Design and Performance Investigation of a Compact Catalytic Reactor Integrated with Heat Recuperator

The catalytic combustion has the advantage of lower auto-ignition temperature and helps to expand the combustible limit of lean premixed gas. However, the intake needs to be preheated to certain temperature commonly through an independent heat exchanger. Similar to the principles of non-catalytic RTO combustion, this paper presents a similar approach whereby the combustion chamber is replaced by a catalytic combustion bed. A new catalytic reactor integrated with a heat recuperator is designed to enhance the heat recirculation effect. Using a two-dimensional computational fluid dynamics model, the performance of the reactor is studied. The reaction performances of the traditional and compact reactors are compared and analyzed. Under the same conditions, the compact reactor has better reaction performance and heat recirculation effect, which can effectively decrease the ignition temperature of feed gas. The influences of the inlet velocity, the inlet temperature, the methane concentration, and the thermal conductivity of porous media on the reaction performance of integrated catalytic reactor are studied. The results show that the inlet velocity, inlet temperature, methane concentration, and thermal conductivity of porous media materials have important effects on the reactor performance and heat recirculation effect, and the thermal conductivity of porous media materials has the most obvious influence. Moreover, the reaction performance of multiunit integrated catalytic reactor is studied. The results show that the regenerative effect of multiunit integrated catalytic reactor is further enhanced. This paper is of great significance to the recycling of low calorific value gas energy and relieving energy stress in the future.

The Efficiency of Pd Addition and Sr Substitution on La1−xSrxMnO3 to Remove Ventilation Air Methane in a Catalytic Flow Reversal Reactor

Ventilation air methane (VAM) is the main cause of greenhouse gas emissions in coal mining. Catalytic flow reverse reactor (CFRR) is widely used in VAM to mitigate methane emissions. In this study, palladium (Pd) and La1−xSrxMnO3 were used as catalysts in a CFRR. Different types of catalysts were prepared by loading La0.8Sr0.2MnO3, La0.9Sr0.1MnO3, and 0.1%Pd-La0.9Sr0.1MnO3 on a cordierite honeycomb reactor coated with γ-Al2O3 to compare their performances. In addition, this study compared the performance of the three catalysts in an 800 °C reactor based on different methane inlet concentrations, inlet speeds, and conversion times. The results showed: (1) 0.1% addition of Pd increased methane conversion. (2) La0.8Sr0.2MnO3 had higher efficiency at lower methane inlet concentrations, whereas La0.9Sr0.1MnO3 was more efficient at higher methane concentrations. This study demonstrates that a higher Sr loading is worth implementing only when the methane concentration of VAM is lower than 0.6%. (3) To achieve a higher methane conversion efficiency, the inlet velocity of methane should also be considered.

CFD Modeling of Flame Jump across Air Gap between Evasé and Capture Duct for Ventilation Air Methane Abatement

The ventilation air–methane (VAM) released from underground mines is often transported into regenerative thermal oxidizer (RTO) devices and burnt into heat energy. This study numerically investigates the scenarios where explosion occurs inside the RTO and the flame and pressure waves propagate back quickly towards the VAM discharge duct. Possibilities of secondary explosion in the discharge duct, hence in the downstream underground mines, are examined. The results critically showed that when the methane concentration accumulated in the RTO reached 7.5% or above, the flame generated from the explosion jumped to the evasé of the discharge section (over a distance of 29.4 m) and could induce explosions in underground mines.

The Development of a Low-Cost Method for Monitoring Methane Leakage from the Subsurface of Natural Gas Fields

The leakage of methane from the subsurface on the coalfield or natural gas field invariably becomes an important issue nowadays. In notable addition, materials such as activated carbon, zeolites, and Porapak have been successfully identified as adsorbents. Those adsorbents could adsorb methane at atmospheric pressure and room temperature. Therefore, in this scholarly study, a new method using adsorbents to detect points of methane leakage that can cover a wide-scale area was developed. In the beginning, the most capable adsorbent should be determined by quantifying adsorbed methane amount. Furthermore, checking the possibility of adsorption in the column diffusion and desorption method of adsorbents is equally necessary. The most capable adsorbent was activated carbon (AC), which can adsorb 1.187 × 10−3 mg-CH4/g-AC. Hereinafter, activated carbon successfully can adsorb methane through column diffusion, which simulates the situation of on-site measurement. The specific amount of adsorbed methane when the initial concentrations of CH4 in a bag were 200 ppm, 100 ppm, and 50 ppm was found to be 0.818 × 10−3 mg-CH4/g-AC, 0.397 × 10−3 mg-CH4/g-AC, 0.161 × 10−3 mg-CH4/g-AC, respectively. Desorption of activated carbon analysis shows that methane concentration increases during an hour in the temperature bath under 80 °C. In conclusion, soil methane leakage points can be detected using activated carbon by identifying the observed methane concentration increase.

The Impact of Cutting with a Shearer on the Conditions of Longwall Ventilation

In coal mines that are exploiting methane-saturated seams, high-level emission of methane is often the basic limitation for modern and high-efficiency longwall complexes. This paper presents selected observations and tests carried out in the Cw-4 longwall in seam 364/2 of the Budryk mine, which belongs to JSW SA. To observe the methane levels in the Cw-4 longwall, additional sensors were installed at the end section of the longwall from the side of the gobs, and the air velocity and methane concentration were registered in a multi-point system that were built in the selected longwall cross-section. The air parameters were recorded in the monitoring system. The use of multi-point simultaneous measurements of the local velocities and concentrations of methane in the longwall cross-section allowed for the precise determination of the air and methane volume flow using the velocity field method. This allowed us to perform a comparative analysis of the obtained records of the air parameters using special software to determine the distribution of the parameters in the cross-section of the excavation. An important element of the study was the simultaneous registration of the methane concentration in the longwall, information on the operating times, the direction of shearer operation, and the type of work being done (i.e., mining/cleaning).