Background component of methane concentration in surface air (Obninsk monitoring station)

2016 ◽  
Vol 52 (1) ◽  
pp. 37-44 ◽  
Author(s):  
V. N. Aref’ev ◽  
R. M. Akimenko ◽  
F. V. Kashin ◽  
L. B. Upenek
2016 ◽  
Vol 52 (3) ◽  
pp. 247-252 ◽  
Author(s):  
F. V. Kashin ◽  
V. N. Aref’ev ◽  
N. I. Sizov ◽  
R. M. Akimenko ◽  
L. B. Upenek

Materials ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 426
Author(s):  
Byeong-Kwan Song ◽  
Hwan-Young Kim ◽  
Kun-Su Kim ◽  
Jeong-Woo Yang ◽  
Nong-Moon Hwang

Although the growth rate of diamond increased with increasing methane concentration at the filament temperature of 2100 °C during a hot filament chemical vapor deposition (HFCVD), it decreased with increasing methane concentration from 1% CH4 –99% H2 to 3% CH4 –97% H2 at 1900 °C. We investigated this unusual dependence of the growth rate on the methane concentration, which might give insight into the growth mechanism of a diamond. One possibility would be that the high methane concentration increases the non-diamond phase, which is then etched faster by atomic hydrogen, resulting in a decrease in the growth rate with increasing methane concentration. At 3% CH4 –97% H2, the graphite was coated on the hot filament both at 1900 °C and 2100 °C. The graphite coating on the filament decreased the number of electrons emitted from the hot filament. The electron emission at 3% CH4 –97% H2 was 13 times less than that at 1% CH4 –99% H2 at the filament temperature of 1900 °C. The lower number of electrons at 3% CH4 –97% H2 was attributed to the formation of the non-diamond phase, which etched faster than diamond, resulting in a lower growth rate.


Energies ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 128
Author(s):  
Justyna Swolkień ◽  
Nikodem Szlązak

Several natural threats characterize hard coal mining in Poland. The coexistence of methane and rock-burst hazards lowers the safety level during exploration. The most dangerous are high-energy bumps, which might cause rock-burst. Additionally, created during exploitation, safety pillars, which protect openings, might be the reason for the formation of so-called gas traps. In this part, rock mass is usually not disturbed and methane in seams that form the safety pillars is not dangerous as long as they remain intact. Nevertheless, during a rock-burst, a sudden methane outflow can occur. Preventing the existing hazards increases mining costs, and employing inadequate measures threatens the employees’ lives and limbs. Using two longwalls as examples, the authors discuss the consequences of the two natural hazards’ coexistence. In the area of longwall H-4 in seam 409/4, a rock-burst caused a release of approximately 545,000 cubic meters of methane into the excavations, which tripled methane concentration compared to the values from the period preceding the burst. In the second longwall (IV in seam 703/1), a bump was followed by a rock-burst, which reduced the amount of air flowing through the excavation by 30 percent compared to the airflow before, and methane release rose by 60 percent. The analyses presented in this article justify that research is needed to create and implement innovative methods of methane drainage from coal seams to capture methane more effectively at the stage of mining.


Coatings ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 888
Author(s):  
Pengfei Zhang ◽  
Weidong Chen ◽  
Longhui Zhang ◽  
Shi He ◽  
Hongxing Wang ◽  
...  

In this paper, we successfully synthesized homoepitaxial diamond with high quality and atomically flat surface by microwave plasma chemical vapor deposition. The sample presents a growth rate of 3 μm/h, the lowest RMS of 0.573 nm, and the narrowest XRD FWHM of 31.32 arcsec. An effect analysis was also applied to discuss the influence of methane concentration on the diamond substrates.


2020 ◽  
Author(s):  
Favis Joseph C. Balinado ◽  
Gerald Paolo Dar Santos ◽  
Engr. Rio A. Escanilla ◽  
Alejandro Danilo Banaag ◽  
Andreana Amor M. Gulay ◽  
...  

1989 ◽  
Vol 4 (2) ◽  
pp. 373-384 ◽  
Author(s):  
B. E. Williams ◽  
J. T. Glass

Thin carbon films grown from a low pressure methane-hydrogen gas mixture by microwave plasma enhanced CVD have been examined by Auger electron spectroscopy, secondary ion mass spectrometry, electron and x-ray diffraction, electron energy loss spectroscopy, and electron microscopy. They were determined to be similar to natural diamond in terms of composition, structure, and bonding. The surface morphology of the diamond films was a function of position on the sample surface and the methane concentration in the feedgas. Well-faceted diamond crystals were observed near the center of the sample whereas a less faceted, cauliflower texture was observed near the edge of the sample, presumably due to variations in temperature across the surface of the sample. Regarding methane concentration effects, threefold {111} faceted diamond crystals were predominant on a film grown at 0.3% CH4 in H2 while fourfold {100} facets were observed on films grown in 1.0% and 2.0% CH4 in H2. Transmission electron microscopy of the diamond films has shown that the majority of diamond crystals have a very high defect density comprised of {111} twins, {111} stacking faults, and dislocations. In addition, cross-sectional TEM has revealed a 50 Å epitaxial layer of β3–SiC at the diamond-silicon interface of a film grown with 0.3% CH4 in H2 while no such layer was observed on a diamond film grown in 2.0% CH4 in H2.


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