinder ◽  
Common Rail Injection System ◽  
Air Temperatures ◽  
Auto Ignition ◽  
Ignition Quality

Sasol isomerized paraffinic kerosene (IPK) is a coal-derived synthetic fuel under consideration as a blending stock with JP-8 for use in military ground vehicles. Since Sasol IPK is a low ignition quality fuel with derived cetane number (DCN) of 31, there is a need to improve its ignition quality. This paper investigates the effect of adding different amounts of Lubrizol 8090 cetane improver to Sasol IPK on increasing its DCN. The experimental investigation was conducted in a single cylinder research type diesel engine. The engine is equipped with a common rail injection system and an open engine control unit. Experiments covered different injection pressures and intake air temperatures. Analysis of test results was made to determine the effect of cetane improver percentage in the coal-derived Sasol IPK blend on auto-ignition, combustion and emissions of carbon monoxide (CO), total unburned hydrocarbon (HC), oxides of nitrogen (NOx), and particulate matter (PM). In addition, the effect of cetane improver on the apparent activation energy of the global auto-ignition reactions was determined.

Improving Vegetable Oil Fueled CI Engine Characteristics Through Diethyl Ether Blending

2016 ◽  
Author(s):  
S. Vedharaj ◽  
R. Vallinayagam ◽  
S. Mani Sarathy ◽  
Robert W. Dibble
Keyword(s):  
Vegetable Oil ◽  
Diethyl Ether ◽  
Cetane Number ◽  
Gaseous Emissions ◽  
Engine Operation ◽  
Lower Viscosity ◽  
Ignition Quality ◽  
Ci Engine ◽  
Ignition Characteristics ◽  
Ignition Quality Tester

In this research, the flow and ignition properties of vegetable oil (VO) are improved by blending it with diethyl ether (DEE). DEE, synthesized from ethanol, has lower viscosity than diesel and VO. When DEE is blended with VO, the resultant DEEVO mixtures have favorable properties for compression ignition (CI) engine operation. As such, DEEVO20 (20% DEE + 80% VO) and DEEVO40 (40% DEE + 60% VO) were initially considered in the current study. The viscosity of VO is 32.4*10−6 m2/s; the viscosity is reduced with the increase of DEE in VO. In this study, our blends were limited to a maximum of 40% DEE in VO. The viscosity of DEEVO40 is 2.1*10−6 m2/s, which is comparable to that of diesel (2.3*10−6 m2/s). The lower boiling point and flash point of DEE improves the fuel spray and evaporation for DEEVO mixtures. In addition to the improvement in physical properties, the ignition quality of DEEVO mixtures is also improved, as DEE is a high cetane fuel (DCN = 139). The ignition characteristics of DEEVO mixtures were studied in an ignition quality tester (IQT). There is an evident reduction in ignition delay time (IDT) for DEEVO mixtures compared to VO. The IDT of VO (4.5 ms), DEEVO20 (3.2 ms) and DEEVO40 (2.7 ms) was measured in IQT. Accordingly, the derived cetane number (DCN) of DEEVO mixtures increased with the increase in proportion of DEE. The reported mixtures were also tested in a single cylinder CI engine. The start of combustion (SOC) was advanced for DEEVO20 and DEEVO40 compared to diesel, which is attributed to the high DCN of DEEVO mixtures. On the other hand, the peak heat release rate decreased for DEEVO mixtures compared to diesel. Gaseous emissions such as nitrogen oxide (NOX), total hydrocarbon (THC) and smoke were reduced for DEEVO mixtures compared to diesel. The physical and ignition properties of VO are improved by the addition of DEE, and thus, the need for the trans-esterification process is averted. Furthermore, this blending strategy is simpler and enables operation of straight run oils and fats in CI engine, replacing diesel completely.

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