scholarly journals Facile diamond synthesis from lower diamondoids

2020 ◽  
Vol 6 (8) ◽  
pp. eaay9405 ◽  
Author(s):  
Sulgiye Park ◽  
Iwnetim I. Abate ◽  
Jin Liu ◽  
Chenxu Wang ◽  
Jeremy E. P. Dahl ◽  
...  
Keyword(s):  
Diamond Synthesis ◽  
Saturated Hydrocarbons ◽  
High Pressure High Temperature ◽  
Onset Timing ◽  
Hydro Carbon ◽  
Chemical Factors ◽  
Dynamics Simulations ◽  
Bulk Diamond ◽  
Carbon Based Nanomaterials ◽  
Physical And Chemical

Carbon-based nanomaterials have exceptional properties that make them attractive for a variety of technological applications. Here, we report on the use of diamondoids (diamond-like, saturated hydrocarbons) as promising precursors for laser-induced high-pressure, high-temperature diamond synthesis. The lowest pressure and temperature (P-T) conditions that yielded diamond were 12 GPa (at ~2000 K) and 900 K (at ~20 GPa), respectively. This represents a substantially reduced transformation barrier compared with diamond synthesis from conventional (hydro)carbon allotropes, owing to the similarities in the structure and full sp3 hybridization of diamondoids and bulk diamond. At 20 GPa, diamondoid-to-diamond conversion occurs rapidly within <19 μs. Molecular dynamics simulations indicate that once dehydrogenated, the remaining diamondoid carbon cages reconstruct themselves into diamond-like structures at high P-T. This study is the first successful mapping of the P-T conditions and onset timing of the diamondoid-to-diamond conversion and elucidates the physical and chemical factors that facilitate diamond synthesis.

scholarly journals Sweet taste of heavy water

2021 ◽  
Vol 4 (1) ◽  
Author(s):  
Natalie Ben Abu ◽  
Philip E. Mason ◽  
Hadar Klein ◽  
Nitzan Dubovski ◽  
Yaron Ben Shoshan-Galeczki ◽  
...  
Keyword(s):  
Heavy Water ◽  
Calcium Release ◽  
Homology Modelling ◽  
Taste Receptor ◽  
Chemical Properties ◽  
Sweet Taste ◽  
Minor Effect ◽  
Dynamics Simulations ◽  
A Minor ◽  
Physical And Chemical

AbstractHydrogen to deuterium isotopic substitution has only a minor effect on physical and chemical properties of water and, as such, is not supposed to influence its neutral taste. Here we conclusively demonstrate that humans are, nevertheless, able to distinguish D2O from H2O by taste. Indeed, highly purified heavy water has a distinctly sweeter taste than same-purity normal water and can add to perceived sweetness of sweeteners. In contrast, mice do not prefer D2O over H2O, indicating that they are not likely to perceive heavy water as sweet. HEK 293T cells transfected with the TAS1R2/TAS1R3 heterodimer and chimeric G-proteins are activated by D2O but not by H2O. Lactisole, which is a known sweetness inhibitor acting via the TAS1R3 monomer of the TAS1R2/TAS1R3, suppresses the sweetness of D2O in human sensory tests, as well as the calcium release elicited by D2O in sweet taste receptor-expressing cells. The present multifaceted experimental study, complemented by homology modelling and molecular dynamics simulations, resolves a long-standing controversy about the taste of heavy water, shows that its sweet taste is mediated by the human TAS1R2/TAS1R3 taste receptor, and opens way to future studies of the detailed mechanism of action.

Method to reduce the oil pressure during HPHT diamond synthesis: FEM simulations and experiments

CrystEngComm ◽  
2020 ◽  
Vol 22 (44) ◽  
pp. 7601-7606
Author(s):  
Chunxiao Wang ◽  
Hong-an Ma ◽  
Liangchao Chen ◽  
Xinyuan Miao ◽  
Liang Zhao ◽  
...  
Keyword(s):  
High Pressure ◽  
High Temperature ◽  
Cell Assembly ◽  
Diamond Synthesis ◽  
Fem Simulations ◽  
High Pressure High Temperature ◽  
New Type

Here, a new type of supercharged cell assembly is proposed that can effectively reduce the oil pressure during high-pressure, high-temperature (HPHT) diamond synthesis.

Further Studies upon Chemical Factors Affecting the Breeding of Anopheles in Trinidad

1934 ◽  
Vol 25 (4) ◽  
pp. 491-494 ◽  
Author(s):  
P. A. Buxton
Keyword(s):  
Analytical Study ◽  
Chemical Constituents ◽  
Physical Factors ◽  
Factors Affecting ◽  
Early Stages ◽  
Freshwater Biology ◽  
Chemical Technique ◽  
Chemical Factors ◽  
Physical And Chemical

During the last decade, entomologists have made progress in understanding the environment in which certain insects live; in particular, we begin to understand the effect of certain physical and chemical factors, which make up a part of the environment. With this gain in knowledge, it is sometimes possible to forecast outbreaks of insects and of diseases conveyed by them, and one can sometimes say that a particular alteration of the environment will result in loss or gain. But so far as mosquitos are concerned, one must admit that though much work has been devoted to the analytical study of the water in which the early stages are passed, the results are disappointing. A consideration of the published work suggests several reasons for this. Investigation into the ecology of the mosquito has had a vogue, and much of it has been done by workers who were isolated and whose knowledge of chemical technique and freshwater biology was limited. Apart from that, the inherent difficulties are great, for the worker must hunt for the limiting chemical and physical factors among a host of others which are doubtless unimportant, and there are few clues to indicate which of the chemical constituents of the water affects the mosquito. The data are therefore voluminous and it is difficult to reduce them to order and present them so that they can be readily understood.

Menadione nicotinamide bisulphite as a source of vitamin K and niacin activities for the growing pig

2000 ◽  
Vol 71 (1) ◽  
pp. 111-117 ◽  
Author(s):  
M. Marchetti ◽  
M. Tassinari ◽  
S. Marchetti
Keyword(s):  
Vitamin K ◽  
Control Diet ◽  
Live Weight ◽  
Organic Salt ◽  
Free Form ◽  
Food Supplementation ◽  
Sodium Bisulphite ◽  
Chemical Factors ◽  
And Control ◽  
Physical And Chemical

AbstractWhen compared with other menadione derivatives such as menadione sodium bisulphite (MSB), menadione nicotinamide bisulphite (MNB), an organic salt combining menadione and nicotinamide, shows better stability towards physical and chemical factors once it is added to pre-mixes or foods. The present work evaluates the bioavailability of the two vitamins present in this compound and toxicity in the pig. To assess vitamin bioavailability, pigs were given small amounts of food containing MNB or equivalent amounts of MSB and nicotinamide in the free form. Menadione and nicotinamide concentrations in blood samples drawn at set times after the diets were given did not reveal any significant differences between the two modes of administration. Haematic levels of both vitamins in animals receiving MNB, or MSB and nicotinamide, were after 2, 4, 8 and 12 h higher (P < 0·001) than those of untreated animals. The tolerance level to MNB was evaluated in pigs given diets containing graded amounts of MNB (100, 500, 2500 mg/kg) for 28 days. No significant (P > 0·05) differences were recorded in live weight, food intake and gain/food ratio in pigs given these diets when compared with those given an unsupplemented diet. Haemoglobin and bilirubin levels did not differ between animals given various amounts of MNB and control animals. Plasma aspartate aminotransferase (AST) and alanine aminotransferase (ALT) activities in pigs given 100 mg/kg of MNB did not show significant differences when compared with those observed in pigs given an unsupplemented control diet. In pigs on the diets supplemented with 500 and 2500 mg/kg of MNB there was a significant increase in the two enzymatic activities as compared with controls (P < 0·001 and P < 0·01). In the case of ALT this had disappeared by 28 weeks. MNB is a good source of vitamin K for the pig and does not appear to have any adverse effects, even when administered at levels higher than those normally used in pig food supplementation.

The Qualitative and Quantitative Distribution of Plankton in the Strait of Georgia in Relation to Certain Oceanographic Factors

1957 ◽  
Vol 14 (4) ◽  
pp. 521-552 ◽  
Author(s):  
Joseph Eugène Henri Légaré
Keyword(s):  
Salinity Gradient ◽  
General Distribution ◽  
Fraser River ◽  
Strait Of Georgia ◽  
Quantitative Distribution ◽  
Qualitative And Quantitative ◽  
Chemical Factors ◽  
Physical And Chemical ◽  
Plankton Communities ◽  
Made In

In order to gain some picture of the seasonal variations in the plankton communities two cruises were made in the Strait of Georgia, one in June 1955, and the other in November 1955; 165 plankton collections were taken, also surface temperatures.The correlation of these data have resulted in a number of conclusions concerning the distribution of plankton in the Strait of Georgia. The chief factor affecting the general distribution of plankton is the salinity gradient. The inflow of fresh water from the Fraser River forms zones of varying properties, and leads to the development of different plankton communities. The extent to which physical and chemical factors may determine the presence or absence of certain organisms from the zones described is discussed.

Sign in / Sign up

Export Citation Format

Share Document