Applicability of Iron Phosphate Glass Medium for Loading NaCl Originated From Seawater Used for Cooling the Stricken Power Reactors

2013 ◽  
Author(s):  
Hidekazu Kobayashi ◽  
Ippei Amamoto ◽  
Takuma Yokozawa ◽  
Teruo Yamashita ◽  
Takayuki Nagai ◽  
...  
Keyword(s):  
Thermal Expansion ◽  
Glass Transition ◽  
Phosphate Glass ◽  
Glass Formation ◽  
Coefficient Of Thermal Expansion ◽  
Glass Melting ◽  
Glass Network ◽  
Iron Phosphate ◽  
Chemical Durability ◽  
Raw Material

As the part of investigation for immobilization of the sludge as one of the radioactive wastes arising from the treatment of contaminated water at Fukushima Dai-ichi nuclear power plant, applicability of vitrification method has been evaluated as a candidate technique. The aim of this study is to evaluate the influence of NaCl as one of the main constituents of sludge, on glass formation and glass properties. Two kinds of iron phosphate glass (IPG) media in the xFe2O3-(100-x)P2O5, with x = 30 and 35 (mol%) were chosen and the glass formation, structure and properties including density, coefficient of thermal expansion, glass transition temperature, onset crystallization temperature and chemical durability of NaCl-loaded IPG were studied. The results are summarized as follows. Sodium chloride, NaCl could be loaded into IPG medium as Na2O and Cl contents and their loading ratio could be up to 19 and 15 mol%, respectively. Majority of Cl content of raw material NaCl was thought to be volatilized during glass melting. Loading NaCl into IPG induces to depolymerize glass network of phosphate chains, leads to decrease both glass transition and onset crystallization temperatures, and to increase coefficient of thermal expansion. NaCl-loaded IPG indicated good chemical durability in case of using 35Fe2O3-65P2O5 medium.

Study on the Addition of SiO2 into Lithium-Iron-Phosphate Glass

2011 ◽  
Vol 306-307 ◽  
pp. 1623-1626 ◽  
Author(s):  
Rui Juan Yang ◽  
Ying Hui Wang ◽  
Hua Li Liu ◽  
Shi Quan Liu
Keyword(s):  
Activation Energy ◽  
Phosphate Glass ◽  
Crystalline Phase ◽  
Lithium Iron Phosphate ◽  
Glass Network ◽  
Iron Phosphate ◽  
Chemical Durability ◽  
Surface Crystallization ◽  
Glass Melts ◽  
Cast Sample

Different amounts of SiO2 were used to substitute P2O5 to prepare lithium-iron-phosphate glass melts. It was found that glass can only formed after annealing the melt cast sample if the sample contains SiO2 not more than 5 mol%. The addition of 5 mol% SiO2 into the lithium-iron-phosphate glass strengthens the phosphate glass network. The density, chemical durability, both the transition and crystallization temperatures increase with the addition of SiO2. In addition, the addition of SiO2 results in the decrease in the activation energy of lithium-iron-phosphate glass, making the glass easier to crystallize. However, both the lithium-iron-phosphate glass and the glass with SiO2 show surface crystallization with LiFeP2O7 as the crystalline phase.

scholarly journals Thermal properties of Na2O–P2O5–Fe2O3 polyphosphate glasses

2020 ◽  
Vol 142 (1) ◽  
pp. 203-209 ◽  
Author(s):  
Paweł Goj ◽  
Małgorzata Ciecińska ◽  
Magdalena Szumera ◽  
Paweł Stoch
Keyword(s):  
Thermal Properties ◽  
Phosphate Glass ◽  
Transformation Temperature ◽  
Glass Network ◽  
Iron Phosphate ◽  
Phosphate Glasses ◽  
Continuous Change ◽  
Glass Transformation ◽  
Immobilization Techniques ◽  
Iron Phosphate Glasses

Abstract Iron phosphate glasses are materials that can have many applications like durable matrixes in waste immobilization techniques, biomaterials, optoelectronic devices, etc. Their possible usage is related to their glass network and thermal properties. The influence of Na2O content on thermal properties and crystallization ability of iron phosphate glass of base composition 30 Fe2O3–70 P2O5 mol% were studied. Increasing the content of Na2O causes a decrease in transformation temperature and increase in ΔCp. Characteristic temperatures, thermal stability and crystallizing phases were determined. Increasing content of sodium causes depolarization of iron phosphate glass network which causes a continuous change in ΔCp and glass transformation temperature. Discontinuous change in some glass properties suggests structure rebuilding about 30 mol% of Na2O.

Highly transparent polyhydroxyimide/TiO2 and ZrO2 hybrid films with high glass transition temperature (Tg) and low coefficient of thermal expansion (CTE) for optoelectronic application

2017 ◽  
Vol 5 (33) ◽  
pp. 8444-8453 ◽  
Author(s):  
Shun-Wen Cheng ◽  
Tzu-Tien Huang ◽  
Chia-Liang Tsai ◽  
Guey-Sheng Liou
Keyword(s):  
Thermal Expansion ◽  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Thermal Expansion Coefficient ◽  
Coefficient Of Thermal Expansion ◽  
High Glass Transition Temperature ◽  
Hybrid Films ◽  
Optoelectronic Application ◽  
Low Thermal Expansion

Highly transparent polyhydroxyimide/TiO2 and ZrO2 hybrids films with high glass transition temperature and low thermal expansion coefficient for optoelectronic application.

Rheological and Thermomechanical Properties of Meso and Non-Porous Silica Filled Epoxy Composites

2015 ◽  
Vol 815 ◽  
pp. 67-71
Author(s):  
Gang Li ◽  
Peng Li Zhu ◽  
Tao Zhao ◽  
Rong Sun ◽  
Daniel Lu
Keyword(s):  
Mechanical Properties ◽  
Thermal Expansion ◽  
Glass Transition ◽  
Mesoporous Silica ◽  
Coefficient Of Thermal Expansion ◽  
Porous Silica ◽  
Thermomechanical Properties ◽  
Epoxy Composites ◽  
Silica Microspheres ◽  
Silica Filler

In the present study, epoxy based composite filled with meso and non-porous silica microspheres with similar size were prepared respectively and their rheological and thermo-mechanical properties were studied systematically. The results showed that the mesoporous silica/epoxy composites showed much higher viscosity, storage modulus and glass transition temperature (Tg) while lower coefficient of thermal expansion (CTE) than did epoxy composites with nonporous silica particles, which could be attributed to the stronger interface interaction between the mesoporous silica filler with larger specific surface area (BET) and the epoxy matrix.

IMPROVEMENT OF MECHANICAL AND THERMAL PROPERTIES OF CFRP LAMINATES USING MICRO-FIBRILLATED CELLULOSE

2012 ◽  
Vol 06 ◽  
pp. 622-627 ◽  
Author(s):  
HYOJIN KIM ◽  
TADASHI SUZUKI ◽  
KENICHI TAKEMURA
Keyword(s):  
Thermal Expansion ◽  
Glass Transition ◽  
Thermal Properties ◽  
Carbon Fiber ◽  
Coefficient Of Thermal Expansion ◽  
Flexural Modulus ◽  
Mechanical And Thermal Properties ◽  
Flexural Test ◽  
Cfrp Laminates ◽  
Carbon Fiber Epoxy

The aim of this study is improvement of mechanical and thermal properties of plain woven carbon fiber (CF) reinforced epoxy with addition of MFC as the additive. Carbon fiber/epoxy laminates with addition 0.3, 0.5, 0.7 and 1wt% of MFC were characterized by flexural test, DSC and TMA. The result represented that the flexural strength improved slightly at 0.3 and 0.5 wt% of MFC, but flexural modulus was not changed, respectively. The glass transition temperature of MFC-CFRP laminates showed the increase according to increase of MFC addition at 0.7 and 1.0 wt%. The coefficient of thermal expansion was decrease by 0.7 wt% of MFC addition.

scholarly journals Iron phosphate glass waste forms for vitrifying Hanford AZ102 low activity waste (LAW), part I: Glass formation model

2017 ◽  
Vol 458 ◽  
pp. 149-156 ◽  
Author(s):  
Chandra S. Ray ◽  
V.A. Samaranayake ◽  
Ali Mohammadkhah ◽  
Thomas E. Day ◽  
Delbert E. Day
Keyword(s):  
Phosphate Glass ◽  
Glass Formation ◽  
Iron Phosphate ◽  
Formation Model ◽  
Glass Waste ◽  
Waste Forms ◽  
Low Activity

Thermal Expansion and Glass Transition Behaviour of Thin Polymer Films with and without a Free Surface Via Neutron Reflectometry

1998 ◽  
Vol 543 ◽  
Author(s):  
D. J. Pochan ◽  
E. K. Lin ◽  
S. Satija ◽  
S. Z. D. Cheng ◽  
Wen-Li Wu
Keyword(s):  
Thermal Expansion ◽  
Glass Transition ◽  
Free Surface ◽  
Film Thickness ◽  
Coefficient Of Thermal Expansion ◽  
Neutron Reflectometry ◽  
Bilayer Films ◽  
Fluorinated Polyimide ◽  
Expansion Behavior ◽  
Before And After

AbstractThe thermal expansion of thin deuterated polystyrene (dPS) films supported on energetically repulsive, fluorinated polyimide (PI) substrates (PI/dPS bilayer) was measured via neutron reflectometry as a function of initial dPS film thickness. Film thickness was measured before and after capping with a top layer of the same repulsive, high glass transition polyimide that comprised the substrate layer (PI/dPS/PI trilayer) in an attempt to observe any effects of the dPS free surface in the bilayer geometry. Bulk thermal expansion behavior, characterized by a discontinuous change in coefficient of thermal expansion (CTE) at the glass transition (Tg), is observed in films with thickness > 70 rim. For thicknesses between 70 nm and 40 nm a transition is seen from bulk behavior in bilayer films to glassy thermal behavior in the trilayer films persisting up to 20 °C above the bulk Tg. In films with thickness < 40 nm the bulk glassy CTE persists well above the bulk Tg for both bilayer and trilayer films

Research on chemical durability of iron phosphate glass wasteforms vitrifying SrF2 and CeF3

2018 ◽  
Vol 508 ◽  
pp. 286-291 ◽  
Author(s):  
Xueyang Liu ◽  
Yanbo Qiao ◽  
Zhenghua Qian ◽  
Hongjun Ma
Keyword(s):  
Phosphate Glass ◽  
Iron Phosphate ◽  
Chemical Durability

scholarly journals Spectroscopic and Surface Crystallization Characterizations of Yttrium-Doped Phosphate Glasses

Crystals ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 109
Author(s):  
Haijian Li ◽  
Hao Zou ◽  
Zhihua Sun ◽  
Yi Xu ◽  
Changjian Wang ◽  
...  
Keyword(s):  
Phosphate Glass ◽  
Glass Melting ◽  
Glass Ceramics ◽  
Glass Network ◽  
Melting Process ◽  
Spectroscopic Characterization ◽  
Phosphate Glasses ◽  
Thermal Behaviors ◽  
Composition Structure

The composition, structure, and thermal behaviors of yttrium-containing phosphate glasses were studied in this work, and the glass-ceramics were prepared via the two-step crystallization method. The XRD and SEM-EDS results show the forming range of the phosphate glass system and the formation of YPO4 (xenotime) due to the addition of excessive Y2O3. The spectroscopic characterization of these glasses presented shifts of the infrared and Raman bands, demonstrating the depolymerization of the glass network and the formation of novel P–O–Y bonds, and the deconvoluted Raman spectra also exhibited the occurrence of the disproportionation reaction in the glass melting process. The content of non-bridging oxygen (NBOs) from the UV–vis spectra first increased and then decreased with increasing Y2O3. The thermal behaviors show that the Y2O3 reduced the crystallization peak temperature and the thermal stability of the glasses. The crystalline behaviors of the phosphate glass matrix were investigated at different crystallization times of 2–10 h, and a transformation of the crystallization mechanism from surface to volume crystallization was found. The yttrium phosphate glass-ceramics crystallized for 10 h exhibited transformation of the main crystalline phases with increasing Y2O3, and the grain-oriented crystalline surface became irregular.

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